全文获取类型
收费全文 | 209篇 |
免费 | 12篇 |
国内免费 | 5篇 |
专业分类
化学 | 103篇 |
晶体学 | 1篇 |
力学 | 23篇 |
综合类 | 2篇 |
数学 | 9篇 |
物理学 | 88篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 6篇 |
2020年 | 8篇 |
2019年 | 5篇 |
2018年 | 12篇 |
2017年 | 1篇 |
2016年 | 9篇 |
2015年 | 8篇 |
2014年 | 6篇 |
2013年 | 39篇 |
2012年 | 12篇 |
2011年 | 16篇 |
2010年 | 7篇 |
2009年 | 7篇 |
2008年 | 14篇 |
2007年 | 9篇 |
2006年 | 13篇 |
2005年 | 5篇 |
2004年 | 4篇 |
2003年 | 3篇 |
2002年 | 6篇 |
2001年 | 2篇 |
1999年 | 2篇 |
1998年 | 7篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1981年 | 1篇 |
排序方式: 共有226条查询结果,搜索用时 15 毫秒
51.
L. M. Ocampo C. O. R. Mattos I. C. P. Margarit-Mattos J. D. Fabris M. C. Pereira H. R. Rechenberg D. L. A. de Faria 《Hyperfine Interactions》2006,167(1-3):739-746
Four samples of steels with alloying elements were exposed to an industrial environment during 1,955 days, aiming to elucidate the effect of the alloying elements Cu and Ni on the resistance of weathering steels to corrosion processes. The samples were characterized with optical microscopy, scanning electron microscopy (SEM), powder X-ray diffraction (XRD), saturation magnetization measurements and with energy dispersive (EDS), infrared, Mössbauer and Raman spectroscopies. All the steels originated orange and dark corrosion layers; their thicknesses were determined from the SEM images. EDS data of such rust layers showed that the alloying element content decreases from the steel core towards the outer part of the rust layer. Moreover, in the dark rust layer some light-gray regions were identified in the W and Cu-alloy steel, where relatively higher Cr and Cu contents were found. XRD patterns, infrared, Raman and Mössbauer spectra (298, 110 and 4 K) indicated that the corrosion products are qualitatively the same, containing lepidocrocite (γFeOOH; hereinafter, it may be referred to as simply L), goethite (αFeOOH; G), feroxyhite (δ′FeOOH; F), hematite (αFe2O3; H) and magnetite (Fe3O4; M) in all samples; this composition does not depend upon the steel type, but their relative concentrations is related to the alloying element. Mössbauer data reveal the presence of (super)paramagnetic iron oxides in the corrosion products. Saturation magnetization measurements suggest that feroxyhite may be an occurring ferrimagnetic phase in the rust layer. 相似文献
52.
4-(2-Thiazolylazo)resorcinol (TAR) is used as a chelating reagent in the reversed-phase HPLC separation and determination of transition and rare earth elements in low-alloy steels. A precolumn derivatization method is used, followed by separation on an octadecyl-bonded silica stationary phase with a sodium octane-1-sulphonate-tartaric acid mobile phase. The eluted metal chelates are detected by uv-visible spectrophotometry. The requirements for sample preparation, characterization of precolumn derivatization and the optimum conditions for the sensitive detection of metal ions after liquid chromatography (LC) separation are discussed. The influence of the pH of the chelating medium and the eluent, the concentration of TAR and the eluent were investigated. The results are compared with those of other methods such as atomic absorption spectrometry (AAS) and inductively coupled plasma atomic emission spectrometry (ICP-AES). 相似文献
53.
We describe the quantitative determination of low nitrogen contents (< 1 %wt) in highly-alloyed, duplex stainless steels
by EPMA using a calibration curve. Five monophasic stainless steels with various nitrogen concentrations were used for the
calibration curve, namely, three highly alloyed steels prepared in the laboratory, with nitrogen contents 0.066, 0.565 and
1.016 %wt and two industrial alloys with nitrogen concentrations 0.174 %wt and 0.023 %wt. For these samples, the plot of nitrogen
X-ray intensities versus nitrogen contents exhibited an acceptable linear relationship. Average nitrogen contents of the analysed
duplex alloys were found to vary in the range < 0.045–0.07 %wt in ferrite and 0.52–0.77 %wt in austenite. These results suggest
that the nitrogen solubility limit in ferrite has been reached; on the other hand, nitrogen solubility in austenite increases
due to the high manganese and low nickel contents. 相似文献
54.
Mary Kamburova 《Mikrochimica acta》1998,128(3-4):177-180
The interaction of Cr(VI) and Nitrotetrazolium Blue has been examined. A 12 NTB (CrO3Cl)2 ion-associate is formed and is extractable into 1,2-dichloroethane. The optimum conditions have been established. The molar absorptivity at 260 nm was (8.2 ± 0.06) × 104L mol–1cm–1. Beer's law was obeyed in the range 0.01–0.4 g ml–1 Cr(VI). A sensitive and selective method for determination of micro-quantities of Cr(VI) in soils and steels is suggested. 相似文献
55.
Hui-Ling Lee 《Talanta》2007,73(1):76-80
A sensitive and robust high-performance liquid chromatography-electrospray ionization tandem mass spectrometry method to analyze 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK) and its five metabolites in one passage was developed and validated. The method achieved excellent reproducibility and accuracy. Linearity was observed for all six compounds (R2 = 0.999) with detection limits (S/N ≥ 3) ranging from 0.2 to 2.4 pg on column and 0.01-0.12 ng ml−1 in samples injected. Average intra-day and inter-day variations (% R.S.D.) were 1.2 and 3.5%, respectively. A sample preparation method involving C8 and C18 solid phase extraction provided satisfactory recovery of the analytes in mouse urine. Each NNK metabolite was identified by its chromatographic retention time and specific fragmentation pattern. Since the carcinogenicity of NNK is related to its metabolism, the method described in this report should facilitate toxicological investigations into the carcinogenesis due to NNK exposure in the environment. 相似文献
56.
使用Spectro Lab M8光电直读光谱仪所提供的Fe-30不锈钢分析程序测定高锰不锈钢中硫量时,所得测定值均偏低。为此,改用高锰不锈钢国家光谱标准样品和内控样品,重新确定了干扰元素(特别是锰)的基体校正模式及测定硫元素的回归分析曲线。通过7个不同含锰量的不锈钢标准样品的分析验证,证明采用经过改进的方法所得测定值均与认定值一致,其绝对误差值均小于JIS标准的允许差。 相似文献
57.
During the last years (2000–2014), many publications concerning the forensic analysis of questioned documents have been published, and new techniques and methodologies are nowadays employed to overcome forensic caseworks. This article reviews a comprehensive collection of the works focused on this issue, including dating studies, the analysis of inks from pens and printers, the analysis of paper, the analysis of other samples related to questioned documents and studies on intersecting lines. These sections highlight the most relevant analytical studies by a wide range of analytical techniques. Separation and spectrometric techniques are critically discussed and compared, emphasizing the advantages and disadvantages of each one. Finally, concluding remarks on the research published are included. 相似文献
58.
In this paper, a finite-element modelling framework is presented with explicit representation of polycrystalline microstructure for a tempered martensite ferritic steel. A miniature notched specimen was manufactured from P91 steel with a 20,000 h service history and tested at room temperature under three point bending. Deformation at the microscale is quantified by electron back scattered diffraction (EBSD) before and after mechanical loading. A representative volume element was developed, based on the initial EBSD scan, and a crystal plasticity model used to account for slip-based inelastic deformation in the material. The model showed excellent correlation with the experimental data when the relevant comparisons were made. 相似文献
59.
The hydrogels prepared by the crosslinking of partially saponified poly(vinyl alcohol) (PVA) which has low critical solution temperature (LCST) in water showed characteristics of swelling at low temperature and shrinkage at high temperature. The hydrogels showed repeatable swelling–shrinking behavior. The hydrogels containing release substances such as cyanocobalamin, p‐acetamidophenol, insulin and ovalbumin were prepared by dipping these aqueous solutions and the release substances were studied. Insulin and ovalbumin were not absorbed by the hydrogels when the use of partially PVA with the degrees of polymerization (DPs) of 540 were prepared, but absorbed by the hydrogels with DPs of 1860. The size of the polymer network prepared with a higher DP was suitable for the absorption of insulin and ovalbumin. In accordance with release substances, the release patterns were different. In this way, the polymer network sizes and their swelling behaviors of partially saponified PVAs were estimated. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
60.