全文获取类型
收费全文 | 3642篇 |
免费 | 489篇 |
国内免费 | 367篇 |
专业分类
化学 | 1403篇 |
晶体学 | 58篇 |
力学 | 657篇 |
综合类 | 26篇 |
数学 | 392篇 |
物理学 | 1962篇 |
出版年
2024年 | 3篇 |
2023年 | 44篇 |
2022年 | 71篇 |
2021年 | 68篇 |
2020年 | 93篇 |
2019年 | 78篇 |
2018年 | 80篇 |
2017年 | 110篇 |
2016年 | 181篇 |
2015年 | 157篇 |
2014年 | 199篇 |
2013年 | 286篇 |
2012年 | 196篇 |
2011年 | 267篇 |
2010年 | 194篇 |
2009年 | 267篇 |
2008年 | 267篇 |
2007年 | 265篇 |
2006年 | 264篇 |
2005年 | 167篇 |
2004年 | 178篇 |
2003年 | 148篇 |
2002年 | 134篇 |
2001年 | 95篇 |
2000年 | 108篇 |
1999年 | 86篇 |
1998年 | 93篇 |
1997年 | 59篇 |
1996年 | 56篇 |
1995年 | 56篇 |
1994年 | 41篇 |
1993年 | 27篇 |
1992年 | 33篇 |
1991年 | 18篇 |
1990年 | 19篇 |
1989年 | 13篇 |
1988年 | 11篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 12篇 |
1984年 | 10篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 11篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1971年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有4498条查询结果,搜索用时 15 毫秒
71.
Yinghong Sheng Jerzy Leszczynski Thuc-Quyen Nguyen Anu Bamgbelu 《Structural chemistry》2007,18(6):827-832
A theoretical study using density functional theory was performed to understand the structure/property relationship of the
cationic conjugated polyelectrolytes, poly[9,9-bis-(6′-N,N,N-trimethylammonium) hexyl] fluorene-alt-4,7-(2,1,3-benzothiadiazole)] (PFBT-X, where X = Br). The torsion angle between the fluorene and benzothiadiazole units in the PFBT monomer was found to substantially affect
the structural and electronic properties of the cationic PFBT monomer. The changes of geometrical parameter, HOMO and LUMO energy levels, and band gap, as well as the absorption maximum
are discussed in terms of the torsion in the PFBT monomer structure. For comparison, its neutral analogue, the monomer of
poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) (F8BT) was also studied. The length of conjugation backbone was also examined. 相似文献
72.
Jeong Hwan Kim Ji Hoon Ko Byeong-Soo Bae 《Journal of Sol-Gel Science and Technology》2007,41(3):249-255
Multi-scale hybrid nanocomposites containing both ∼15 nm silica colloids and ∼2 nm oligosiloxanes in a methacryl polymer matrix
were newly designed and fabricated. Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized
by sol-gel reaction of methacryloxypropylmethoxysilane and diphenylsilanediol. On the basis of TEM and SANS analyses, it was
confirmed that the silica colloids were compatibly dispersed and different sizes of colloidal silica and oligosiloxanes co-exist
in the solutions. Multi-scale hybrid nanocomposites fabricated by UV and thermal curing with incorporation of silica colloids
in the nano-hybrid materials show enhanced mechanical and thermal characteristics. 相似文献
73.
苯及其衍生物甲苯,一氯代苯都是重要的有机试剂和化工原料,也是对人体有害的有机物。为了了解这些有机试剂对处于生物液晶态的生物膜毒害的机理,我们以含水卵磷脂组成的液晶体系作为人工模型用小角X射线散射(SAXS)方法探讨这些有机试剂对它们结构的影响。关于苯或其它非极性有机介质与含水卵磷脂形成液晶体系及其结构模型前人有一些报导。 相似文献
74.
In this paper, minimax principles are explored for elliptic mixed hemivariational–variational inequalities. Under certain conditions, a saddle-point formulation is shown to be equivalent to a mixed hemivariational–variational inequality. While the minimax principle is of independent interest, it is employed in this paper to provide an elementary proof of the solution existence of the mixed hemivariational–variational inequality. Theoretical results are illustrated in the applications of two contact problems. 相似文献
75.
Let be a Kähler surface and be a -symplectic critical surface in . If is bounded for some , then we give a uniform upper bound for the Kähler angle on . This bound only depends on and the functional of . For , this estimate is known and we extend the scope of . 相似文献
76.
Norio Konno 《Journal of Theoretical Probability》1995,8(4):833-876
In this paper we consider the basic contact process with infection rate λ and stirring rateD. We study the asymptotic behavior of the critical value
and survival probability
asD→∞. 相似文献
77.
A model, based on inverse gas chromatography experiments, has been developed for intermolecular interaction and its temperature dependence. The model ascribes to each substance a four-component solubility parameter; the four components reflect the van der Waals, polar, electron donor, and electron acceptor interactive properties. Their values depend on temperature in the same manner as does the cohesive energy. The latter was found to depend only on the critical temperature, the acentric factor, and the reduced temperature. The model was used for evaluation of the solubility parameters from polymer-solvent interaction coefficients and their temperature dependence with high accuracy. For binary solventsolvent mixtures, the free energy of mixing and its temperature dependence, as well as enthalpy of mixing can be derived from this model with a good accuracy. 相似文献
78.
Odin C 《Magnetic resonance in chemistry : MRC》2004,42(4):381-388
A variable-temperature high-resolution 13C and 87Rb solid-state NMR study of powder rubidium hydrogencarbonate, RbHCO3, is presented for the first time. At ambient temperature, RbHCO3 is formed by centrosymmetric dimers linked by hydrogen bonds, but almost no information is available on this compound concerning proton disorder and the low-temperature phase. However, potassium hydrogencarbonate, KHCO3, which has an isomorphic structure for the high temperature phase, was well studied: it undergoes a non-ferroic, non-ferroelectric phase transition at Tc = 318 K between two monoclinic structures. The protons are disordered in an asymmetric double-well potential in the low-temperature phase, and the double-well potential becomes symmetric in the high-temperature phase. By comparison with recent solid-state NMR experimental results on KHCO3, we show that RbHCO3 undergoes a phase transition at Tc approximately 245 K, and give evidence that the proton dynamic disorder in both compounds is very similar. 相似文献
79.
Katja Jankova 《Journal of fluorine chemistry》2005,126(2):241-250
Block copolymers based on poly(pentafluorostyrene), PFS, in various numbers and of different lengths, and polystyrene are prepared by atom transfer radical polymerization (ATRP). Di- and triblock copolymers with varying amounts of PFS were synthesized employing either 1-phenylethylbromide or 1,4-dibromoxylene as initiators for ATRP. Diverse bromo(ester) (macro)initiators were also devised and involved in the formulation of fluorinated pentablock as well as amphiphilic triblock copolymers with a central polyether segment. Amphiphilic star-shaped fluoropolymers, hydrophobic fluorinated nanoparticles, or segmented fluorinated star-shaped block copolymers are further designed by use of different multifunctional initiators. The composition of the novel materials with PFS is determined by combination of SEC and 1H NMR. Glass transition temperatures and thermal stabilities of the hydrophobic star-shaped PFSs on a six arm dipentaerythritol core are investigated in a wide range of molecular masses and further discussed. 相似文献
80.
Samuel O. Asekomhe Janet A. W. Elliott 《Colloids and surfaces. A, Physicochemical and engineering aspects》2003,220(1-3):271-278
Much research has been done on line tension measurement and interpretation, and attempts have also been made to measure line tension with simple, cheap and reliable methods that do not require excessive sophistication. Of particular interest is the method of determining line tensions of solid–liquid–vapor systems from the capillary rise in a conical tube. This simple and relatively inexpensive method gives line tension values comparable to those reported in the literature obtained via highly sophisticated instruments or techniques such as the well known axisymmetric drop shape analysis technique. The absolute value of line tension obtained using the conical tube method and assuming a spherical liquid–vapor interface is larger but of the same order of magnitude (1 μJ m−1) as that reported in the literature. A theoretical analysis presented herein shows that by including the deformation of the liquid–vapor interface due to gravity in the conical capillary analysis, the line tension value inferred from the experimental data is reduced by approximately 50% and compares better with values in the literature obtained using other sophisticated methods. Thus a relatively simple, cheap, accurate and reliable method of line tension measurement has been advanced. 相似文献