Raman Spectroscopy of Nitrogen Clathrate Hydrates

在253 K和16 MPa的压力下,于实验室内合成了氮气水合物,用显微共焦拉曼光谱对其N-N和O-H键伸缩振动的光谱特征进行了研究．结果表明,氮气水合物中的N-N和O-H键的拉曼峰分别为2322.4和3092.1 cm^-1,与天然的空气水合物中的数据十分接近．另外,还测定了液氮和溶解于水中的氮分子中N-N键的拉曼峰值,分别为2326.6和2325.0 cm^-1．氮气笼型水合物分解的拉曼谱图表明,氮分子同时进入水合物的大笼和小笼中,但由于氮分子在大、小笼中的环境氛围十分接近,其拉曼位移相差不大,故拉曼谱图只能显示N-N键伸缩振动一个峰．     

Resonance Raman Study of Aggregated Meso-tetra(4-pyridinium) porphyrin Diacid

研究了近激子吸收带激发下四-(4-吡啶基)卟啉二酸(H₈TPyP⁶⁺)聚集体的共振拉曼光谱．测量了H₈TPyP⁶⁺单体和聚集体的紫外可见吸收谱和共振光散射光谱．在氘代位移的基础上结合相关体系振动光谱研究,对测得的H₈TPyP⁶⁺)单体和聚集体的拉曼谱带进行了指认．聚集体的形成导致H₈TPyP⁶⁺的卟啉环CC/CN面内伸缩振动向低波数方向位移2～6 cm^-1,而卟啉环鞍形面外振动带向高波数方向位移12cm^-1．基于拉曼谱带的强度和频率变化分析了聚集引起的H₈TPyP⁶⁺分子内结构变化和分子间氢键作用     

Mass-analyzed Threshold Ionization Spectroscopy of Rotamers of p-ethoxyphenol Cations and Configuration Effect

利用双色双光子质量分辨的阈值电离光谱技术,研究了对位乙氧基苯酚顺式和反式两种构型的离子态振动特性. 测得顺式和反式精确的绝热电离势分别为61565±5和61670±5 cm^-1. 与对位甲氧基苯酚实验结果比较,顺式和反式的测得的绝热电离势分别降低了645和643 cm^-1. 从所得到的两种构型的高分辨离子态光谱中,可知顺式和反式不同构型对苯环平面的振动影响很小,而低频率的C-OC₂H₅弯曲振动在两种构型中都很活跃.     

Quantitative Surface Chirality Detection with Sum Frequency Generation Vibrational Spectroscopy: Twin Polarization Angle Approach

介绍了一种新的表面和频振动光谱方法: 定量手性检测中的双偏振角方法. 一般来讲表面光谱信号中非手性项贡献最强,而纯界面手性信号要比非手性信号弱两到三个数量级. 因此在和频振动光定量测量和分析界面手性的贡献问题上存在困难. 在和频振动光谱的双偏振角方法中,通过固定入射红外光偏振方向,并同时改变入射可见光和初涉和频信号光的偏振角进行测量. 这样所得到的偏振依赖的和频振动光谱信号能够直接给出界面手性贡献的特征,并 且能够用于准确测量界面的手性和非手性贡献. 对双偏振角方法进行了描述,并且通过S和R手性的柠檬烯空     

航空稳像光电平台设计

分析了随机振动对调制传递函数的影响,指出角位移是影响航空成像质量的主要因素.研究了特定条件下可容许的MTF下降,并转变为稳定系统的设计参量,用来指导稳像系统的设计.利用空间机构学及平行四边形平动原理,研制了一种新的无角位移减振稳像平台,满足既无角位移又达到减振要求.根据设计理论给出了设计实例,对频率高于100 HZ的振动,衰减达34dB,并利用动力学软件进行测试仿真,仿真曲线验证无角位移减振的正确性,同时对无角位移机构进行光学测试,结果耦合角度小于8″,可以满足航空成像要求.     

A fiber micro-vibration sensor based on single-mode fiber ring laser

A new micro-vibration sensor based on single-mode fiber ring laser is put forward. The Mach-Zehnder interferometric （MZI） detection technique is presented for interrogating laser frequency shift due to the measurand （piezoelectric transducer （PZT） is used to simulate the micro-vibration） induced laser cavity strain from both single- and multi-mode lasers. In the experiment, compared with multi-mode laser sensors, the single-mode laser sensor is proved to be a sensor with high resolution. When the PZT is driven by the analog signal （0.03 rad near 2 kHz）, the signal-to-noise ratio （SNR） of output signal from the single-mode laser sensor is close to 55 dB and the sensitivity of the sensor is about 5 ×10^-5 rad/Hz1/2.     

Localization theory of distributed fiber vibration sensor

Based on Sagnac interferometer, a simple distributed optical fiber sensing system with sub-loop is presented to monitor the vibration applied on the sensing fiber. By introducing a sub-loop, three output beams of interference with different delay time are gotten. Location of the vibration is analyzed through mathematical-physical equations. The vibration frequency, amplitude, and location are theoretically simulated. The results agree well with the previous experiments.     

直线运动型无线光通信中振动对光接收功率的影响分析

对直线运动型无线光通信中的光束偏转进行了分析,给出了不同运动距离与光斑半径、光接收功率的关系;不同偏转角度与光接收功率、像点偏移量的关系.在直线轨道上,进行了发射端静止、接收端运动,发射端运动、接收端静止两种情况下的光功率接收实验,并分别比较大孔径光纤和实心耦合光锥的空间光接收性能,提出采用实心光锥作为空间光耦合接收元件.实验结果表明:在运动距离最远为80 m的情况下,实心耦合光锥能有效接收光束偏移后的聚焦光信号,适用于直线运动型无线光通信.     

Lattice Boltzmann Simulation of the Cross Flow Over a Cantilevered and Longitudinally Vibrating Circular Cylinder

The multiple-relaxation-time lattice Boltzmann method （MRT-LBM） is implemented to numerically simulate the cross flow over a longitudinal vibrating circular cylinder. This research is carried out on a three-dimensional （3D） finite cantilevered cylinder to investigate the effect of forced vibration on the wake characteristics and the 3D effect of a cantilevered cylinder. To meet the accuracy of this method, the present calculation is carried out at a low Reynolds number Re =100, as well as to make the vibration obvious, we make the vibration strong enough. The calculation results indicate that the vibration has significant influence on the wake characteristics. When the vibrating is big enough, our early works show that the 2D vortex shedding would be locked up by vibration. Contrarily, this phenomenon would not appear in the present 3D case because of the end effect of the cantilevered cylinder.     

Ultrasonic Vibration Suspends Large Pendant Drops

A stationary substrate can suspend only small pendant drops even with excellent wetting ability because of gravity. We report the suspension of large pendant water drops by a copper substrate that vibrates ultrasonically with a frequency of 22 kHz. The mass of the largest pendant drop suspended by the vibrating substrate reaches 1.1 g, which is 9 times that by the same stationary substrate. The pendant drop deforms drasticaJly and quickly at both the beginning and the end of the vibration procedure. As the vibration power increases, the contact area between the drop and substrate expands and the drop height shrinks accordingly. Theoretical analysis indicates that the Bernoulli pressure induced by ultrasonic vibration may contribute strongly to enhancing the suspensibility of pendant drops.