量子尺寸效应对原子表面扩散运动具有调制作用

近日，中科院物理所表面物理国家重点实验室SF4研究组及其合作者在薄膜生长动力学研究中取得新进展．他们从实验和理论上研究了Si（111）单晶衬底上Pb薄膜中的厚度变化对原子表面扩散运动的影响，证明了量子尺寸效应对原子表面扩散运动的调制作用．该成果被选作封面图片发表在美国《物理评论快报》上．     

Unexpected Synthesis of 2, 2＇-[1-（4-Methoxyphenoxy）propane-2, 2-diyl]bis（5-methoxy-3-methylbenzofuran）

A new bisbenzofuran analogue Ⅶ was achieved unexpectedly in one step procedure from 1-（4-methoxyphenoxy）acetone Ⅰ by using Amberlyst 15 resin as catalyst in excellent yield. The structure was elucidated by spectroscopy analysis including ^1H-NMR, ^13C-NMR, DEPT, ESI-MS, element analysis.     

用于电热原子吸收光谱法机理研究的方法

本文对电热原子吸收光谱法机理研究的常用方法，特别是多种物理测试手段进行介绍。     

低密度聚乙烯光引发交联机理

首次用溶液高分辨￣（１３）ＣＮＭＲ研究了由二苯甲酮光引发低密度聚乙烯（ＬＤＰＥ）交联所产生的交联结构，现已观测和鉴定了Ｈ型和Ｙ型长链支化两类交联点。对于熔融态紫外光交联５－１０ｓ的ＬＤＰＥ样品，其Ｈ型和Ｙ型交联点的浓度据估测分别为一万个碳原子中有５．７－１６．９和７．６－２１．６个结构单元。     

孔隙材料的动态破碎机理

本文利用动态微孔长大的Ｃ－Ｈ－Ｊ细观模型，分析子孔隙材料的动态破碎的细观机理，利用Ｇｒａｄｙ的动态破碎的能量描述，给出了破碎尺寸分布与材料孔隙度（损伤度）的定量关系，利用本文的结果，对破甲弹的破甲规律也可给出合理的解释。     

Mixed Symmetry Isomeric States in Nuclei

Mixed symmetry states are studied in the framework of the neutron-proton interacting boson model.It is found that some of the mixed symmetry states with moderate high spins change very fast with respect to the Majorana interaction.Under certain conditions,they become the yrast state or yrare state.These states are difficult to decay and become very stable.This study suggests that a possible new mode of isomers may exist due to the special nature in their proton and neutron degrees of freedom.     

介绍一个化学工程与分析化学相结合的综合化学实验——超滤回收聚乙二醇

介绍超滤回收溶液中聚乙二醇的实验。采用Dragendorff试剂方法测定聚乙二醇浓度和截留率,研究操作条件对渗透速率的影响,探讨膜污染机理以及清洗方法,并根据实验中发现的问题,改进了Dragendorff测定方法。     

Isospin Effect of Coulomb Interaction on Nuclear Stopping in Intermediate Energy Heavy Ion Collisions

Nuclei offer an interesting isospin situation where symmetry potential, Coulomb term and isopin dependent nucleon-nucleon collisions are simultaneously present. However, in general, Coulomb potential is not studied in the heavy ion collisions. As we know that the Coulomb potential is an important asymmetry term which can bring important isospin effect into the observable in the intermediate energy heavy ion collisions. Recently extensions by Colonna et al.[1] to finite nuclei show that Coulomb and surface effects reduce instability regions. So in this paper the isospin effects of Coulomb term and symmetry potential on the nuclear stopping at intermediate energy heavy ion collisions are studied by using isospin-dependent quantum molecular dynamics model (IQMD).     

铸造锌铝合金稀土变质机理的电子理论研究

根据分子动力学理论建立了液态锌铝合金ZA27的模型，结合计算机编程构造出了ZA27合金α 相与液相共存时的原子结构模型，利用递归方法计算了稀土固溶于晶粒内和富集于结晶前沿 时的电子结构.由此得出：稀土处于相界区比在晶内更稳定，从而解释了稀土在α相内溶解 度很小，结晶时富集于结晶前沿液体中的事实；稀土处于液态和晶态的结构能差相对于铝较 大解释了稀土在相界前的富集使α晶枝产生熔断、游离、增殖的观点.原子间的键级积分计 算也表明，稀土处于结晶前沿液体中与铝相比不容易结晶到晶体表面，起到阻碍晶粒长大， 细化晶粒的作用，这就从电子层次解释了稀土的变质机理. 关键词： 电子结构 液固相界原子结构模型 稀土变质机理