Polystyrene—supported Benzyl Selenide：An Effcient Reagent for Highly Stereocontrolled Synthesis of Substituted Olefins

Polystryene-supported benzly selenide has been prepared.This novel reagent was treated with LDA to produce a selenium stabilized carbanion,which reacted with alkyl halide,followed by selenoxide syn-elimination,to give substituted olefins stereospecificly.     

大米中硒的FI-HG-AAS测定方法研究

研究了原子化器温度、载气流速、KBH4 浓度等条件对流动注射 氢化物发生 原子吸收光谱法 (FI-HG -AAS)测定硒时的影响。建立了FI-HG -AAS测定大米中硒的分析方法。在优化的工作条件下 ,测定硒的最低检测浓度为 0 3 3 μg·L- 1,线性范围为 0～ 5 0 μg·L- 1,相对标准偏差小于 4% ,加标回收率为 94%～ 1 0 2 %。本法克服了传统的间断氢化物发生 原子吸收光谱法分析速度慢、样品耗量大、操作繁琐且因手工进样在进样速度和进样体积上容易带来误差等缺点。方法操作简便、快速 ,灵敏度及自动化程度高 ,已广泛应用于大米及富硒大米中微量硒的测定     

理想流体一维绝热稳定流动能量方程推导

对理想流体一维绝热稳定流动作了讨论．对一般理想流体(可压缩或不可压缩)，用两种方法推出了能量方程．在此基础上，讨论了流动可逆性及不同流体性质对流动参数的影响．     

流动注射原子吸收光谱法测定富硒天麻、葡萄及大米中的硒

建立了流动注射氢化物发生-原子吸收光谱法测定富硒天麻、葡萄及大米中硒的方法。测定硒的线性范围为0．33μg/L-50μg/L，相对标准偏差小于3％，加标回收率为93％-106％。方法已广泛应用于实际样品中微量硒的测定。     

Ni（Ⅱ）—MOBTAMB—TritonX—100体系析相光度法测定痕量镍

研究了Triton X-100在浊点条件下,对Ni(Ⅱ)-2-[2′-(6′-甲氧基-苯并噻唑)偶氮]-5-二甲氨基苯甲酸(MOBTAMB)配合物的析相条件。在pH 8.6～9.5的氨-氧化铵缓冲体系中,90℃水浴加热1.5h,析相完全。配合物最大吸收峰位于658nm处,表观摩尔吸光系数为5.5×10~5。镍含量在0～3μg/30ml范围内符合比耳定律。所拟方法用于天然水中的痕量镍测定,结果满意。     

一类二阶非线性常微分方程非线性边界条件的两点边值问题

本文讨论了一类二阶非线性常微分方程之具有线性边界条件的和具有非线性边界条件的两点边值问题解的存在性.     

乙醇增敏光泽精－H_2O_2－Pb（Ⅱ）化学发光体系的研究及应用

本文研究了Ｈ＿２Ｏ＿２氧化光泽精发光反应及乙醇的敏化作用，发现加入乙醇可使铅催化Ｈ＿２Ｏ＿２，氧化光泽精的发光强度有较大幅度的增强；铅量在３×１０￣（－７）～８×１０￣（－５）ｇ／ｍＬ。范围内与发光强度成正比．方法检出限为０．１０μｇ／ｍＬ；对含４μｇ／ｍＬＰｂ（Ⅱ）１１次重复测定，其ＲＳＤ为２．３％．对３２种常见的阴阳离子进行了干扰实验，表明方法具有较好的选择性。本法应用于水样及沉积物标样中痕量铅的测定，结果良好。     

液态金属流的表面张力问题中的两点边值问题解的存在性

本文讨论了在区域提纯过程中，研究液态金属流的表面张力时提出的一个带有非负参数Ｑ的两点边值问题．利用上、下解方法和Ｓｃｈａｕｄｅｒ不动点定理，证明了当０Ｑ８５１时，该问题至少有一个解，对已有结果０Ｑ＜１进行了重要的改进．     

A Heterogeneous Agent Herding Model with Time and Space Effect

We propose a heterogeneous agent herding model, in which the agent clusters are in active or inactive states. When agent clusters are in active states, they tend to buy or sell. In active states, an exchange may occur when two heterogeneous agent clusters encounter each other, and they may merge into a bigger one when two homogeneous agent clusters meet. The ratio of successful exchange or merging depends on two parameters： i.e. the reliability κ, reflecting the credible degree in the interacting agent clusters, being the space effect of the market, and the response degree q, reflecting the influence of the former trading to the current action, being the time effect of the market. Our numerical calculation shows that the dynamics of the model exhibits some behaviour very close to real markets when tuning the reliability and the degree of reaction to some specific values.     

Multiple-State Storage Capability of Stacked Chalcogenide Films （Si16Sb33Te51/Si4Sb45Te51/Si11Sb39Te50） for Phase Change Memory

The multiple-state storage capability of phase change memory （PCM） is confirmed by using stacked chalcogenide films as the storage medium. The current-voltage characteristics and the resistance-current characteristics of the PCM clearly indicate that four states can be stored in this stacked film structure. Qualitative analysis indicates that the multiple-state storage capability of this stacked film structure is due to successive crystallizations in different Si-Sb-Te layers triggered by different amplitude currents.