全文获取类型
收费全文 | 2335篇 |
免费 | 194篇 |
国内免费 | 487篇 |
专业分类
化学 | 2571篇 |
晶体学 | 87篇 |
力学 | 15篇 |
综合类 | 21篇 |
物理学 | 322篇 |
出版年
2024年 | 4篇 |
2023年 | 36篇 |
2022年 | 46篇 |
2021年 | 83篇 |
2020年 | 88篇 |
2019年 | 78篇 |
2018年 | 68篇 |
2017年 | 102篇 |
2016年 | 112篇 |
2015年 | 114篇 |
2014年 | 97篇 |
2013年 | 281篇 |
2012年 | 173篇 |
2011年 | 92篇 |
2010年 | 108篇 |
2009年 | 113篇 |
2008年 | 109篇 |
2007年 | 140篇 |
2006年 | 136篇 |
2005年 | 146篇 |
2004年 | 122篇 |
2003年 | 98篇 |
2002年 | 96篇 |
2001年 | 53篇 |
2000年 | 61篇 |
1999年 | 56篇 |
1998年 | 52篇 |
1997年 | 54篇 |
1996年 | 45篇 |
1995年 | 48篇 |
1994年 | 57篇 |
1993年 | 26篇 |
1992年 | 35篇 |
1991年 | 22篇 |
1990年 | 13篇 |
1989年 | 12篇 |
1988年 | 9篇 |
1987年 | 6篇 |
1986年 | 6篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有3016条查询结果,搜索用时 15 毫秒
61.
四核钴羰基簇合物Co4(CO)8(μ-CO)2(μ4-PSR)2的合成和晶体结构 总被引:1,自引:0,他引:1
The title compounds Co4(CO)8(μ-CO)2 (μ4-PSR) [R=-CH3, -C2H5, -C(CH3)3,-(CHa)4CH3] were synthesized by the reaction of Co2(CO)8 with RSPCl2. They were characterized by IR, 1HNMR, elemental analysis. The crystal and molecular structure of Co4(Co)8(μ-CO)2 (μ4-PSC2H5) has been determined by single crystal diffraction method. Crystal data: monoclinic, space group P21 /c, with a=8-445(3), 6=8.562(3), c= 17.125(6)Å, β=104.26 (3)' 9 V=1200.1Å3, Z=2, Dc=1.937gcm-3. Its molecular structure contains an octahedral Co4P2 skeleton which consists of a rectangular four cobalt atoms core and the Co4 core is capped above and below by two quadruply bridging PSR ligands. 相似文献
62.
Pentaazadienido Complexes of Zinc, Cadmium, and Mercury. The Crystal Structure of [Cd(EtOC6H4-N5-C6H4OEt)2(py)2] and [Hg(tol-N5-tol)2(py)] The pentaazadienido complexes [M(EtOC6H4N5C6H4OEt)2] (M = Zn ( 1 ), Cd ( 2 )) are formed by the reaction of [M(NH3)4]2+ with [EtOC6H4N5C6H4OEt]? in aqueous ammonia. 2 crystallizes from pyridine as [Cd(EtOC6H4N5C6H4OEt)2py2] ( 3 ) with the triclinic space group P1 and a = 937.2(2); b = 1422.7(2); c = 2085.5(2) pm; α = 75.28(1)°; β = 94.74(1)°; γ = 99.75(1)°; Z = 2. The central Cd2+ ion of 3 exhibits an octahedral coordination by two pyridine ligands in cis arrangement and two (N1, N3)-2+ chelating pentaazadienide ions. The reaction of [HgI4]2 with the 1,5-di(tolyl)pentaazadienide anion in aqueous ammonia affords [Hg(p-tol-N5-tol)2] ( 4 ), which crystallizes from pyridine in form of [Hg(tol-N5-tol)2py] ( 5 ) with the space group P1 and a = 1176.2(4); b = 1203.1(3); c = 1295.6(5) pm; α = 100.77(3)°; β = 110.08(3)°; γ = 94.29(2)°; Z = 2. In 5 the Hg2+ cation is threefold coordinated by two monodentate (N3)-η1 pentaazadienid anions and one pyridine ligand. Within the N5 chains of the pentaazadienid anions of 3 and 5 localized N? N double bonds are found in the positions N1? N2 and N4? N5 with distances between 125 and 129 pm. 相似文献
63.
富镉Hg_(1-x)Cd_xTe是一种新型的光电转换材料,已用于固体结太阳能光伏电池:ITO/CdS/Hg_(1-)Cd_xTe/Au。我们曾对Hg_(1-x)Cd_xTe的电沉积机理作过研究。最近我们用电沉积制备的Hg_(0.09)Cd_(0.91)Te多晶薄膜做成了液体结太阳能光电化学电池并观察到明显光电响应。 相似文献
64.
Kenji Miyatake Mitsutoshi Jikei Junya Katoh Kimihisa Yamamoto Hiroyuki Nishide Eishun Tsuchida 《先进技术聚合物》1994,5(4):216-220
Poly(2,5-dimethylphenylene sulfide) was prepared by oxidative polymerization of sulfur chloride with p-xylene using 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) as an oxidizing agent. The reaction proceeded efficiently under atmospheric pressure and at room temperature. The polymer formed had a high melting temperature and linear structure which was confirmed by spectroscopies. The effects of reaction time, solvent, temperature and oxidizing agent on polymerization are also discussed. 相似文献
65.
66.
Semiconductor–semiconductor and molecule (molecular ion)–semiconductor products are formed upon the implantation of Ag+, Cu+, and Cu2+ ions in the CdS surface. Possible mechanisms were examined for their photocatalytic action in the reduction of methylene blue. 相似文献
67.
A. Müller E. Krickemeyer F. El-Katri D. Rehder A. Stammler H. Bgge F. Hellweg 《无机化学与普通化学杂志》1995,621(7):1160-1170
Simple Trithio- and Perthiocarbonato Complexes with Interesting Bond Properties: [E(CS3)2]2? (E = Sn, Zn, Cd), [E(CS3)3]3? (E = As, Sb, Bi, Co), {Cu(CS3)?}∞ and [Zn(CS4)2]2? By reactions of potassium trithiocarbonate ( 1 ) with solutions of zinc(II)- acetylacetonate, cadmium(II)-chloride, tin(II)-chloride, arsenic(III)-sulfide (suspension), antimony(III)-chloride, bismuth(III)-chloride and copper(II)-chloride in dimethyl sulfoxide, as well as of trisodium hexanitrito cobaltate(III) in water, and the precipitation of the complexes with an aqueous solution of tetraphenylphosphonium chloride the compounds (PPh4)2[Zn(CS3)2] ( 2 ), (PPh4)2[Cd(CS3)2] ( 3 ), (PPh4)2[Sn(CS3)2] ( 4 ), (PPh4)3[As(CS3)3] ( 5 ), (PPh4)3[Sb(CS3)3] ( 6 ), (PPh4)3[Bi(CS3)3] ( 7 ), (PPh4)3[Co(CS3)3] ( 8 ) and (PPh4)Cu(CS3) ( 9 ) have been isolated. (PPh4)2[Zn(CS4)2] · CH3NO2 ( 10 ) has been prepared by heating a solution of 2 in nitromethane to 60--70°C in presence of air. The reaction of 1 in dimethyl sulfoxide with an aqueous tetraphenylphosphonium chloride solution in presence of oxygen leads to (PPh4)2[C2S6] ( 11 ). The compounds have been characterized by spectroscopical studies (IR, Raman, UV/Vis, 113Cd/59Co-NMR), magnetic susceptibility measurements, powder diffractometry, elemental analyses and single crystal X-ray structure analysis ( 4 – 7 , 10 and 11 ). The difficult growing of single crystals has been reported in detail. For crystal data see Inhaltsübersicht. 相似文献
68.
Synthesis and Crystal Structure of a Novel Hexagonal Modification of Al2S3 with Five-coordinated Aluminum A new hexagonal high temperature modification of Al2S3 could be prepared by chemical vapour transport with iodine (860 → 750°C) or by annealing of α -Al2S3 at 550°C. According to the single crystal X-ray structure determination the novel form of Al2S3 crystallizes in space group P 61 (No. 169) with a = 6.491(1), c = 17.169(4) Å, V = 626.5 Å3, Z = 6; R = 0.0253. In this modification one half of the aluminum atoms are tetrahedrally coordinated [d(Al? S): 2.226–2.267 Å], whereas the other half are in trigonal bipyramidal coordination of five S atoms with bond lengths of 2.272–2.315 Å (equatorial) and 2.495–2.521 Å (axial). Aluminum in AlS5 coordination is observed for the first time in this compound. The crystal structure is isotypic to In2Se3 and AlInS3. In addition, results of a refinement of the α -Al2S3 crystal structure are reported which were obtained on crystals prepared also by chemical vapour transport with iodine. 相似文献
69.
A new method for the determination of trace cadmium in water samples by flame atomic absorption spectrometry (FAAS) after
cloud point extraction (CPE) is proposed. The method is based on the complexation of Cd with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone
(PMBP) in the presence of non-ionic micelles of Triton X-100. The effect of experimental conditions such as pH, concentration
of chelating agent and surfactant, equilibration temperature and time on cloud point extraction was studied. Under the optimum
conditions, the detection limits are 0.64 ng mL±1 with relative standard deviations (RSDs) of 2.1% (n = 10). The proposed method was applied to the determination of trace
cadmium in water samples with satisfactory results. 相似文献
70.
《中国化学快报》2020,31(6):1535-1539
Chlorinated organic pollutants(COPs) have caused serious contaminants in soil and groundwater,hence developing methods to remove these pollutants is necessary and urgent.By a simple hydrothermal method,we synthesized the bimetallic iron-nickel sulfide(FeNiS) particles which exhibited excellent catalytic property of COPs removal.FeNiS was chosen as the peroxydisulfate(PDS) activator to removal COPs including 4-chlorophenol(4-CP),1,4-dichlorophenol(1,4-DCP) and 2,4,6-trichlorophenol(2,4,6-TCP).The results show that FeNiS can efficiently activate PDS to produce sulfate radical(SO_4~(·-)) which plays major role in the oxidative dechlorination and degradation due to its strong oxidizing property and the ability of producing hydroxyl radicals(~·OH) in the alkaline condition.Meanwhile,the Cl-abscised from COPs during the dechlorination can turn into the chlorine radicals and enhance the degradation and cause further mineralization of intermediate products.This bimetallic FeNiS catalyst is a promising PDS activator for removal of chlorinated organics. 相似文献