全文获取类型
收费全文 | 493篇 |
免费 | 39篇 |
国内免费 | 131篇 |
专业分类
化学 | 566篇 |
晶体学 | 15篇 |
力学 | 2篇 |
综合类 | 1篇 |
物理学 | 79篇 |
出版年
2024年 | 3篇 |
2023年 | 3篇 |
2022年 | 5篇 |
2021年 | 9篇 |
2020年 | 7篇 |
2019年 | 12篇 |
2018年 | 7篇 |
2017年 | 12篇 |
2016年 | 11篇 |
2015年 | 12篇 |
2014年 | 27篇 |
2013年 | 55篇 |
2012年 | 36篇 |
2011年 | 23篇 |
2010年 | 18篇 |
2009年 | 19篇 |
2008年 | 32篇 |
2007年 | 34篇 |
2006年 | 44篇 |
2005年 | 28篇 |
2004年 | 29篇 |
2003年 | 27篇 |
2002年 | 28篇 |
2001年 | 16篇 |
2000年 | 20篇 |
1999年 | 15篇 |
1998年 | 18篇 |
1997年 | 17篇 |
1996年 | 15篇 |
1995年 | 8篇 |
1994年 | 16篇 |
1993年 | 11篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 1篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有663条查询结果,搜索用时 46 毫秒
71.
N. S. Mosyagin A. N. Petrov A. V. Titov 《International journal of quantum chemistry》2011,111(14):3793-3798
The dissociation energy, equilibrium internuclear distance, and spectroscopic constants for the 1Σ ground state of the Yb2 molecule are calculated. The relativistic effects are introduced through generalized relativistic effective core potentials with very high precision. The scalar relativistic coupled cluster method particularly well suited for closed‐shell van der Waals systems is used for the correlation treatment. Extensive generalized correlation basis sets were constructed and used. The relatively small corrections for high‐order cluster amplitudes and spin—orbit interactions are taken into account using smaller basis sets and the spin—orbit density functional theory. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
72.
Dr. Véronique Jubera Dr. Marie Chavoutier Dr. Alla Artemenko Dr. Philippe Veber Dr. Matias Velazquez Dr. Alain Garcia 《Chemphyschem》2011,12(7):1288-1293
Synthesized powders and grown single crystals of nominal compositions Li6Ln(BO3)3:Yb3+ (Ln=Y, Gd) were investigated by means of powder and single‐crystal X‐ray diffraction (XRD), as well as optical near‐IR spectroscopy in conjunction with electron paramagnetic resonance (EPR) spectroscopy. The appearance of two distinct zero‐phonon lines suggests the existence of two kinds of Yb3+ ions in the single crystals. The XRD results exclude the possibility of a phase transition occurring between room and low temperatures. EPR spectra of single crystals show the presence of both isolated ions and pairs of ytterbium ions substituted for Y3+. A strong temperature dependence of the intensity of Yb–Yb pairs resonance lines coincides with temperature dependence of emission peak at 978 nm, confirming a common origin of the defect giving rise to these spectra. Calculated from EPR spectra, the distance between pairs of Yb3+ is in good agreement with crystallographic ones: R=3.856 Å, Rcryst=3.849 Å. 相似文献
73.
I. V. Berezovskaya N. P. Efryushina A. S. Voloshinovskii G. B. Striganyuk P. V. Pir V. P. Dotsenko 《Journal of Applied Spectroscopy》2006,73(6):861-865
We have studied the luminescent properties of Eu2+/3+ and Yb2+ ions in strontium hexaborate SrB6O10 for excitation in the 120–400 nm region. The luminescence spectra of Ln2+ ions in SrB6O10 consist of overlapping bands in the 370–520 nm region, due to 5d → 4f transitions at several nonequivalent centers. In the
excitation spectra, besides the bands associated with 4f → 5d transitions in the Ln2+ ions, we also observe a band in the 135–160 nm region due to the transitions O(2p) → B(2s,2p) within the borate anions. The
luminescence of the Eu3+ ions is excited most efficiently in the region of the Eu3+ charge transfer band (λmax = 226 nm). The results obtained are compared with data for Ln in other strontium borates.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 6, pp. 770–774, November–December, 2006. 相似文献
74.
Quasi-CW diode-pumped Yb3+∶borate glass and Yb3+∶phosphate glass microchip lasers have been reported. From Yb3+∶phosphate glass laser, the maximum average output power was 31 mW and the optical-optical conversion efficiency was 5%.The maximum average output power was 18 mW, and optical-optical conversion efficiency was 3% for Yb3+∶borate glass laser. 相似文献
75.
76.
Najmedin AziziMohammad R. Saidi 《Tetrahedron》2003,59(28):5329-5332
A very mild, efficient and simple method for the synthesis of tertiary α-amino phosphonates is reported by reaction of an aldehyde, a secondary amine and trialkylphosphite in ethereal solution of lithium perchlorate, LPDE, at ambient temperature with high yields. 相似文献
77.
Guorong Duan Junwu Zhu Chun Kan Xujie Yang Lude Lu Xin Wang 《Reaction Kinetics and Catalysis Letters》2007,92(2):247-256
For the first time, novel structural nanosized Y2O3 powders were successfully synthesized by the n-butanol soft-template method. X-ray diffraction, transmission electron microscopy, scanning electron microscopy and Raman
spectroscopy were used to characterize the products. The results indicate that these products (calcined at 700°C) were comprised
of many Y2O3 nanomembranes, and the nanomembranes could change into nanorods when calcined at 1000°C. Interestingly, differential thermal
analysis studies suggested that the nanosized Y2O3 crystals had intense catalytic activity on the thermal decomposition of ammonium perchlorate. 相似文献
78.
Professor Vladimir V. Boldyrev has made numerous important contributions to a wide range of chemical topics, not only limited
to studies of the decompositions of solids. Of particular value has been his emphasis on exploring, in detail, the chemical
steps participating in the thermal reactions of solids by carefully designed experiments that rely on more observational evidence
than the run-of-the-mill collection of overall kinetic data. Some of these major contributions to both the theory and the
uses of solid-state reactions are identified here and discussed in relation to his illuminating and fundamental mechanistic
studies of the thermal decompositions of silver oxalate, ammonium perchlorate, potassium permanganate and the dehydration
of copper sulfate pentahydrate. 相似文献
79.
Ali Jinnah MM Sasirekha V Ramakrishnan V 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(4-5):840-844
Infrared and Raman spectra of L-citrullinium perchlorate crystals have been recorded at room temperature. The vibrational assignments of the observed wavenumbers are proposed on the basis of group theoretical analysis. The presence of carbonyl group indicates that the molecule exists in the ionic form. The shifting of stretching and bending wavenumbers indicates the presence of extensive hydrogen bonding in the crystal. The anion fundamentals however continue to be degenerated. This suggests that its symmetry is not affected in the crystal. 相似文献
80.
1INTRODUCTIONInterestinpolynuclearcomplexesisstimulatedbytherolestheyplayindifferentfields,e.g.heterogeneouscatalysis,bioinorganicchemistryandthedesignofmagneticmaterials.Since1985ill,considerableattentionshavebeengiventomolecularcomplexest'isimultaneouslycomprisingdandfmetalionsduetotheirspecialmagneticproperties.Coupledpolyr^uclearsystemscontaining3delementshavebeenextensivelyinvestigatedL,3,butonlyafew,derivedfromcarboxylatesL4--63,thatcontainbothtransitionandrare--earthmetalionshavebe… 相似文献