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41.
H. Schumann F. H. Grlitz F. E. Hahn J. Pickardt Changtao Qian Zuowei Xie 《无机化学与普通化学杂志》1992,609(3):131-138
The partial hydrolysis of [O(CH2CH2C5H4)2]Y(C5H4CH3) 1 , [O(CH2CH2C5H4)2]Y(C5H5) 3 , and [O(CH2CH2C5H4)2]Ho(C5H4CH3) 5 results in the formation of [O(CH2CH2CH2C5H4)2Y(μ-OH)2]2 2 , (C5H5)3Y(OH2) 9 and (MeC5H4)3Ho(OH2) 11 . The new compounds have been characterized by elemental analyses, IR and NMR spectra. The X-ray structural analyses shows 2 to be monoclinic, space group P21/n with a = 1146.0(3), b= 1046.6(3), c = 1514.9(3) pm, β = 94.83(2)°. The molecular structure shows bridging hydroxyl groups with a mean distance Y? O = 223.8(3) pm. 11 crystallizes in the cubic space group 14 3d with a = 1847.9(3)pm with Z = 16 molecules per unit cell. The molecules posses symmetry C3-3, the coordination is trigonal pyramidal with three methylcyclopentadienyl anions and one water molecule as ligands. The distance Ho? O is 231 pm. 相似文献
42.
Debprasad Patra Poulami Pattanayak Jahar Lal Pratihar Surajit Chattopadhyay 《Polyhedron》2007,26(18):5484-5490
The reactions of HL 1 [where HL is 1N-(2-pyridyl-2-methyl)-2-arylazoaniline and is formulated as ArN = NC6H4N(H)(CH2C5H4N); Ar = C6H5 (for HL1) or p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)] with K2PtCl4 and Co(ClO4)3 · 6H2O afforded the (L)PtCl and [(L)2Co]ClO4 complexes, respectively. The HL ligands bind the platinum(II) and cobalt(III) centres in a tridentate (N,N,N) fashion, forming new diazoketiminato chelates upon dissociating the amino proton. The X-ray structures of (L3)PtCl and [(L3)2Co]ClO4 were determined. Redox properties of the new complexes have been examined. 相似文献
43.
稀土高氯酸盐开环冠醚三缩乙二醇(EO_3)[La(C_6H_(14)O_4)_3(H_2O)](ClO_4)_3·H_2O,单斜晶系,P2_1/c空间群。晶胞参数为:a=15.474(2),b=11.386(1),c=20.841(4),β=99.82(1)°,V=3618(1),MoKα,Z=4,D_c=1.718g/cm3,μ=1.499mm ̄(-1)。全矩阵最小二乘精细修正,结构因子R=0.056,R_w=0.083。中心原子La与开环冠醚醚链上的O(1)~O(9)及一个水分子形成10配位双帽四方反棱柱结构。弱配体高氯酸根不参加配位。 相似文献
44.
45.
Solvation interaction and ion association in solutions of lithium perchlorate/4-methoxymethyl-ethylene carbonate (MEC) have been studied by using Infrared and Raman spectra as a function of concentration of lithium perchlorate. The splitting of ring deformation band and ring ether asymmetric stretching band, and the change of carbonyl stretching band suggest that there should be a strong interaction between Li^+ and the solvent molecules, and the site of solvation should be the oxygen atom of carbonyl group. The apparent solvation number of Li^+ was calculated by using band fitting technique. The solvation number was decreased from 3.3 to 1.1 with increasing the concentration of LiClO4/MEC solutions. On the other hand, the band fitting for the ClO4^- band revealed the presence of contact ion pair, and free ClO4^- anion in the concentrated solutions. 相似文献
46.
用T-jump/FTIR研究MnCP、NiCP和PbCP的快速热分解(英) 总被引:1,自引:0,他引:1
0IntroductionCarbohydrazideisahydrazinederivativewithwhitecrystalofstrongreducingbehaviors.Becauseithasmanycoordinationatoms(fournitrogenatomsandoneoxygenatom),carbohydrazidecan,therefore,beusedasmultidentateligand.Itscoordinationcom鄄poundiswidelyusedint… 相似文献
47.
用过渡金属络合催化剂聚合环氧氯丙烷能获高分子量的聚合物。稀土络合催化剂对环氧乙烷,环氧丙烷及环硫丙烷的开环聚合具有明显效果。本文选用Y(acac)_3-H_2O-Al(i-Bu)_3催化剂,考察环氧氯丙烷的均聚合及其与环氧乙烷,环氧丙烷的共聚合,并用核 相似文献
48.
Studyofthegrowthprocessofcolloidalparticlesofnonequilibriumandirreversibilityisanactiveareaofresearch.Therecognitionofcolloidalaggregatesasfractalobjectshasinspiredalargenumberofexperimentalandtheoreticalstudiesonthestructuralandkineticaspectsofaggregationprocesses"'.Morerecently,kineticsofhematiteaggregationbypolyacrylicacidhavebeenstudiedbyzhangandBume3.Theprimaryhematiteparticleswerequiteuniformandfairlyspherical.Inthispaper,wewillreportthesizeevolutionoffractalaggregatesofinitiallypolydis… 相似文献
49.
Crystalline [Y(OH2)3(NCMe)(benzo-15-crown-5)][ClO4]3·benzo-15-crown-5-CH3CN can be obtained by slowly cooling a reaction mixture of Y(ClO4)3·n H2O with benzo-15-crown-5 in a solution of acetonitrile and methanol (3 : 1) from 60°C to room temperature. The crystal structure of this complex has been determined at –150 and 20°C. The complex is triclinic,P
. At –150°C the cell parameters area = 11.986(4),b = 12.071(7),c = 16.364(5) Å, = 93.56(3), = 98.68(3), = 109.68(4)°, vol = 2187 Å3, andD
calc = 1.61 g cm–3 forZ = 2 formula units. 3633 independently observed [F
o 5(F
o)] reflections were used in the final least-squares refinement leading to an agreement index ofR = 0.048. The Y(III) ion coordination geometry approximates a tricapped trigonal prism with three water molecules and three benzo-15-crown-5 oxygen atoms forming the prism, with the two remaining benzo-15-crown-5 oxygen atoms and the acetonitrile molecule completing the coordination as capping atoms. The three water molecules hydrogen bond a second crown ether molecule and two of the perchlorate anions. The two acetonitrile molecules have contacts with perchlorate oxygen atoms close enough for some weak interaction. One perchlorate is ordered, one is partially disordered as is the coordinated solvent molecule, and the third anion is totally disordered. The two unique crown ether molecules have distinctively different conformations.For Part 20, see reference [1]. 相似文献
50.
Bengi Yilmaz 《光谱学快报》2014,47(1):24-29
In this study, nano hydroxyapatite doped with yttrium (2.5, 5, and 7.5 mol%) and fluoride (2.5 mol%) ions were synthesized by precipitation method and sintered at 900°C, 1100°C, and 1300°C. Raman spectroscopy was applied to track the structural modifications in pure and doped hydroxyapatites. The results showed that the main characteristic band of pure hydroxyapatite at 963 cm?1 was not affected significantly by ion doping but exhibited higher intensity with increasing sintering temperature. Due to fluoride substitution, the 1048 and 1034 cm?1 bands of pure hydroxyapatites appeared with a wavenumber shift in the spectra of ion-doped hydroxyapatites. The 333 cm?1 band of pure hydroxyapatite disappeared and an additional calcium–fluor bond at 322 cm?1 was observable in ion-doped hydroxyapatites. Two fluorescence bands at 770 and 697 cm?1, which were also observed in the spectra of pure hydroxyapatites, shifted to higher wavenumbers in the spectra of ion-doped hydroxyapatites. This was considered to result from the perturbation in the hexagonal structure of hydroxyapatite due to yttrium and fluoride codoping. 相似文献