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991.
992.
Aryl substituted α-carbonyl bromo-alkynes undergo facile cyclizations to the corresponding substituted 4-methylene-tetrahydrofurans using indium(I) iodide in acetonitrile under sonication in high yields. The reaction is predicted to proceed via a radical process initiated by InI and a plausible radical pathway is suggested. 相似文献
993.
994.
Chongjun Zhao Quanzhong Zhao Qitao Zhao Jianrong Qiu Congshan Zhu 《Applied Surface Science》2006,252(20):7415-7421
Au nanoparticles, which were photoreduced by a Nd:YAG laser in HAuCl4 solution containing TiO2 colloid and accompanied by the TiO2 particles, were deposited on the substrate surface. The film consisting of Au/TiO2 particles was characterized by the absorption spectra, scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. The adhesion between the film and substrate was evaluated by using adhesive tape test. It was found that the presence of TiO2 dramatically enhanced the adhesion strength between the film and the substrate, as well as the deposition rate of film. The mechanism for the deposition of Au/TiO2 film was also discussed. 相似文献
995.
Martin Skutella 《Mathematical Programming》2002,91(3):493-514
In the single source unsplittable min-cost flow problem, commodities must be routed simultaneously from a common source vertex
to certain destination vertices in a given graph with edge capacities and costs; the demand of each commodity must be routed
along a single path so that the total flow through any edge is at most its capacity. Moreover, the total cost must not exceed
a given budget. This problem has been introduced by Kleinberg [7] and generalizes several NP-complete problems from various
areas in combinatorial optimization such as packing, partitioning, scheduling, load balancing, and virtual-circuit routing.
Kolliopoulos and Stein [9] and Dinitz, Garg, and Goemans [4] developed algorithms improving the first approximation results
of Kleinberg for the problem of minimizing the violation of edge capacities and for other variants. However, known techniques
do not seem to be capable of providing solutions without also violating the cost constraint. We give the first approximation
results with hard cost constraints. Moreover, all our results dominate the best known bicriteria approximations. Finally,
we provide results on the hardness of approximation for several variants of the problem.
Received: August 23, 2000 / Accepted: April 20, 2001?Published online October 2, 2001 相似文献
996.
J. -P. Kauthen 《Numerische Mathematik》1989,56(5):409-424
Summary Integral equations of mixed Volterra-Fredholm type arise in various physical and biological problems. In the present paper we study continuous time collocation, time discretization and their global and discrete convergence properties. 相似文献
997.
Summary The optimality question for blockp-cyclic SOR iterations discussed in Young and Varga is answered under natural conditions on the spectrum of the block Jacobi matrix. In particular, it is shown that repartitioning a blockp-cyclic matrix into a blockq-cyclic form,q
, results in asymptotically faster SOR convergence for the same amount of work per iteration. As a consequence block 2-cyclic SOR is optimal under these conditions.Research supported in part by the US Air Force under Grant no. AFOSR-88-0285 and the National Science Foundation under grant no. DMS-85-21154 Present address: Boeing Computer Services, P.O. Box 24346, MS 7L-21, Seattle, WA 98124-0346, USA 相似文献
998.
The collision-generated hybridization which has been found responsible for the on-site mixing of the atomic-likef-state and the band-liked states in mixed valence solids has been studied for the cerium solid. A practical expression which depends on the lattice
constant and temperature has been obtained for the collision-generated hybridization. Numerical calculations show that the
valence varies continuously with lattice constant and that temperature makes the transition smoother. The collision-generated
hybridization is found to be of significant strength in the intermediate valence regime; but over a wide range of the valence
near 3.5 it varies rather slowly without preferring a particular valence. Factors which can assist the collision-generated
hybridization in stabilizing the mixed valence phase at a particular lattice constant are discussed. 相似文献
999.
CuX(X=Al, Ga, In)分子的势能函数与稳定性的密度泛函研究 总被引:5,自引:3,他引:2
刘风丽 《原子与分子物理学报》2006,23(5):838-842
根据原子分子反应静力学原理导出了CuX(X=Al,Ga,In) 分子基态电子状态及其离解极限,并在B3LYP/LANL2DZ水平上计算了平衡几何、振动频率和解离能.利用Murrell-Sorbie 函数拟合出了解析势能函数,并计算出光谱参数和力常数.计算结果表明该分子体系是稳定存在的,其稳定性排序为 CuAl>CuGa>CuIn. 相似文献
1000.
利用瞬态受激旋转拉曼散射(SRRS)模型及相位畸变模型,对具有空间相位畸变的强紫外激光束在空气中长程传输的SRRS效应进行了研究。详细讨论了低频和中高频空间相位畸变对SRRS阈值条件、斯托克斯光转换效率、剩余泵浦光和斯托克斯光相位的影响。研究结果表明,泵浦光的初始相位畸变对斯托克斯光相位畸变的影响较剩余泵浦光的更为明显;高频相位畸变对转换效率影响较低频相位畸变更大; SRRS效应阈值随低频相位畸变的增大而减小,随高频相位畸变的增大而增大。 相似文献