全文获取类型
收费全文 | 398篇 |
免费 | 36篇 |
国内免费 | 33篇 |
专业分类
化学 | 342篇 |
晶体学 | 7篇 |
力学 | 2篇 |
综合类 | 4篇 |
数学 | 9篇 |
物理学 | 103篇 |
出版年
2023年 | 2篇 |
2022年 | 17篇 |
2021年 | 11篇 |
2020年 | 12篇 |
2019年 | 12篇 |
2018年 | 7篇 |
2017年 | 18篇 |
2016年 | 12篇 |
2015年 | 10篇 |
2014年 | 17篇 |
2013年 | 30篇 |
2012年 | 17篇 |
2011年 | 25篇 |
2010年 | 13篇 |
2009年 | 19篇 |
2008年 | 25篇 |
2007年 | 25篇 |
2006年 | 15篇 |
2005年 | 14篇 |
2004年 | 17篇 |
2003年 | 10篇 |
2002年 | 17篇 |
2001年 | 14篇 |
2000年 | 12篇 |
1999年 | 15篇 |
1998年 | 9篇 |
1997年 | 19篇 |
1996年 | 10篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有467条查询结果,搜索用时 531 毫秒
51.
The 1H and 13C NMR spectra of methaqualone, 1, have been extensively studied using one and two-dimensional techniques. These 300 MHz 1H and 75 MHz 13C studies have allowed rigorous assignments to be made for the methyl groups and the quinazolinone nucleus. The 60 MHz 1H spectra for 1 in CDCl3 have been examined with 相似文献
52.
53.
光束的空间相干性与空间质量评价 总被引:3,自引:2,他引:1
光束空间质量评价的标准应该能够反映光束的空间相干性和强度(功率或能量)分布,并主要由空间相干性的优劣来说明.本文对模式纯度(1-δ)以及空间质量评价因子-衍射极限倍数因子M2做了讨论,并对此因子的表达形式提出了我们的改进建议. 相似文献
54.
T. Idehara N. Nishida K. Yoshida I. Ogawa T. Tatsukawa D. Wagner G. Gantenbein W. Kasparek M. Thumm 《International Journal of Infrared and Millimeter Waves》1998,19(7):919-930
The cavity of the newest gyrotron, Gyrotron FU IVA in the high frequency series of Fukui University gyrotrons (the Gyrotron FU series) is designed to minimize the mode conversion from the main cavity mode to the higher modes. In this paper, the experimental results are compared with simulations for the complete gyrotron oscillator. The gyrotron has an additional advantage to cover the wide frequency range in submillimeter wave region. 相似文献
55.
醋酸甲羟孕酮与β-环糊精包络作用的光谱研究及应用 总被引:1,自引:0,他引:1
用紫外吸收、荧光光谱法对水溶液中β-环糊精(β-CD)与醋酸甲羟孕酮(MA)主客体包络物的光谱行为进行了研究.利用改进的Benesi-Hildebrand法测定了包络物的形成常数,初步探讨了某些水溶性一元醇的引入对该包络物形成及荧光性质的影响,并提出了测定MA的高灵敏度荧光光度新方法,方法的最低检出限为8.9×10-9mol·L-1.用该法测定样品中MA的结果令人满意,回收率为97.9%~101.7%,平均回收率为99.9%(n=5) 相似文献
56.
57.
B. Joseph 《Journal of Thermal Analysis and Calorimetry》1993,40(3):1447-1450
The Laboratory of the Government Chemist (LGC) is a focal point for the production, analysis and certification of reference materials. Within the field of thermal analysis the LGC is concerned with the development of purity standards and materials certified for enthalpy of fusion and melting point. For some time the LGC has been concerned with the significant differences in purity data which can be produced by the different manufactures' differential scanning calorimeters. This paper will highlight the initiatives the LGC is undertaking in overcoming this uncertainty in purity measurements through the use of certified thermal standards. 相似文献
58.
采用固态反应法制备了Gd3PO7:Eu3+ 和 La3PO7:Eu3+发光材料,通过X射线衍射和SEM确定了样品的结构和形貌。 在真空紫外光的激发下,Gd3PO7:Eu3+样品展示了较弱的基质吸收;但在紫外光的激发下,Gd3PO7:Eu3+显示了比La3PO7:Eu3+更强的红光发射,其原因是在Gd3PO7:Eu3+中存在Gd3+到Eu3+的有效能量传递过程。两个样品的发射光谱峰值位于618 nm,属于Eu3+的5D0→7F2跃迁。Eu3+在材料中处于较低的格位对称环境,具有很好的色纯度。 相似文献
59.
Annealing of radiation induced defects in p-type germanium was studied by measuring Hall coefficient and conductivity. The dopant was gallium or indium. It was concluded that the annealing stage between 80° and 140°K is caused by migration of the vacancy to the sink of an impurity atom. In this stage the vacancy migrates to a substitutional impurity atom and makes an association. The activation energy of the stage was found tO be 0.1 ev ad it is regarded to be that of the vacancy migration. The model for the annealing stage which occurs in the range 220 to 270°K is proposed as follows: An interstitial impurity atom migrates to a substitutional impurity atom and makes an association. From the activation energy of the stage, the migration energy of the interstitial impurity atom was concluded to be about 0.4 eV for gallium and 0.7 eV for indium atoms. 相似文献
60.
The 60 MHz 1H NMR spectra of racemic 5-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]-4-thiazolidinone, 1, have been studied in CDCl3 solution at 28° with the achiral lanthanide shift reagent (LSR), tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium (III), 2, and the chiral LSRs, tris[3-(heptafluoropropylhydroxymethylene)- (+)-camphoratojeuropium(III), 3, and tris[3-(trifluoromethylhydroxymethylene-(+) -camphorato]europium (III), 4, Significant enantiomeric shift differences were observed in the presence of added 3, for the aryl protons of 1 that should permit direct determination of enantiomeric excess. Relative magnitudes of lanthanide-induced shift for the different nuclei of 1 with the three LSRs are compared and discussed in terms of preferred LSR binding sites. A favored conformation of 1 with respect to rotation about the C(5)-CH2 bond is suggested. 相似文献