多维谱的简化探测

提出一种利用谱编辑的方法来简化二维谱的探测,使得一张二维谱可以被简化为N条一维谱(N等于二维谱中F1维上的谱线总数),从而达到缩短数据采集时间和减少数据贮存空间的目的。文中给出了运用此方法探测二维碳氢异核相关实验的实例,并分析了由于F1维的谱线不为δ函数而产生的编辑误差的大小,最后将此方法推广到三维的简化探测,即通过对N张二维谱的编辑获得三维谱的信息。     

Indirect conductimetric detection of nonelectrolytes in microcolumn liquid chromatography

Summary Indirect conductimetric detection of nonelectrolytes was investigated in microcolumn liquid chromatography. The mobile phase contained an electrolytic substance which maintained a high background and analytes were indirectly detected owing to a depression of the background signal. The dynamic reserve, defined as the ratio of the background to its noise level, was 9.3×10⁴, and the detection limits at S/N=3 were 10–32 ng for alcohols examined.     

Reconstruction of signals from multiscale edges

We present a method for signal reconstruction based upon the location of its singularities which are identified by a wavelet transform technique. The reconstructed signal is an infconvolution spline approximant. The data for the interpolation problem which we solve comes from a compact signal coding procedure. Error bounds and convergence results for the calculated signal are given.     

On-line detection of emulsion polymerization by solid-state NMR spectroscopy

 The on-line detection of emulsion polymerization processes by means of solid-state NMR spectroscopy is demonstrated for the first time using poly(butyl acrylate) as a model system. Relatively short time intervals are accessible via ¹H detection while the use of ¹³C NMR spectroscopy results in an increased spectral resolution. Details of sample preparation and experimental techniques are given, while remaining artifacts of the preliminary results will be addressed in further investigations. Received: 7 November 1997 Accepted: 5 January 1998     

利用几何特性及神经网络进行人脸探测技术的研究

在人脸识别过程中 ,首先也是最重要的一个环节是人脸探测 ,因为一旦从图像中定位并提取到了人脸 ,那么下一步的人脸识别工作就变得非常容易。眼睛是人脸图像中最容易探测的部位 ,而且通过探测双眼来发现人脸最符合人的视觉习惯。提出了一种基于几何特征分析和人工神经网络的由粗到细的两级人脸探测方法。在第一级中 ,眼睛和脸是通过测量眼睛的尺寸和眼睛与脸的位置关系探测到的 ,第一级的输出是一个尺寸归一化的人脸 ,但偶尔也伴随着一个或多个因对复杂背景中与眼睛类似的物体的误判而得到的非人脸图像 ;第二级神经网络正是用来过滤掉第一级中被误判的人脸。实验表明 ,这种由粗到细的两级人脸探测系统具有很高的稳定性和探测正确率     

一种新的自动调焦方法—离轴探测法

本文提出了的种新的自动调焦方法——离轴探测法,此法没用任何附加元件,结构简单、装调容易、线性度好、灵敏度高、调焦范围大、实用性强;介绍了此法的原理、理论计算结果及实验结果;给出了应用实例.     

一种改进的基于小波变换的图像边缘提取算法

在对现有的基于小波变换的图像边缘提取方法进行简要分析的基础上,提出了图像边缘提取改进算法.该算法主要是对边缘点的判断准则进行了改进,通过将任一点的梯度方向与水平、垂直、45°、135°方向进行比较,将这4个方向中与该点梯度方向最接近的一个方向重新赋给该点的梯度方向,并检验二进小波变换的模在该点是否为新的梯度方向上的局部极大值,若是,该点就是边缘点,否则不是.最后通过模拟实验给出了该方法的实验结果,实验结果有力地证明了该方法的有效性.     

Capillary electrophoresis with direct chemiluminescence detection for the analysis of catecholamines in human urine

A rapid and sensitive method for the analysis of three catecholamines by capillary electrophoresis(CE)with directchemiluminescence(CL)detection is described.The detection limits(S/N=3)were 1.3*10-8g/mL for isoprenaline,1.0*10-8g/mL for epinephrine and 2.8*10-8g/mL for dopamine.The proposed method was successfully applied to theanalysis of catecholamines in urine samples of cigarette smokers and nonsmokers.The results showed that there is a close relationbetween the release of dopamine in human body fluids and cigarette smoking/nonsmoking.     

Sub-millimolar determination of formalin by pulsed amperometric detection

Formalin, formaldehyde in the presence of methanol, was determined by pulsed amperometric detection (PAD). A triple waveform using E_det=−0.3 V (t_det=30 ms), E_oxd=+0.8 V (t_oxd=200 ms), and E_red=−0.8 V (t_red=350 ms) versus Ag/AgCl was applied at a Au electrode for detection in a flow injection (FI) system. The approach was rapid and yielded a sub-millimolar detection limit (0.0129 mM) with a dynamic range up to 100 mM. A precision of 8.8% R.S.D. at 1.0 mM for two hundred repetitive injections by the FI-PAD was obtained, whereas holding at a constant potential (−0.3 V versus Ag/AgCl) for anodic oxidation of formaldehyde caused the response to decrease dramatically after a few measurements. The method developed was used to analyze the formalin contents of water from rinsed samples of vegetables and fruit and ice-melt from seafood, and the method showed good agreement with the liquid chromatography (LC) method.     

紫外线的应用、探测及其新发展

紫外辐射在电磁辐射波谱中的波长范围为４００～１０ｎｍ。随着波长的变化，紫外线具有各种不同的物理特性和效应。本文概述了各种紫外线效应及其应用，尤其指出了它在军事应用方面的新发展及其广阔前景，例如：紫外线制导，紫外线告警，紫外线通讯和干扰等。上述应用得到了广泛的重视和迅猛的发展。紫外技术的应用与探测技术有关。本文指出了紫外探测的三种方法：紫外荧光转换法，分光光度法和卫星遥感法。并着重指出了上述应用中需解决的有关探测技术方面的关键问题：紫外大气传输理论和散射模型及其仿真系统，新型高灵敏度低噪声紫外探测器，低噪声信息处理系统，高性能紫外光源和紫外光学系统。