Surface Nucleation Kinetics on Active Centers from Supersaturated Vapor

The formation of nuclei from a supersaturated vapor on a surface with active centers is treated within standard self-consistent classical model with exhaustion of active centers. Basic characteristics of nucleation process (total number of nuclei, nucleation rate, time lag and size distribution of nuclei) are determined by numerical solution of kinetic equations. It is shown that standard approach to nucleation on active centers based on Avrami model coincides with our approach in the values of time lag of nucleation process, but it differs in the total number of nuclei.     

Crystallization of poly(butylene adipate) in the presence of nucleating agents

The effect of nucleating agents on the polymorphic crystallization behavior of poly(butylene adipate) (PBA) was studied with four kinds of commercially available nucleating agents, such as talc and boron nitride. The crystal structures of the α and β forms were studied with wide‐angle X‐ray diffraction. The β‐to‐α‐crystal transformation of PBA in the absence and presence of the nucleating agents in isothermal crystallization and nonisothermal crystallization processes was studied with differential scanning calorimetry and polarized optical microscopy. In both isothermal and nonisothermal crystallization, the introduction of nucleating agents selectively initiated the nucleation of the α‐form crystal, which was relatively slow in the absence of nucleating agents. The nucleating activity of the four kinds of nucleating agents in the crystallization of the PBA α‐form crystal was determined by the study of the nonisothermal crystallization, spherulite morphology, and isothermal kinetics. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2340–2351, 2005     

Intensified and controllable vaporization of phase-changeable nanodroplets induced by simultaneous exposure of laser and ultrasound

Phase-changeable contrast agents have been proposed as a next-generation ultrasound contrast agent over conventional microbubbles given its stability, longer circulation time and ability to extravasate. Safe vaporization of nanodroplets (NDs) plays an essential role in the practical translation of ND applications in industry and medical therapy. In particular, the exposure parameters for initializing phase change as well as the site of phase change are concerned to be controlled. Compared to the traditional optical vaporization or acoustic droplet vaporization, this study exhibited the potential of using simultaneous, single burst laser and ultrasound incidence as a means of activating phase change of NDs to generate cavitation nuclei with reduced fluence and sound pressure. A theoretical model considering the laser heating, vapor cavity nucleation and growth was established, where qualitative agreement with experiment findings were found in terms of the trend of combined exposure parameters in order to achieve the same level of vaporization outcome. The results indicate that using single burst laser pulse and 10-cycle ultrasound might be sufficient to lower the exposure levels under FDA limit for laser skin exposure and ultrasound imaging. The combination of laser and ultrasound also provides temporal and spatial control of ND vaporization and cavitation nucleation without altering the sound field, which is beneficial for further safe and effective applications of phase-changeable NDs in medical, environmental, food processing and other industrial areas.     

激光散射,透射消光方法应用于测量同质核化率的实验研究

应用激光散射方法和透射消光方法，对戊醇在２５０Ｋ、１．０ｂａｒ状态附近同质核化凝结过程中微滴浓度和尺度进行了测算，并根据脉冲成核时间长短确定了戊醇同质核化率大小。实验结果表明：戊醇在携带气体—氦气中，在２５０Ｋ、１．０ｂａｒ附近的同质核化率范围为１．６０３×１０１５～６．６４５×１０１５ｍ－３ｓ－１，相应的饱和比范围为１３．０４～２０．７６。     

Cavity nucleation, growth and stress field in elastic-plastic medium

A finite element method is used to study the cavity nucleation and growth in an elastic-plastic medium. The critical cohesion strength, _c at IPM (interface between second phase particle and matrix) is employed as the criterion of cavity formation. Three different values of _c are taken to examine their influence on the overall mechanical behaviour and process of cavity formation.     

How a Zigzag Carbon Nanotube Grows

Owing to the unique structure of zigzag (ZZ) carbon nanotubes (CNTs), their ring‐by‐ring growth behavior is different from that of chiral or armchair (AC) CNTs, on the rims of which kinks serve as active sites for carbon attachment. Through first‐principle calculations, we found that, because of the high energy barrier of initiating a new carbon ring at the rim of a ZZ CNT, the growth rate of a ZZ CNT is proportional to its diameter and significantly (10–1000 times) slower than that of other CNTs. This study successfully explained the broad experimental observation of the lacking of ZZ CNTs in CNT samples and completed the theory of CNT growth.     

大颗粒磷钼酸铵:制备与结晶动力学(英文)

通过缓慢滴加焦磷酸钾的硝酸溶液到钼酸铵溶液中制得了大颗粒磷钼酸铵(AMP)。研究了AMP的成核速率(G)与晶体生长速率。与晶体生长速率相比成核速率的反应级数更高。最初,大颗粒磷钼酸铵的结晶过程处于相变反应控制的动力学区域,此时溶液的过饱和生成速率比过饱和消除速率高。晶体线生长速率与溶液的过饱和度先增加后降低。在滴加中期,过饱和消除速率增长到与其生成速率相当。在滴加后期,晶体成核速率快速增高,而晶体的线生长速率下降。晶体的成核速率成为过饱和消除的唯一控制步骤。因此,AMP成核大部分是在首先接触到滴加液的局部溶液中完成的。     

异相成核和拉伸诱导对生物基PHBV复合纤维结晶结构与力学性能的影响

采用熔融纺丝法制备了聚(3-羟基丁酸酯-co-3-羟基戊酸酯)(PHBV)/二硫化钨(WS_2)复合纤维.利用示差扫描量热仪(DSC)、热台偏光显微镜、二维广角射线衍射仪(2D-WXRD)、纤维强力仪研究了WS_2异相成核作用和牵伸诱导作用对纤维的结晶结构和力学性能的影响.研究表明,WS_2显著提高了PHBV的结晶温度,当使用2 wt%WS_2时,复合材料的结晶温度提高到115~130oC,比纯PHBV(99~105oC)提高了约25oC.WS_2不仅没有影响PHBV球晶的径向生长速率,且明显提高了PHBV/WS_2复合材料的晶核密度,熔体成核活性Φ由1.0降低为0.49.随着牵伸倍率和WS_2用量的增加,纤维的拉伸强度呈现出先增加后减小的趋势.当添加1 wt%WS_2并采用单向牵伸3.8倍时,纤维中的晶体取向产生了β晶结构,使复合纤维的拉伸强度由纯PHBV的37 MPa提高至155 MPa,断裂伸长率由2.4%增加至45%.     

Micromechanics of cleavage fracture initiation in ferritic steels by carbide cracking

Cleavage fracture in ferritic steels is often initiated in brittle carbides randomly distributed in the material. The carbides break as a result of a fibre loading mechanism in which the stress levels in the carbides are raised, as the surrounding ferrite undergoes plastic deformation. The conditions in the vicinity of the nucleated micro-crack will then determine whether the crack will penetrate or be arrested by the ferrite. The ferrite is able to arrest nucleated cracks through the presence of mobile dislocations, which blunt and shield the microcrack and thus lowers the stresses at the crack tip. Hence, the macroscopic toughness of the material directly depends on the ability of the ferrite to arrest nucleated micro-cracks and in turn on the plastic rate sensitivity of the ferrite. The initiation of cleavage fracture is here modelled explicitly in the form of a micro-crack, which nucleates in a brittle carbide and propagates into the surrounding ferrite. The carbide is modelled as an elastic cylinder or in a few cases an elastic sphere and the ferrite as an elastic viscoplastic material. The crack growth is modelled using a cohesive surface, where the tractions are governed by a modified exponential cohesive law. It is shown that the critical stress, required to propagate a microcrack from a broken carbide, increases with decreasing plastic rate sensitivity of the ferrite. The results also show that a low stress triaxiality and a high aspect ratio of the carbide promote the initiation of cleavage fracture from a broken carbide.     

Numerical modeling of the formation of aerosol particles in jet engine plumes

The formation of liquid sulfate aerosols in the isobaric axisymmetric plume of a subsonic aircraft is modeled numerically. The specific features of the appearance and evolution of sulfate aerosols attributable to 2D effects, such as the parameter nonuniformity in the initial section (at the nozzle outlet), mixing of the hot engine jet with the cold air stream, and the transverse turbulent diffusion of aerosol particles and gas mixture components. The equations of gas dynamics for a turbulent axisymmetric jet, the equations of chemical kinetics, the equations for the liquid fractions (water and sulfuric acid), and the relations for the binary nucleation, condensation growth and coagulation of aerosol particles are used. The distributions of the parameters determining the formation of the aerosol phase in the exhaust plume of a B-747 aircraft are obtained and the geometry of the nucleation zone in this plume is determined.