全文获取类型
收费全文 | 6977篇 |
免费 | 891篇 |
国内免费 | 500篇 |
专业分类
化学 | 3498篇 |
晶体学 | 122篇 |
力学 | 367篇 |
综合类 | 42篇 |
数学 | 617篇 |
物理学 | 3722篇 |
出版年
2024年 | 8篇 |
2023年 | 57篇 |
2022年 | 138篇 |
2021年 | 166篇 |
2020年 | 156篇 |
2019年 | 234篇 |
2018年 | 238篇 |
2017年 | 346篇 |
2016年 | 329篇 |
2015年 | 334篇 |
2014年 | 408篇 |
2013年 | 711篇 |
2012年 | 469篇 |
2011年 | 451篇 |
2010年 | 361篇 |
2009年 | 421篇 |
2008年 | 401篇 |
2007年 | 413篇 |
2006年 | 379篇 |
2005年 | 295篇 |
2004年 | 273篇 |
2003年 | 233篇 |
2002年 | 229篇 |
2001年 | 202篇 |
2000年 | 180篇 |
1999年 | 164篇 |
1998年 | 119篇 |
1997年 | 112篇 |
1996年 | 64篇 |
1995年 | 64篇 |
1994年 | 57篇 |
1993年 | 57篇 |
1992年 | 40篇 |
1991年 | 24篇 |
1990年 | 22篇 |
1989年 | 24篇 |
1988年 | 74篇 |
1987年 | 20篇 |
1986年 | 12篇 |
1985年 | 20篇 |
1984年 | 12篇 |
1983年 | 4篇 |
1982年 | 9篇 |
1981年 | 14篇 |
1980年 | 10篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有8368条查询结果,搜索用时 281 毫秒
71.
太赫兹半导体探测器研究进展 总被引:4,自引:0,他引:4
太赫兹(THz)探测器是THz技术应用的关键器件之一.基于半导体的全固态THz量子阱探测器(THzQWIP)具有探测响应速度快、制作工艺成熟、体积小和易集成等优点.文章简要介绍了THz探测器的分类和特点,重点介绍了THzQWIP的工作原理和研究进展. 相似文献
72.
A. Ducrot 《Mathematical Methods in the Applied Sciences》2007,30(3):291-304
This paper is devoted to the study of multi‐dimensional travelling wave solution for a thermo‐diffusive model, describing the propagation of curved flames in an infinite cylinder. The linear dependence of the components of the reaction rate together with the existence of an ignition temperature ensure that the corresponding linearized operator does not satisfy the Fredholm property. A direct consequence is that solvability conditions for the linearized operator are not known and classical methods of nonlinear analysis cannot be directly applied. We prove in this paper existence results of such travelling waves, by first introducing a suitable re‐formulation of the equations and then by choosing suitable weighted spaces that allows us to move the essential spectrum away from zero. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
73.
Najate Bensari-zizi Claude Alamichel 《International Journal of Infrared and Millimeter Waves》1989,10(1):137-151
About 2500 lines of CH3
35Cl have been assigned. The strong xy Coriolis resonance between thev
2 andv
5 modes is quite visible between thev
4+v
4
±1
perpendicular band, centered around 4383 cm–1, and thev
4
±1
+v
5
±1
perpendicular component, centered around 4475 cm–1, with a crossing of upper energy levels allowing the observation of lines which are normally forbidden. Although not yet observed with certainty, because of the great density of lines of the spectrum, thev
4
1
+v
5
±1
parallel component is nevertheless detectable by its effects onv
2+v
4
±1
which is linked by Coriolis resonance to both components ofv
4+v
5. Moreover the spectrum is much complicated by many other resonances with weak bands which occur at level crossings: it is the case ofv
2+3v
6
±1
, connected tov
2+v
4
±1
by the well known Darling Dennison resonance which couplesv
4
±1
and 3v
6
±1
, and also ofv
5
±1
+3v
6
±1
connected tov
4
±1
+v
5
±1
by the same resonance; but this last case is complicated by an anharmonic resonance betweenv
5
±1
+3v
6
±1
and 2v
3+3v
6
1
. Two more perturbations occur on the K=–1 side ofv
2+v
4: a weak Coriolis resonance gives rise to one subband ofv
1+v
2 at a level crossing withv
2+v
4, and thev
1+v
5 band (linked of course tov
1+v
2 by the Coriolis resonance between thev
2 andv
5 modes) is quite visible and perturbs several subbands ofv
2+v
4 of high values of K through an anharmonic resonance. Moreover, the complex (3v
5
±1
,v+2v
5
0
, 2v
2+v
5
±1
, 3v
2,v
2+2v
5
±2
, 3v
5
±3
) system of Coriolis-connected bands is linked to the bands studied in the present work by two Fermi resonances: one betweenv
2+2v
5
0
andv
1+v
2, and the other one betweenv
1+v
5 and 3v
5
±1
, whose several subbands have been observed on the low part of the spectrum. The values of all the band centres and of the different coupling constants have been estimated, but all these interactions make the line assignments and the interpretation of the spectrum very difficult. 相似文献
74.
纳米二氧化钛粒子分散性能的研究 总被引:15,自引:0,他引:15
以四氯化钛为原料,采用溶胶-凝胶法技术合成路线,获得了平均粒径为63nm的二氧化钛粉末。采用分散技术,不仅可以改善粒子的分散性能,而且对粒子的生长也起到一定的抑制作用。研究表明:(1)采用SDS作为分散剂时,其极性基团和非极性基团分别与水和纳米TiO2粒子相结合,从而阻隔了TiO2粒子的团聚,起到分散作用。(2)以稀土元素La作为分散剂,其独特的轨道结构,不仅扩大了能量吸收的范围,更重要的是它与TiO2形成的络合物,使其成为相对独立的小团体,而它本身很小的固溶度使其难于形成合金化组元,结果被释放出来,从而形成更小的纳米TiO2粒子,起到分散纳米TiO2粒子的作用,并同时抑制纳米TiO2粒子的生长。 相似文献
75.
聚乙烯单晶的退火效应 总被引:1,自引:1,他引:1
用混合晶红外光谱法和SAXS、DSC和LAM等方法研究了聚乙烯单晶在75℃、90℃和105℃退火前后的结构变化,发现在90℃以下和105℃以上退火,遵循不同的退火机制 相似文献
76.
本文以二苯基甲酮的KBr压片为标样,在Bruker IFS 120HR付里叶变换红外光谱仪上系统考察了该仪器折一些重要操作参数(光源光栏、切趾函数、扫描速度)对光谱质量(信噪比,分辨率)的影响。从而获得了测样时的优化操作条件。 相似文献
77.
报道了FTS-20F富里叶红外光谱仪数据系统改造的工作采用IBM486计算机及新的数据接口取代了陈旧的NOVA4数据系统,文章详细描述了其硬件设计和软件编辑,改造不仅更新了FTS-20E里叶红外光谱仪,而且还使其达到90年代的水平。 相似文献
78.
79.
Cu-12.7(wt)%Al合金从900℃高温淬至365℃~500℃温度范围等温不同时间(30秒至15分钟)的试样中形成了大量树枝状的γ_2相沉淀粒子。应用配有X线能谱仪(XEDS)和电子能量损失谱仪(EELS)的分析电子显微镜(JEOL JEM-2000FX型)对上还试样研究,结果表明:这些γ_2相粒子具有富铝的“核心”,长大到粒子线度大于约800nm后以不稳定方式生长成“花朵”状。生长过程中伴随着溶质元素Al由基体向γ_2相内的富集。而且在γ_2相粒子内部呈现出Spinodal分解组织的形貌特征,表明γ_2粒子内形成了化学成分调幅。EELS分析表明试样含氧。 相似文献
80.
Vora A. Riga A. Dollimore D Alexander K. 《Journal of Thermal Analysis and Calorimetry》2004,75(3):709-717
This study attempts to identify the degradative process which folic acid undergoes in the solid-state under thermal stress.
In order to facilitate the process, the various pieces of the chemical structure, namely, p-amino benzoic acid, pterin and glutamic acid as both its d- and l-isomers were investigated as separate entities. These structured solid-state pieces were then compared to the composite solid
state folic acid degradative curves in order to identify the peaks seen and provide direction for the interpolation of the
degradative mechanism. It was observed that none of the structural pieces could be superimposed as assumed earlier and hence
an attempt was made to identify the decomposition products using various analytical techniques such as infrared spectroscopy,
mass spectroscopy and X-ray diffraction which suggested that the glutamic acid fragment is lost first as evidenced by acid
loss and amide enhancement in the IR spectra. The vitamin was ultimately degrading to carbon fragments and that further identification
was not necessary.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献