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51.
双(十二烷基亚磺酰)乙烷溶剂萃取钯及其机理的研究 总被引:2,自引:0,他引:2
本文研究用双(十二烷基亚磺酰)乙烷萃取钯的性能,在KI存在下从7mol/L盐酸介质中用含有BDSE的氯仿能定量萃取钯,有机的钯可被硫脲或氨溶液反萃继之用TMK-TritonX-100光度法测定,研究了萃取的最佳条件及干扰情况,斜率法测得萃合物组成为Pd:I:BDSE=1:2:1,红外光谱证实萃合物中BDSE的二个亚砜以硫原子与钯配位,萃合物为异位体络合物,提出了选择性萃取分离钯的新方法。 相似文献
52.
The synthesis and characterization of metal poly-yne polymers containing disilane, disiloxane and phosphine groups in the main chain are described. The platinum and palladium poly-yne polymers were synthesized by polycondensation reactions between a metal chloride and an α, ω-bisethynyl complex in amines in the presence of cuprous iodide as a catalyst. The nickel poly-yne polymers were synthesized by an alkynyl ligand exchange reaction between a nickel acetylide and an α, ω-bisethynyl complex in diethylamine in the presence of cuprous iodide as a catalyst. The reaction of the platinum poly-yne polymer, containing disiloxane groups in the main chain, with copper (I) salts afforded adducts of η-2-bonded σ-acetylide polymer complexes. The reactions of the palladium poly-yne polymer, containing phosphine groups in the main chain, with transition-metal carbonyl complexes afforded polymer complexes which have phosphorus in the main chain-transition-metal bonds. A concentrated solution of the platinum poly-yne polymer containing disiloxane groups in the main chain forms a lyotropic liquid crystal in dichloromethane or 1, 2-dichloroethane. 相似文献
53.
利用浓盐酸脱苯基方法合成混合二烃基二氯化锡 总被引:1,自引:1,他引:0
利用RSnPh3(R= Me3SiCH2、EtMe2SiCH2、Bu)和浓盐酸直接混合加热反应,合成了三种混合二烃基二氯化锡,通过IR,1H NMR和MS的测定,对产物的结构进行了表征;并探讨了反应时间、温度和浓盐酸用量对该反应产率的影响.实验结果表明,该方法与其它方法比较,具有操作简单、反应速度快、环境污染小、产率较高等特点;当四烃基锡与浓盐酸的物质的量比为1:8,在97 ℃反应7 min,混合二烃基二氯化锡的产率大于70%. 相似文献
54.
We consider a class of non-linear mixed integer programs with n integer variables and k continuous variables. Solving instances from this class to optimality is an NP-hard problem. We show that for the cases with
k=1 and k=2, every optimal solution is integral. In contrast to this, for every k≥3 there exist instances where every optimal solution takes non-integral values.
Received: August 2001 / Accepted: January 2002?Published online March 27, 2002 相似文献
55.
Hidenori Hanaoka Yuka Imamoto Takahiro Hino Tetsuya Kohno Kazunori Yanagi Yoshiaki Oda 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3668-3676
Chromium catalysts combined with phosphorous‐bridged bisphenoxy ligands were found to be highly active for ethylene polymerization. The most efficient catalyst precursor among them, generated by combining bis[3‐tert‐butyl‐5‐methyl‐2‐hydroxyphenyl](phenyl)phosphine hydrochloride ( 1a ) and CrCl3(THF)3, was characterized. X‐ray analysis of (3‐tert‐butyl‐5‐methyl‐2‐phenoxy)(3‐tert‐butyl‐5‐methyl‐ 2‐hydroxyphenyl)(phenyl)phosphine bis(tetrahydrofuran)chromium dichloride ( 6 ), obtained by the reaction of 1a and CrCl3(THF)3 in the presence of NaH, revealed a unique structure in which one phenol moiety of the bisphenol did not coordinate to the chromium center. Complex 6 showed higher activities than those observed in the in situ catalyst system. Polyethylene of various molecular weights was obtained with differing activators. The highest activity (113.5 kg mmol (cat)?1 h?1) was observed when TIBA/TB was used as a cocatalyst. A medium molecular weight polymer with narrow molecular weight distribution (Mw = 128,700, Mw/Mn = 1.8) was obtained using a 6 ‐TIBA/B(C6F5)3 system. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3668–3676, 2007 相似文献
56.
Lubomír Kubáček 《Mathematica Slovaca》2007,57(1):59-82
In some situations estimates of unknown parameters must be corrected by additional measurements. It is in principle no problem
to calculate the corrected estimates, however, it is of more interest to find formulae for correction itself. The formulae
enable us to design an additional experiment and to judge its usefulness.
The aim of the paper is to find such formulae for several situations.
Supported by the grant of the Council of Czech Government MSM 6 198 959 214. 相似文献
57.
58.
We investigate traces of functions, belonging to a class of functions with dominating mixed smoothness in ℝ3, with respect to planes in oblique position. In comparison with the classical theory for isotropic spaces a few new phenomenona
occur. We shall present two different approaches. One is based on the use of the Fourier transform and restricted to p = 2. The other one is applicable in the general case of Besov-Lizorkin-Triebel spaces and based on atomic decompositions. 相似文献
59.
60.
研究了初态为混合态的电荷量子比特与量子化光场之间的纠缠.通过求解系统的concurrence下限, 研究初态的混合度λ和失谐量Δ对系统纠缠随时间演化的影响. 在弱场中, 电荷量子比特初始是激发态的系统, 其纠缠度远远大于电荷量子比特初始是基态的系统, 并且Δ对系统的纠缠有明显的抑制作用. 在强场中, 电荷量子比特初始分别为激发态和基态时系统的纠缠演化接近一致, 初态混合度最高时系统的纠缠度最小, 并且Δ对系统纠缠的影响变弱.
关键词:
约瑟夫森结
纠缠
混合态
concurrence下限 相似文献