全文获取类型
收费全文 | 9730篇 |
免费 | 1069篇 |
国内免费 | 1753篇 |
专业分类
化学 | 10753篇 |
晶体学 | 61篇 |
力学 | 148篇 |
综合类 | 108篇 |
数学 | 127篇 |
物理学 | 1355篇 |
出版年
2024年 | 14篇 |
2023年 | 149篇 |
2022年 | 208篇 |
2021年 | 365篇 |
2020年 | 450篇 |
2019年 | 392篇 |
2018年 | 331篇 |
2017年 | 366篇 |
2016年 | 457篇 |
2015年 | 447篇 |
2014年 | 520篇 |
2013年 | 692篇 |
2012年 | 822篇 |
2011年 | 712篇 |
2010年 | 635篇 |
2009年 | 670篇 |
2008年 | 695篇 |
2007年 | 757篇 |
2006年 | 715篇 |
2005年 | 631篇 |
2004年 | 477篇 |
2003年 | 414篇 |
2002年 | 296篇 |
2001年 | 228篇 |
2000年 | 184篇 |
1999年 | 169篇 |
1998年 | 131篇 |
1997年 | 118篇 |
1996年 | 94篇 |
1995年 | 87篇 |
1994年 | 88篇 |
1993年 | 46篇 |
1992年 | 53篇 |
1991年 | 23篇 |
1990年 | 29篇 |
1989年 | 18篇 |
1988年 | 13篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 6篇 |
1979年 | 2篇 |
1978年 | 4篇 |
1973年 | 2篇 |
1969年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
LaPO4纳米微粒的制备及表征 总被引:5,自引:0,他引:5
Surface-modified LaPO4 nanoparticales were synthesized in the mixture solvent of water-ethanol with the surface modification age of dialkylphosphate. The conditions of synthesis and characterization were discussed. The results indicated that nanoparticle core of LaPO4 and surface-modified layer were formed. The surface-modified nanoparticles of LaPO4 can be dispersed in organic solvent and has better lubricating properties. 相似文献
102.
一种复合絮凝剂的絮凝性能及应用研究 总被引:18,自引:1,他引:18
以淀粉为原料,通过化学改性研制出同时兼含羟基、氰基、酰胺基和季铵盐基团的两亲型高分子絮凝剂(ASF),然后加入铝酸纳和硅酸钠,以一定的比例进行复配,制得复合型高分子絮凝剂CF-1,并综合研究了CF-l的絮凝性能。结果表明,CF-1对印染、造纸、皮革、制药等工业废水具有很强的絮凝和脱色效果,废水的色度去除率达96%以上,SS去除率达95%以上,CODCr去除率达74%以上。而且其絮凝性能明显优于阳离子聚丙烯蠢胺(CPAM)、聚合氯化铝(PAC)、硫酸铝以及硫酸亚铁等絮凝剂。 相似文献
103.
104.
《Surface and interface analysis : SIA》2003,35(12):1015-1017
Material surface properties of polymers, plastics, ceramics and textiles can be modified by atmospheric or low‐pressure glow discharge plasma. The aim of the present work is to study the surface modification of biaxially oriented polypropylene (BOPP) film in order to improve its hydrophilic and wetting properties. In this article we used low‐pressure, low‐temperature oxygen plasma for the surface treatment of BOPP. Scanning electron microscopy indicates that plasma treatment causes mainly physical changes by creating microcraters and roughness on the surface and increasing surface friction. Attenuated total reflectance infrared spectra show oxygen‐containing groups such as ? OH at 3513 cm?1 and C?O at 1695 cm?1. Microscopic investigations of water droplets on BOPP (treated, untreated) show that the interfacial adhesion of treated surfaces is increased. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
105.
In this work, influence of molecular weight and periodate modification ofβ-D-glucans isolated from Poria cocos sclerotium on the antitumor activities against Sar-coma 180 and Ehrlich ascites carcinoma (EAC) tumor was studied. The results show thattwo glucans PC3 (linear β-(1→3)-D-glucan) and PC4 [β-(1→3)-D-glucan with a fewof branches and glucuronic acid] are devoid of antitumor activity. However, when theglucans were modified by periodate oxidation, borohydride reduction and mild hydrolysisor partially hydrolysis, the derivatives have obvious antitumor activities. The decreasein molecular weight of glucans after periodate modification hardly affects their antitumoractions, but on the other hand, the decrease of molecular weight without periodate modi-fication could lead to an enhancement of the antitumor activities. Moreover, the glucansand these derivatives have much higher enhancement ratios of body weight of mice thanthat of 5-Fluorouracil (5-Fu), suggesting that they are less toxic than 5-Fu. 相似文献
106.
以紫外光谱、荧光光谱、粘度法和凝胶电泳方法研究了全反式维甲酸合钇(Ⅲ)配合物与DNA的作用。结果表明,该配合物能在生理条件下比配体和金属离子更有效地切割质粒DNA,体系离子强度和pH值的变化对配合物的切割活性有较大影响,自由基捕捉剂的加入不影响配合物的切割活性。该配合物对DNA的切割可能通过水解机理进行。该配合物可使DNA的粘度增加,使EB-DNA体系的荧光强度和DNA溶液的紫外吸收强度降低。据此推断,该配合物主要以嵌入方式与DNA作用。 相似文献
107.
108.
109.
In weakly acidic buffer medium, the interaction of amikacin with calf thymus DNA, yeast RNA and denatured DNA has been investigated by using resonance Rayleigh scattering (RRS) technique. The result shows that calf thymus DNA is capable of enhancing the RRS intensity of the amikacin, while yeast RNA and denatured DNA have very little enhancement effect. Based on the characteristics, a sensitive assay for detecting double-stranded DNA in the presence of denatured DNA and yeast RNA has been developed. The enhancement of the RRS signal is directly proportional to the concentration of double-stranded DNA in the range 0.02-12.0 μg ml−1 for calf thymus DNA and its detection limit (3σ) is 2.5 ng ml−1. The method shows a wide linear range and high sensitivity, and almost no interference can be observed from RNA, denatured DNA, amino acid and most of the metal ions. The trace amounts of nucleic acid in synthetic samples and practical samples are determined with satisfactory results. Therefore, the proposed method is promising for as an effect means for recognition in vivo and determination in situ of double-stranded DNA. 相似文献
110.
氧气在阴极的电还原及其应用研究进展 总被引:3,自引:0,他引:3
本文综述了氧阴极电还原的研究进展,着重介绍了阴极表面修饰对该过程的影响以及氧阴极电还原在有机物电合成与废水处理方面的研究进展。 相似文献