全文获取类型
收费全文 | 3715篇 |
免费 | 404篇 |
国内免费 | 672篇 |
专业分类
化学 | 4045篇 |
晶体学 | 34篇 |
力学 | 29篇 |
综合类 | 9篇 |
数学 | 2篇 |
物理学 | 672篇 |
出版年
2024年 | 10篇 |
2023年 | 32篇 |
2022年 | 36篇 |
2021年 | 102篇 |
2020年 | 114篇 |
2019年 | 110篇 |
2018年 | 104篇 |
2017年 | 135篇 |
2016年 | 151篇 |
2015年 | 171篇 |
2014年 | 186篇 |
2013年 | 370篇 |
2012年 | 240篇 |
2011年 | 274篇 |
2010年 | 206篇 |
2009年 | 231篇 |
2008年 | 227篇 |
2007年 | 242篇 |
2006年 | 208篇 |
2005年 | 207篇 |
2004年 | 167篇 |
2003年 | 178篇 |
2002年 | 123篇 |
2001年 | 96篇 |
2000年 | 99篇 |
1999年 | 76篇 |
1998年 | 72篇 |
1997年 | 82篇 |
1996年 | 45篇 |
1995年 | 50篇 |
1994年 | 50篇 |
1993年 | 32篇 |
1992年 | 23篇 |
1991年 | 12篇 |
1990年 | 20篇 |
1989年 | 18篇 |
1988年 | 17篇 |
1987年 | 34篇 |
1986年 | 38篇 |
1985年 | 62篇 |
1984年 | 25篇 |
1983年 | 24篇 |
1982年 | 36篇 |
1981年 | 30篇 |
1980年 | 18篇 |
1979年 | 6篇 |
1978年 | 2篇 |
排序方式: 共有4791条查询结果,搜索用时 15 毫秒
91.
Viorica Lopez-Avila Janet Benedicto Emi Baldin Werner F. Beckert 《Journal of separation science》1992,15(3):160-164
Nineteen halogenated and/or nitrated diphenyl ethers (currently listed in EPA Method 8111) have been separated on a DB-5/ DB-1701 column pair connected to an inlet splitter and separate electron capture detectors. Retention times are included for 10 additional compounds evaluated for their suitability as internal standards or surrogate compounds for incorporation into Method 8111. Method reproducibility and linearity are discussed, and results are presented for extracts of two real samples spiked with the 19 diphenyl ethers and analyzed using the dual-column dual-detector arrangement. 相似文献
92.
Mingdeng Wei Kiyomi Okabe Hironori Arakawa Yesutake Teraoka 《Reaction Kinetics and Catalysis Letters》2002,77(2):381-387
SiO2 was modified by hexagonal mesoporous silica to form a mixture with meso-/macroporous sizes and used as support of Co catalysts for Fischer-Tropsch synthesis in a slurry phase. A synergistic effect on the activity of Co catalyst was found. The catalytic properties are related to the state of surface Co and the character of support. 相似文献
93.
《Journal of separation science》2003,26(8):701-708
A micellar electrokinetic chromatographic and a fast reversed‐phase liquid chromatographic method have been developed for determination of the purity of phenoxymethylpenicillin. The optimized running buffer composition was 40 mM phosphate–borate–125 mM SDS–3.5% (v/v) methanol. The HPLC method employed a monolithic silica C18 column and a mobile phase composed of phosphate buffer, pH 3.5, and ACN, the flow‐rate being 3.5 mL/min. Both methods were successfully validated. Linearity, intermediate precision, limits of quantitation, accuracy, and a good correlation of the HPLC and MEKC results were demonstrated. Both methods proved to be fast and reliable and sufficiently sensitive. A combination of the two methods can be very useful in impurity profiling. 相似文献
94.
Y. Akiyama F. Mizukami H. Izutsu M. Sato K. Maeda Y. Kiyozumi K. Sakaguchi 《Journal of Sol-Gel Science and Technology》1998,13(1-3):421-425
A novel organic-inorganic composite was prepared by a sol-gel process using hydrolysis and condensation of tetraethoxysilane (TEOS) reacted with a saccharide. During the process, ethoxy groups of the TEOS were replaced with hydroxyl groups of the saccharide and, consequently, saccharide molecules were combined with silica through their hydroxyl groups. Samples obtained under different reaction conditions were used for optical resolution of a metal chelate compound. The resolution ability of the composites was affected by the amount of water added for hydrolysis and of the saccharide. In particular, the amount of water drastically influenced the optical resolution performance. Composites obtained at the lower H2O/TEOS ratio gave the metal chelate compound a higher optical rotation. Three types of composites with the same composition were prepared by kneading, impregnation and by the sol-gel method, and were compared. The sol-gel composite showed the best optical resolution ability. It was concluded that the optical resolution ability was closely related to dispersibility of saccharide in the silica matrix. 相似文献
95.
CO2氧化异丁烷制异丁烯用Pd/V2O5-SiO2催化剂 总被引:4,自引:0,他引:4
利用表面化学反应改性法制备了不同V2O5负载量的V2O5-SiO2表面复合物载体,进而采用等体积浸渍法制备了负载型Pd催化剂. 用N2吸附、 X射线衍射、透射电镜、 X射线光电子能谱、程序升温脱附、化学吸附-红外光谱和微反技术对系列Pd/V2O5-SiO2催化剂的比表面积、晶相结构、价态、异丁烷的化学吸附性能和CO2部分氧化异丁烷制异丁烯的催化性能进行了研究. 结果表明, Pd/V2O5-SiO2催化剂中的钒以V5+形式存在, V5+在催化剂表面形成活性位V=O, 其中 V=O 晶格氧与 i-C4H10分子的-CH3 和-CH 中的H产生化学吸附作用; 催化剂中金属Pd与V4+协同作用使CO2在催化剂上产生了卧式吸附态; 晶格氧参加了催化氧化反应,催化剂中 V5+←→V4+ 的变化构成了催化反应的氧化还原过程. 在525 ℃, CO2/i-C4H10体积比为1和空速为 1200 h-1的条件下,以Pd/25%V2O5-SiO2为催化剂时异丁烷转化率为22.8%, 异丁烯选择性为89.1%. 相似文献
96.
The synthesis of magnetic vesicles is described. The vesicles are constituted by didodecyldimethylammonium bromide and have a diameter of about 1 m. An aqueous magnetic fluid, constituted by charged magnetic nanoparticles dispersed in water without surfactant, is encapsulated in the vesicle with a volume fraction in particles that may range up to 10%. The first step of the encapsulation is the synthesis of a multiple emulsion the intermediate oily phase being evaporated to obtain the DDAB bilayer. The magnetic vesicles thus synthesized align and change shape when a magnetic field is applied. 相似文献
97.
Uulke A. van der Heide Marc A. M. J. Zandvoort Ernst van Faassen Gijs van Ginkel Yehudi K. Levine 《Journal of fluorescence》1993,3(4):271-279
Measurements of fluorescence depolarization decays are widely used to obtain information about the molecular order and rotational dynamics of fluorescent probe molecules in membrane systems. This information is obtained by least-squares fits of the experimental data to the predictions of physical models for motion. Here we present a critical review of the ways and means of the data analysis and address the question how and why totally different models such as Brownian rotational diffusion and wobble-in-cone provide such convincing fits to the fluorescence anistropy decay curves. We show that while these models are useful for investigating the general trends in the behavior of the probe molecules, they fail to describe the underlying motional processes. We propose to remedy this situation with a model in which the probe molecules undergo fast, though restricted local motions within a slowly rotating cage in the lipid bilayer structure. The cage may be envisaged as a free volume cavity between the lipid molecules, so that its position and orientation change with the internal conformational motions of the lipid chains. This approach may be considered to be a synthesis of the wobble-in-cone and Brownian rotational diffusion models. Importantly, this compound motion model appears to provide a consistent picture of fluorescent probe behavior in both oriented lipid bilayers and lipid vesicle systems. 相似文献
98.
Drying dissipative structural patterns formed in the course of drying colloidal crystals of silica spheres (110 nm in diameter)
in water, methyl alcohol, ethyl alcohol, 1-propyl alcohol, diethyl ether, and in the mixtures of ethyl alcohol with the other
solvents above have been studied on a cover glass. The macroscopic broad rings were formed in the outside edges of the dried
film for all the solvents examined. Furthermore, much distinct broad rings appeared in the inner area when the solvents were
ethyl alcohol, methyl alcohol, and their mixtures. Profiles of the thickness of the dried films were sensitive to the organic
solvents and explained well with changes in the surface tensions, boiling points, and viscosities of the solvents. The macroscopic
and microscopic spoke-like crack patterns formed. The drying area (or the drying time) increased (or decreased) as the surface
tension of the solvent decreased. However, the absolute values of these drying parameters are determined also by the boiling
points of the solvents. Importance of the fundamental properties of the solvents is supported in addition to the characteristics
of colloidal particles in the drying dissipative pattern formation. 相似文献
99.
高效液相色谱氮杂冠醚键合固定相的合成及性能研究 总被引:2,自引:0,他引:2
我们曾用γ-氯丙基键合硅胶(CPS),在氢化钠(NaH)作用下合成了3-(氮杂-18-冠-6)丙基键合固定相(BCP)[1].该固定相对碱基、核苷酸、硝基苯酚等有较好的分离选择性,但由于NaH对硅胶基质腐蚀作用较大,导致BCP柱效及渗透性较低.本文采... 相似文献
100.
Zanin Gisella M. Neitzel Ivo De Moraes Flavio F. 《Applied biochemistry and biotechnology》1993,(1):477-489
The axial dispersion of a liquid fluidized bed of controlled pore silica (CPS) particles has been determined by the pulse
tracer method. The CPS used was the same as for enzyme immobilization, having an average diameter of 0.436 mm and mean pore
size of 37.5 nm. The fluidization liquid is α-amylase liquefied manioc starch, 30% w/v, 45°C pH=4.5. Nominal bed porosities
tested were 0.7 and 0.8. The results show that the axial dispersion coefficient increases with greater superficial liquid
velocities. Various available correlations tested disagree with each other to a large extent and are unable to represent collected
experimental data. 相似文献