全文获取类型
收费全文 | 5698篇 |
免费 | 1313篇 |
国内免费 | 578篇 |
专业分类
化学 | 2931篇 |
晶体学 | 90篇 |
力学 | 363篇 |
综合类 | 76篇 |
数学 | 317篇 |
物理学 | 3812篇 |
出版年
2024年 | 14篇 |
2023年 | 66篇 |
2022年 | 146篇 |
2021年 | 184篇 |
2020年 | 230篇 |
2019年 | 208篇 |
2018年 | 187篇 |
2017年 | 203篇 |
2016年 | 249篇 |
2015年 | 222篇 |
2014年 | 331篇 |
2013年 | 497篇 |
2012年 | 359篇 |
2011年 | 405篇 |
2010年 | 321篇 |
2009年 | 385篇 |
2008年 | 299篇 |
2007年 | 326篇 |
2006年 | 337篇 |
2005年 | 274篇 |
2004年 | 251篇 |
2003年 | 281篇 |
2002年 | 279篇 |
2001年 | 209篇 |
2000年 | 227篇 |
1999年 | 188篇 |
1998年 | 163篇 |
1997年 | 86篇 |
1996年 | 70篇 |
1995年 | 72篇 |
1994年 | 67篇 |
1993年 | 54篇 |
1992年 | 57篇 |
1991年 | 50篇 |
1990年 | 38篇 |
1989年 | 34篇 |
1988年 | 42篇 |
1987年 | 32篇 |
1986年 | 28篇 |
1985年 | 14篇 |
1984年 | 18篇 |
1983年 | 11篇 |
1982年 | 8篇 |
1981年 | 11篇 |
1980年 | 12篇 |
1979年 | 15篇 |
1978年 | 9篇 |
1977年 | 9篇 |
1974年 | 3篇 |
1973年 | 2篇 |
排序方式: 共有7589条查询结果,搜索用时 240 毫秒
51.
Koichi Itoh Takeji Takui 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(2):29
This review paper deals with an overview of molecule-based magnetism as a rapidly developing interdisciplinary field, topological symmetry rule as the first principle of spin alignment in organic open-shell systems in the ground state, the proposal of organic through-bond 1D and 2D ferro- and superparamagnets and the detection of the first organic high-spin molecule, m-phenylenebis(phenylmethylene) in the quintet ground state (S = 2), followed by extended organic high-spin systems with π-conjugation such as aromatic hydrocarbons having S = 3, 4, 5. The paper also describes a theoretical approach to the understanding of electronic spin structures of organic high-spin molecules by invoking both Heisenberg and Hubbard model Hamiltonians, weakly interacting intramolecular high-spin systems from both experimental and theoretical sides, the spin density distribution of the first organic high-spin molecule in terms of electron- nuclear multiple resonance spectroscopy and the detection and characterization of ionic high-spin hydrocarbons, emphasizing the establishment of high spin chemistry underlying organic molecular magnetism. 相似文献
52.
王守宇 马英君 T.Komatsubara 刘运祚 张玉虎 梁国栋 K.Furuno T.Hayakawa J.Mukai Y.Iwata T.Morikawa G.B.Hagcmann G.Sletten J.Nyberg D.Je 《中国物理 C》2004,28(5):491-494
利用融合蒸发反应116Cd(14N,4n)126Cs布居了126Cs的高自旋态.观测到了100多条新的γ跃迁和相应的能级,建立了双奇核126Cs由9个转动带构成的能级纲图.尝试性地指定了大部分能级的自旋和宇称以及各转动带的Nilsson单粒子组态.极大地丰富了已有的实验结果. 相似文献
53.
Ginette Ratovo Jean‐Pierre Souchard Pascale Urizzi Yvon Coulais Franoise Nepveu Etienne Hollande 《应用有机金属化学》2004,18(1):1-8
Pancreatic cancer has an extremely poor prognosis, due, in part, to lack of methods for early diagnosis. The present study was designed to evaluate the potential of labeling low‐density lipoprotein (LDL) with a radionuclide using a lipid chelating agent, bis(stearylamide) of diethylenetriaminepentaacetic acid (L), to detect pancreatic tumors by gamma‐scintigraphy. Previous studies indicated that the difficulty of visualization of pancreatic tumors was due to their poor vascularization. This study compares the ability of two radiotracers, 111In–L–LDL and 153Gd–L–LDL to target highly vascularized rat pancreatic tumors (AR4‐2J) implanted in nude mice. Biodistribution studies showed that the tumor uptake of 111In–L–LDL and 153Gd–L–LDL tracers was twofold and fivefold higher respectively than with the controls (111In citrate and 153Gd citrate respectively). These tracers would thus be suitable for scintigraphic imaging. We show here that LDL could be employed as a delivery system for tracers such as 111In or 153Gd when these two radionuclides are complexed by a lipid‐chelating anchor, and that 111In–L–LDL and 153Gd–L–LDL enabled better visualization of the pancreatic tumor tissues, with a better result with 153Gd–L–LDL. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
54.
Finite chains of a two-state random Potts spin model with periodic boundary conditions are studied within Glauber dynamics. The spin exchange is assumed random with frustration between ferro and antiferromagnetic values (±J). Time-dependent fluctuations are induced by periodic temperature oscillations. Master type differential equations for spin correlation functions are solved within linear response theory. The spectrum of relaxation times are calculated at different temperatures. The ±J Potts glass chains undergo a zero temperature phase transition. The barriers against inversion of the spin chain take only two values; 0 and 2|J|. The temperature behaviour of specific heat is characterized by rounded peaks. The frequency dependence displays two plateaus for the real part of specific heat and two corresponding peaks for the imaginary part. The dynamic specific heat is not affected by the longest relaxing mode like susceptibility. The time separation of the modes is demonstrated by the Cole-Cole plots. 相似文献
55.
本文运用信息保存法对低速二维的流动现象进行模拟,考察了低速条件下的有限平板绕流以及微槽道气体流动问题。研究表明:在对低速流动的模拟过程中,运用IP法在能够获得较好的结果的同时,具有比DSMC方法更高的计算效率。 相似文献
56.
狄拉克方程的单旋量解法以及由此引起的认识上的差异 总被引:2,自引:0,他引:2
把狄拉克方程分解成了两个单旋量的联立方程组.指出现行的自旋理论仅考虑了其中的一个方程,是以一个单旋量代替双旋量来描述状态而建立起来的.笔者在认同现行自旋理论可以作为狄拉克方程的一种求解方法,因而同意其中的某些提法外,对于其主要的物理观念:微观粒子存在着独立于现实的位形空间之外的一个自旋空间,在这个自旋空间内禀着角动量S和磁矩μ;这个自旋理论是相对论性量子力学导出的必然结论等等看法予以否定.笔者认为,只有同时考虑两个单旋量的方程,同时计及两个单旋量,才能准确地描述状态,从而正确地描述客观规律. 相似文献
57.
陈化温度和Fe/Zr配比对SO42-/Fe2O3-ZrO2固体超强酸结构与性能的影响 总被引:6,自引:0,他引:6
用低温陈化法制备了SO42 -/Fe2 O3 ZrO2 (简称SFZ)固体超强酸催化剂 ,用红外光谱 (IR)和X光衍射(XRD)对其结构进行了表征 ,并考察了它对合成癸二酸二正丁酯的催化性能 .IR谱显示 ,低温陈化的SFZ样品在10 70cm-1处吸收峰远强于常温陈化样品 .XRD分析则显示 ,在焙烧温度为 6 5 0℃、Fe/Zr为 2∶1时 ,低温陈化的样品出现了亚稳态的ZrO2 四方晶相 .该样品在催化酯化反应中使产率达 90 %以上 ,高于常温陈化样品的 30 % .研究结果表明 :在其他条件不变时 ,低温陈化所出现的亚稳态的ZrO2 四方晶相是表面酸性和催化活性增加的微观原因 相似文献
58.
Sebastiaan van Dijken Xavier Fain Steven M. Watts Kentaro Nakajima J. M. D. Coey 《Journal of magnetism and magnetic materials》2004,280(2-3):322-326
A detailed study of the in-plane magnetotransport properties of spin valves with one and two Fe3O4 electrodes is presented. Fe3O4/Au/Fe3O4 spin valves exhibit a clear anisotropic magnetoresistance in small magnetic fields but no giant magnetoresistance (GMR). The absence of GMR in these structures is due to simultaneous magnetization reversal in the two Fe3O4 layers. By contrast, a negative GMR effect is measured on Fe3O4/Au/Fe spin valves. The negative GMR is attributed to an electron spin scattering asymmetry at the Fe3O4/Au interface or an induced spin scattering asymmetry in the Au interfacial layers. 相似文献
59.
60.
P. Tekely V. G rardy P. Palmas D. Canet A. Retournard 《Solid state nuclear magnetic resonance》1995,4(6):361-367
A simple modification of the standard cross-polarization method designed for quenching the proton T1ρ dependence when studying polarization transfer is presented. It is demonstrated that by using this simple procedure, new and subtle details of cross-polarization dynamics, previously hidden by the T1ρ(1H) effect, can be observed in dipolar-coupled spin systems. 相似文献