Microscale heat transfer in an evaporating moving extended meniscus

The evaporative heat flux distribution in the leading edge region of a moving evaporating thin liquid film of pentane on quartz was obtained by analyzing the measured thickness profile for thicknesses, δ < 2 μm. The profiles in a constrained vapor bubble were obtained using image analyzing interferometry. Although the evaporating meniscus appeared to be benign (i.e., without additional observed motion beyond creeping), high heat fluxes were obtained. Significantly higher heat fluxes are possible. The interfacial slope, curvature, interfacial shear stress, and liquid pressure profiles were also obtained. Results obtained using a continuum model were consistent with those obtained using a control volume model. The measured pressure field profile of the isothermal extended meniscus agreed with the constant pressure field predicted by the augmented Young–Laplace model. For the non-isothermal case, measured thickness gradients lead to disjoining pressure and curvature gradients for fluid flow and evaporation. The experimental results demonstrate that disjoining pressure at the contact line controls fluid flow within an evaporating completely wetting thin curved film and is, therefore, a useful boundary condition. However, in small interfacial systems, non-idealities can have a dramatic effect.     

含环向表面裂纹圆柱壳的波传播特性研究

研究了振动波在含有环向表面裂纹的无限长圆柱壳中的传播特性.圆柱壳体的振动用Flügge方程来描述.运用线弹性断裂力学的理论,考虑到裂纹的张开、滑移和撕裂3种模式以及它们相互之间的耦合,利用分布的线弹簧来模拟裂纹并建立了裂纹所在区域的局部柔度矩阵,得到由此引起的附加位移和壳体中内力之间的关系.在入射波已知的情况下,根据裂纹两侧区域的位移和内力的连续性条件得到了反射和透射波的幅值系数.分析了入射波通过裂纹后的透射、反射系数与激励频率和裂纹尺寸之间的关系.为基于振动功率流方法识别圆柱壳表面损伤提供了理论基础.     

有限元网格自动生成及绘制中的实用处理技巧

提出了超大单元、结点归一化相对距离判别法这一快速三维自动剖分技术，针对大型水工建筑物的特点，给出了几种常遇问题的实用处理方法；还给出了适合工程实际的超大面判断立体消隐图绘制法和基于Ａｕｔｏｌｉｓｐ语言及Ａｕｔｏ－ＣＡＤ的立体图处理方法．     

压电材料平面应力状态的直线裂纹问题一般解

研究了含直线裂纹系的压电材料平面应力问题单个裂纹和双裂纹问题的封闭解答表明，在裂纹尖端，应力、电场强度和电位移有１／２阶的奇异性并与前人结果比较了产生电场奇异性的物理因素     

两跨输电线非线性主共振响应分析

研究两跨输电线非线性共振响应问题,应用Hamilton变分原理推导了两跨输电线的振动微分方程以及对应的边界条件。利用Galerkin离散方法和多尺度法,得到了单模态主共振响应。研究结果表明:幅频响应曲线表现出软、硬弹簧性质,随着外激励幅值的增大,输电线系统响应由软弹簧性质向硬弹簧性质转换;系统阻尼减小或外激励幅值增大时,系统幅值个数也随之发生变化,表现出多值和跳跃现象。     

可压缩材料平面应变滑移线场的数值解和边界条件

简要介绍了可压缩材料平面应变滑移线理论。导出了滑移线场应力和速度数值解。处理了应力边界条件，阐明了应力和速度间断规律。举例说明了边界条件处理和数值解步骤。     

Far‐Red and Near‐IR AIE‐Active Fluorescent Organic Nanoprobes with Enhanced Tumor‐Targeting Efficacy: Shape‐Specific Effects

The rational design of high‐performance fluorescent materials for cancer targeting in vivo is still challenging. A unique molecular design strategy is presented that involves tailoring aggregation‐induced emission (AIE)‐active organic molecules to realize preferable far‐red and NIR fluorescence, well‐controlled morphology (from rod‐like to spherical), and also tumor‐targeted bioimaging. The shape‐tailored organic quinoline–malononitrile (QM) nanoprobes are biocompatible and highly desirable for cell‐tracking applications. Impressively, the spherical shape of QM‐5 nanoaggregates exhibits excellent tumor‐targeted bioimaging performance after intravenously injection into mice, but not the rod‐like aggregates of QM‐2.     

White‐Light Emission Strategy of a Single Organic Compound with Aggregation‐Induced Emission and Delayed Fluorescence Properties

A novel white‐light‐emitting organic molecule, which consists of carbazolyl‐ and phenothiazinyl‐substituted benzophenone (OPC) and exhibits aggregation‐induced emission‐delayed fluorescence (AIE‐DF) and mechanofluorochromic properties was synthesized. The CIE color coordinates of OPC were directly measured with a non‐doped powder, which presented white‐emission coordinates (0.33, 0.33) at 244 K to 252 K and (0.35, 0.35) at 298 K. The asymmetric donor–acceptor–donor′ (D‐A‐D′) type of OPC exhibits an accurate inherited relationship from dicarbazolyl‐substituted benzophenone (O2C, D‐A‐D) and diphenothiazinyl‐substituted benzophenone (O2P, D′‐A‐D′). By purposefully selecting the two parent molecules, that is, O2C (blue) and O2P (yellow), the white‐light emission of OPC can be achieved in a single molecule. This finding provides a feasible molecular strategy to design new AIE‐DF white‐light‐emitting organic molecules.     

A Porous Tricyclooxacalixarene Cage Based on Tetraphenylethylene

A quadrangular prismatic tricyclooxacalixarene cage 1 based on tetraphenylethylene (TPE) was efficiently synthesized by a one‐pot S_NAr condensation reaction. As a result of the porous internal structure in the solid state, cage 1 exhibited a good CO₂ uptake capacity of 12.5 wt % and a high selectivity for CO₂ over N₂ adsorption of 80 (273 K, 1 bar) with a BET surface area of 432 m² g^?1. Formation of cage 1 led to the fluorescence of TPE being switched on in solution. The system was employed as a single‐molecule platform to study the mechanism of aggregation‐induced emission (AIE) by examining the restriction of intramolecular rotation (RIR).     

Organic Crystals with Near‐Infrared Amplified Spontaneous Emissions Based on 2′‐Hydroxychalcone Derivatives: Subtle Structure Modification but Great Property Change

A series of highly efficient deep red to near‐infrared (NIR) emissive organic crystals 1 – 3 based on the structurally simple 2′‐hydroxychalcone derivatives were synthesized through a simple one‐step condensation reaction. Crystal 1 displays the highest quantum yield (Φ_f) of 0.32 among the reported organic single crystals with an emission maximum (λ_em) over 710 nm. Comparison between the bright emissive crystals 1 – 3 and the nearly nonluminous compounds 4 – 7 clearly gives evidence that a subtle structure modification can arouse great property changes, which is instructive in designing new high‐efficiency organic luminescent materials. Notably, crystals 1 – 3 exhibit amplified spontaneous emissions (ASE) with extremely low thresholds. Thus, organic deep red to NIR emissive crystals with very high Φ_f have been obtained and are found to display the first example of NIR fluorescent crystal ASE.