粉末化学镀法制备的NiB／TiO2非晶态合金催化剂对环丁烯砜加氢反应的催化性能

 采用诱导沉积法及粉末化学镀法分别制备了纯态NiB及负载型NiB／TiO2非晶态合金催化剂．用XRD，ICP，SEM，TEM和DSC等手段对催化剂的物性及TiO2载体与NiB非晶态合金之间的相互作用进行了表征，考察了非晶态合金的结构、组成、形貌和热稳定性，并将其用于环丁烯砜加氢反应中．结果表明，相对于NiB而言，NiB／TiO2催化剂具有优良的热稳定性和催化活性，这缘于NiB和TiO2载体之间的相互作用及载体的分散作用．     

APPLICATION OF THE MOMENT METHODS TO ANALYSIS OF X-RAY DIFFRACTION LINE PROFILE FOR PA1010-BMI SYSTEM

Pure X-ray diffraction profiles have been analysed for polyamide 1010 and PA1010--BMI system by means of multipeak fitting resolution of X-ray diffraction.The methods ofvariance and fourth moment have been applied to determine the particle size and strainvalues for theparacrystalline materials.The results indicated that both variance and fourthmoment of X-ray diffraction line profile yielded approximately the same values of theparticle size and the strain.The particle sizes of(100)reflection have been found todecrease with increasing BMI content,whereas the strain values increased.     

锌—镉法测定天然水中硝酸盐的盐误差及其解决方法

研究了锌-镉法测定天然水中硝酸盐的盐误差,发现水中含盐量对还原率有重大影响,但在盐度为1%以后还原率基本不变;加入人工海盐(1.5g/50ml水样)可消除盐误差.由此建立了没有盐误差的新的锌-镉法.方法相对标准偏差小于3%,回收率为98%～102%,与镉-铜法对比,两种方法的相对偏差小于8%.     

天然药物及制剂中微量元素硒的测定方法概况

硒是人体必需的微量元素，具有抗肿瘤、防衰老、防辐射和增强机体免疫力等多种功能。本文就国内近年来对天然药物及其制剂中微量元素硒的分析方法概况作一综述，包括：原子吸收分光光度法、荧光分光光度法、电感耦合等离了光谱法、催化分光光度法、分光光度法、化学发光淬灭法、极谱法、中子活化分析法和色谱法等。     

Thermal behavior of selected ferroelectric liquid crystals

Thermal properties of three ferroelectric liquid crystals, namely: 3-octyloxy-6-[2-fluor-4-(fluoroctyloxy)phenyl]-pyridine (FFP), 3-(3-fluor-nonyl)-6[4-heptyloxyphenyl]-pyridine (FNHPh-P), 4-[(S,S)-2,3-epoxyhexyloxy]phenyl 4-(decyloxy)benzoate (EHPhDB) were studied using heat flux differential scanning calorimetry method. All the transitions expected in this compounds, except the SmC^*-SmA^* and SmC^*-S₃ transitions, were detected in the DSC curves. The temperatures of the phase transitions and the enthalpy changes associated with them were determined. The transition from the liquid crystalline to the crystalline state showed significant hysteresis for all three compounds studied. The following transitions: SmA^*-Is, SmG^*-SmC^* for FNHPh-P, N^*-Is for EHPhDB, N^*-Is and SmC^*-N^* for FFP also showed a small hysteresis basing on which first-order character of all the above transitions was implied. All three substances studied in this work are characterized by a complex polymorphism in the solid state.The author is grateful to Dr. Stanislaw Wróbel for his stimulating interest, valuable discussions and supplying the samples. This work has been done in the framework of the KBN grant 2 P302 139 07.     

Determination of polycyclic aromatic sulfur heterocycles (PASH) in diesel fuel by high performance liquid chromatography and photodiode-array detection

An oxidation method (sulfone method) for the determination of polycyclic aromatic sulfur heterocycles (PASH) in diesel fuel is presented. The aromatic fraction of a diesel fuel, isolated by solid phase extraction, is oxidized under controlled conditions with hydrogen peroxide. The oxidation products, mainly methylated dibenzosulfone, are determined and quantified directly, without further clean-up, by HPLC with photodiode-array detection.     

On the Proper Normalization Constraint

In the variational optimization of a trial function the proper functional to be varied is the Rayleigh quotient with the normalization constraint explicitly imposed. It will be shown that only under certain very rigorous conditions can one use the energy functional to replace the Rayleigh quotient and that, therefore, the normalization constraint is by no means a matter of no consequence.     

Synthesis and Electrochemical Studies of Spinel LiNi1−xMnxVO4

Spinel compound LiNi_1−xMn_xVO₄ (0≤x≤0.4) had been prepared by using the moist chemical method. X-ray diffraction spectra showed that the lattice constant increased with x in the LiNi_1−xMn_xVO₄, XPS spectra indicating that Li1s had a chemical shift towards lesser binding energy, and manganese in LiNi_1−xMn_xVO₄ existing as the mixed valence of Mn²⁺ and Mn³⁺. The electrochemical charge and discharge testing at a current density of 0.1 mA/cm² between the potentials of 4.0 and 3.0 V vs Li/Li⁺ in 1 mol/dm³ LiPF₆/EC+DEC (1:1 by volume) at 25°C showed that LiNi_1−xMn_xVO₄ cell has a better rechargeability, but a lower cell voltage of 4.0 V vs Li/Li⁺ than that without the doping sample, and the capacity and the cycle efficiency of the Li/LiNi_1−xMn_xVO₄ cells increased with x in the LiNi_1−xMn_xVO₄.     

Application of an Ion Beam Technique for the Design of Visible Light-Sensitive, Highly Efficient and Highly Selective Photocatalysts: Ion-Implantation and Ionized Cluster Beam Methods

As a new concept for the design of effective photocatalysts, an ion beam technology using accelerated metal ions, a metal ion implantation and an ionized cluster beam (ICB) method, have been applied to design unique photocatalysts. The metal ion implantation of TiO₂ and Ti-containing zeolites with highly accelerated metal ions (V⁺, Cr⁺, etc.) is useful in designing photocatalysts that can operate efficiently under visible light irradiation. Also, an ICB method with a low acceleration energy is useful in preparing transparent TiO₂ thin films on various types of substrates for the efficient photocatalytic degradation of pollutants diluted in water and air. The combination of the ICB method and metal ion implantation can develop the TiO₂ thin films that are able to operate not only under UV light but also under visible light irradiation.     

Comparison between adsorption isotherm determination techniques and overloaded band profiles on four batches of monolithic columns

The adsorption isotherms of 4-tert.-butyl phenol were measured on four different monolithic columns, using three different techniques, classical frontal analysis (FA), the perturbation on a plateau method (PP) and the recently introduced numerical procedure known as the inverse numerical method (IN). This last approach requires only the recording of a few overloaded profiles and has the potential advantage of affording a dramatic decrease of the amounts of compounds, solvent, and time needed to determine accurate estimates of the coefficients of the isotherm. The reproducibility of the adsorption data measured on the four columns is discussed with reference to the specific techniques used for obtaining these data and to the most suitable equation used for modeling them. The data obtained for the different columns were highly consistent. The inverse numerical approach was confirmed to provide a powerful, accurate, and economic method for measuring single component adsorption data.