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31.
Dynamic surface elasticity of polymer solutions 总被引:1,自引:0,他引:1
B. A. Noskov 《Colloid and polymer science》1995,273(3):263-270
The surfaces of surfactant solutions exhibit viscoelastic dilational behavior which may be investigated by modern optical and mechanical methods. The present study focuses on the dynamic dilational properties of the polymer solution — gas interface. Linear flexible polymer chains at the surface are considered as consisting of trains, lying on the surface, and loops and tails that protrude into the liquid. The Rouse model is used to describe the inner dynamics of the trains, whereas their motion relative to their neighbors on the surface can be described with the help of the reptation conception. An expression for the complex dynamic dilational surface elasticity has been derived. Although, in general, the relaxation of the surface tension is characterized by an infinite series of relaxation times, it is shown that for many systems the dynamics of the surface layer can be described approximately by only two main relaxation times. The dispersion equation, which was obtained earlier for solutions of conventional surfactants, is shown to be fulfilled for polymer solutions also. 相似文献
32.
Chun-Long?Chen Andrea?M.?Goforth Mark?D.?Smith William?R.?Gemmill Cheng-Yong?Su Hans-Conrad?zur?LoyeEmail author 《Journal of Cluster Science》2005,16(4):477-487
A new flexible ligand, 1,5-bis(8-oxaquinoline)-3-methylpentane (C5MeOQ), was synthesized and used in the preparation of the
new dinuclear copper(II) complex 1: [Cu2(μ-OMe)2(μ-C5MeOQ)(NO3)2]. Single crystal X-ray analysis revealed that complex 1 contains dinuclear Cu(II) units with bridging methoxo groups. The ligand, C5MeOQ, takes on a bent conformation in order to
connect to and complete the square planar coordination environment of both copper centers; and one of the two Cu(II) centers
adopts a distorted square planar configuration as a result of the ligand conformation. The magnetic properties of complex
1 were investigated by variable-temperature magnetic susceptibility measurements in the 100–300 K range. Interestingly, the
susceptibility data for complex 1 reveals that the compound is diamagnetic, suggesting the presence of very strong antiferromagnetic coupling interactions
between the adjacent Cu(II) centers. 相似文献
33.
We present a computational protocol which uses the known three-dimensional structure of a target enzyme to identify possible ligands from databases of compounds with low molecular weight. This is accomplished by first mapping the essential interactions in the binding site with the program GRID. The resulting regions of favorable interaction between target and ligand are translated into a database query, and with UNITY a flexible 3D database search is performed. The feasibility of this approach is calibrated with thrombin as the target. Our results show that the resulting hit lists are enriched with thrombin inhibitors compared to the total database. 相似文献
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现有光伏系统的控制器普遍选用微控制器为核心,为使之与电子技术课程教学案例开发相结合,提出采用集成运放替代微控制器的智能太阳能控制器方案,并以直流12V/10A小功率应用为研究实例。实验结果表明该控制器方案可行,且电路简单、成本低廉,适用于实验教学与课程设计。 相似文献
37.
《Mendeleev Communications》2021,31(5):726-727
Low-temperature XRD measurements were performed to confirm the phase composition and structural parameters of the electrochemically deposited Cu2ZnSnSe4 thin films on flexible metal substrates. 相似文献
38.
《Electroanalysis》2018,30(2):345-352
We reported here three simple, low cost and easy to accomplish strategies for the fabrication of microelectrodes and other conductive patterns using ordinary office laser‐printers. In this work, toner patterns were directly printed onto the flexible substrate, acting as a mask to create the intended conductive design. To highlight the versatility of such technology, toner‐printed patterns were employed in two diverse ways: one in which the patterned toner had the exact design of the electrode and other employing a reverse toner‐printed pattern. The first one was used for the adaptation of the well‐known printed circuit board (PCB) fabrication technique, but using direct toner printing (DTP) in an already conductive flexible substrate. The second was employed for the two remaining strategies: one based on the deposition of conductive film, followed by lift‐off process; and another based on drop‐casting of a conductive ink into the formed toner cavities, followed by thermal cure. As proof‐of‐concept, all three DTP strategies were used for the fabrication of miniaturized gold electrodes in polyimide substrate, and electrochemical performance of each obtained electrode was evaluated by cyclic voltammetry. Insights about DTP technology, alignment issues, advantages, limitations and resolution of each presented approach were provided. Finally, direct toner printing showed to be a simple, affordable and quite promising technology for the fabrication of low cost point‐of‐care electrochemical devices using flexible platforms. 相似文献
39.
K. Irmer 《Isotopes in environmental and health studies》2013,49(10):417-418
Bei der kontinuierlichen Durchstrahlungsprüfung von Werkstücken werden überwiegend Meßeinrichtungen, bestehend aus 60Co-Strahlungsquelle, Szintillationsdetektor und schreibendem Meßgerät, verwendet 1. 相似文献
40.
Shuhei Akahori Prof. Dr. Takahiro Sasamori Prof. Dr. Hiroshi Shinokubo Prof. Dr. Yoshihiro Miyake 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(31):8178-8184
Quadruply BN-fused tetrathia[8]circulenes were synthesized through four-fold electrophilic borylation. The single-crystal X-ray diffraction analysis revealed that the BN-fused tetrathia[8]circulene with peripheral phenyl groups exhibits crystal polymorphism, in which the circulene core adopts both planar and saddle conformations in the solid state. The experimental and theoretical studies revealed that the weaker aromaticity of azaborine compared with benzene renders the flexibility of the BN-fused tetrathia[8]circulenes. 相似文献