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991.
992.
Kevin E. Riley 《International journal of quantum chemistry》2010,110(10):1833-1841
In this work, we study the hydrogen bonds (H‐bonds) involving hydroxyl and amino groups bonded to phenyl and pyrimidine rings (as H‐bond donors). These types of interactions play important roles in the recognition of ligands by proteins and are also important in the design of materials. The effects of aromatic fluorine substitutions on aromatic rings are also investigated, and it is found that these substitutions can have large effects on the hydrogen bonding interactions that occur in our model systems, making them substantially stronger. This finding offers a new mechanism for the modification of these types of interactions, potentially opening new paths in the design of novel pharmaceuticals and materials. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010 相似文献
993.
《Journal of Coordination Chemistry》2012,65(22):3678-3688
Traditional catalytic procedures for oxidation of phenol produce environmentally undesirable wastes. As a consequence, there is a clear demand for development of an environmentally benign catalytic route for the selective oxidation of phenol. A series of zeolite-Y enslaved Mn(III) complexes with Schiff bases derived from vanillin furoic-2-carboxylic acid hydrazone (VFCH), vanillin thiophene-2-carboxylic acid hydrazone (VTCH), ethylvanillin thiophene-2-carboxylic acid hydrazone (EVTCH), and/or ethylvanillin furoic-2-carboxylic acid hydrazone have been synthesized and characterized by physico-chemical techniques. Catalytic oxidations of phenol using 30% H2O2 as an oxidant over [Mn(VTCH)2·2H2O]+-Y, [Mn(VFCH)2·2H2O]+-Y, and [Mn(EVTCH)2·2H2O]+-Y under mild conditions were studied. These zeolite-Y enslaved Mn(III) complexes are stable and recyclable under current reaction conditions. 相似文献
994.
《Journal of Coordination Chemistry》2012,65(17):2995-3011
Reaction between CuCl2 and (Z)-2-(1-(2-(1H-benzo[d]imidazol-2-yl)ethylimino)ethyl)phenol (Hhap-aebmz) derived from o-hydroxyacetophenone (Hhap) and 2-aminoethylbenzimidazole (aebmz) gives [CuII(hap-aebmz)Cl]. Elemental analysis, magnetic susceptibility, spectral (IR and electronic) data, and single crystal X-ray studies confirm the distorted square planar structure of the complex. [CuII(hap-aebmz)Cl] has been encapsulated in the nano-cavity of zeolite-Y and its encapsulation is ensured by various physico-chemical techniques. The encapsulated complex has been used as a catalyst for oxidation of cyclohexene and phenol in the presence of H2O2. With nearly quantitative oxidation of cyclohexene, the selectivity of the oxidation products follows the order, 2-cyclohexene-1-ol (44%)?>?2-cyclohexene-1-one (40%)?>?cyclohexeneoxide (12%)?>?cyclohexane-1,2-diol (4%). Oxidation of phenol (65.7%) gives catechol (66.1%)?>?hydroquinone (32.9%). 相似文献
995.
《Analytical letters》2012,45(2):235-257
Abstract A simple TLC separation and semi-quantitative visual determination method was used to analyse the volatile phenols in the waste water of the petroleum industry and the grain irrigated by the waste water. The phenol in the rice irrigated by the water that contained phenol for artificial preparation was also studied. A preliminary conclusion was obtained, that the grain could absorb volatile phenols from irrigation water. 相似文献
996.
《Analytical letters》2012,45(11):1735-1746
Abstract Nanoscale Pt/RuO2 colloid with carbon paste support was synthesized and used to prepare a modified electrode for phenol detection. The results showed that the Pt/RuO2 catalyst has high activity for electrooxidation of phenol with reduced intermediate polymerization due to its significantly low potential for phenol oxidation. The detection limit was as low as 10?9 mol L?1 for the polishable Pt/RuO2/C paste electrode with good reproducibility. 相似文献
997.
《Analytical letters》2012,45(4):683-695
Abstract A highly selective and sensitive triiodide sensor based on a 2‐(((2‐(((E)‐1‐(2‐hydroxy phenyl) methylidine) amino) phenyl) imino) methyl) phenol with iodine (CTC) as membrane carrier was developed. The electrode revealed a Nernstian behavior over a very wide triiodide‐ion concentration range (5.0×10?8–1.0×10?2 M), and relatively low detection limit (3.0×10?8 M). The potentiometric response is independent of the pH of solution in the pH range of 3.0–10.0. The electrodes manifest advantages of low resistance, very fast response (<12 s), and most importantly, good selectivities relative to a wide variety of inorganic and organic anions, including iodide, bromide, chloride, fluoride, sulfite, sulfate, cyanide, thiocyanate, and acetate. In fact, the selectivity behavior of the proposed triiodide ion‐selective electrode shows great improvements compared to the previously reported electrodes for the triiodide ion. The proposed membrane sensor can be used for at least 6 months without any significant divergences in the potential. The electrode was successfully applied as an indicator electrode in the titration of triiodide with thiosulfate ion. 相似文献
998.
Zu-Pei?LiangEmail author Jian?Li Cheng-Yun?Wang Xi-Shi?Tai 《Journal of chemical crystallography》2009,39(10):708-710
Abstract The title compound 2-(2,3,4-trimethoxy-6-methylbenzylideneamino)phenol (C17H19NO4, M
r = 301.33) was synthesised and characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. The crystal
belongs to monoclinic, space group P21/c, with a = 10.4458(14), b = 8.3870(10), c = 17.780(2) ?, β = 91.102(2)°, V = 1557.4(3) ?3, Z = 4, D
c = 1.285 g/cm3, λ = 0.71073 ?, μ(Mo Kα) = 0.092 mm−1, F(000) = 640. The final refinement gave R = 0.0452, wR(F
2) = 0.1065 for 2,743 observed reflections with I > 2σ(I). X-ray diffraction analysis reveals that the molecule adopts an E configuration at the C=N functional bond. The dihedral angle between the two phenyl rings is 38.3(3)°. The crystal structure
is stabilized by C–H···O, O–H···O and O–H···N hydrogen bonds and π–π stacking interactions.
Graphical Abstract The title compound 2-(2,3,4-trimethoxy-6-methylbenzylideneamino)phenol (C17H19NO4, M
r = 301.33) was synthesised and characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. The crystal
belongs to monoclinic, space group P21/c, with a = 10.4458(14), b = 8.387(1), c = 17.780(2) ?, β = 91.102(2)°, V = 1557.4(3) ?3, Z = 4, D
c = 1.285 g/cm3, λ = 0.71073 ?, μ(Mo Kα) = 0.092 mm−1, F(000) = 640. The final refinement gave R = 0.0452, wR(F
2) = 0.1065 for 2,743 observed reflections with I > 2σ(I). X-ray diffraction analysis reveals that the molecule adopts an E configuration at the C=N functional bond. The dihedral angle between the two phenyl rings is 38.3(3)°. The crystal structure
is stabilized by C–H···O and O–H···O hydrogen bonds and π–π stacking interactions.
相似文献
999.
Liquid phase hydrogenation of phenol over Pt/C catalysts was investigated under conventional conditions and supercritical carbon dioxide (scCO2). The equivalent ration of hydrogen to phenol shows a significant effect on the product selectivity. Hydrogenation of phenol in different solvents was also studied, the experimental results show that polarity of solvents influences the yield of cyclohexanone remarkably, scCO2 has the highest one. Catalytic hydrogenation of phenol in scCO2 or sub-scCO2 was emphatically researched. The result is that near the critical point of CO2 phenol has higher reaction activity than that of normal organic solvents, cyclohexanone has 47% in yield and 87% in selectivity. 相似文献
1000.
(−)-β-Caryophyllene has been converted into three stereoisomers of a new bicyclic compound that is structurally related to the known macrocyclic diterpene, flexibilene, in the same way β-caryophyllene is related to humulene. Key steps are selective cleavage of caryophyllene, addition of a five carbon component by a Wittig reaction and McMurry cyclization. 相似文献