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91.
(Ca,Mg)—Sialon陶瓷在空气及水润滑条件下的磨损机理研究 总被引:7,自引:7,他引:7
利用SRV球-盘磨损试验机考察了一种(Ca,Mg)-Sialon陶瓷在空气及水中的摩擦学性能,并采用EPMA,SEM,EDAX以及XPS等分析手段对其磨损机理做了进一步研究。结果表明:(Ca,Mg)-Sialon陶瓷在水中比在空气中具有更低的摩擦因数,但具有较高的磨损体积损失。 相似文献
92.
用均匀化理论分析蜂窝结构的等效弹性参数 总被引:8,自引:3,他引:8
在线弹性范围内,根据均匀化理论,并结合有限元方法推导出适用于二维周期性结构的均匀化的有限元格式(Homo FEM),计算出不同相对密度下的规则蜂窝结构的等效弹性模量Ee和泊松比νe.同时,利用蜂窝结构的代表胞元模型,用常规的有限元方法(FEM)模拟计算出相应的等效弹性参数.最后将两种数值计算结果与己有的理论公式进行了比较和分析讨论.结果表明:在考察的相对密度全场范围内(0~0.4),HOmO FEM得到的蜂窝结构的 Ee和νe 与 FEM使用平面实体单元模拟计算得到的结果一致吻合,反映出 Homo FEM数值方法的客观准确性和可行性.而 Gibson公式和 W-K得到的等效弹性模量值 Ee只是在较小相对密度的情况下(小于0.15)与数值计算结果吻合.当结构的相对密度较大时,必须考虑胞棱附近区域由应力集中导致的复杂的应力和应变分布的影响. 相似文献
93.
IntroductionDuetotheintrinsiccouplingcharacteristicsbetweenelectricandelasticbehaviors,thatis,appliedmechanicalloadingproduceselasticdeformation ,aswellaselectricfield ,andconverselyelectricfieldcangiverisetoelasticdeformation ,piezoelectricmaterialshave… 相似文献
94.
Both the mechanical and the electrical damages are introduced to study fracture mechanics of piezoelectric ceramics in this paper. Two kinds of piezoelectric fracture criteria are proposed by using the damage theory combined with the well-known piezoelectric fracture experiments of Park and Sun [Fracture criteria of piezoelectric ceramics, J. Am. Ceram. Soc. 78 (1995) 1475-1480]. One is based on a critical state of the mechanical damage and the other on a critical value of a proper linear combination of both the mechanical and the electrical damage variables. It is found that the fracture load predicted, which takes the mechanical damage into account only (mode 1), has greater deviation than predicted result by considering a proper linear combination of the mechanical and the electrical damages (mode 2). And the fracture criterion corresponding to mode 2 presented is shown to be superior to mode 1. It is also demonstrated that the mechanical damage has greater effect on fracture than the electrical damage. 相似文献
95.
Tong-Yi Zhang 《Acta Mechanica Sinica》2002,18(5):537-550
The paper gives an overview on experimental observations of the failure behavior of electrically insulating and conducting
cracks in piezoelectric ceramics. The experiments include the indentation fracture test, the bending test on smooth samples,
and the fracture test on pre-notched (or pre-cracked) compact tension samples. For electrically insulating cracks, the experimental
results show a complicated fracture behavior under electrical and mechanical loading. Fracture data are much scattered when
a static electric field is applied. A statistically based fracture criterion is required. For electrically conducting cracks,
the experimental results demonstrate that static electric fields can fracture poled and depoled lead zirconate titanate ceramics
and that the concepts of fracture mechanics can be used to measure the electrical fracture toughness. Furthermore, the electrical
fracture toughness is much higher than the mechanical fracture toughness. The highly electrical fracture toughness arises
from the greater energy dissipation around the conductive crack tip under purely electric loading, which is impossible under
mechanical loading in the brittle ceramics.
The project supported by an RGC grant from the Research Grant Council of the Hong Kong Special Administrative Region, China 相似文献
96.
Structure Modification Function of g‐C3N4 for Al2O3 in the In Situ Hydrothermal Process for Enhanced Photocatalytic Activity 下载免费PDF全文
Prof. Fa‐tang Li Shao‐jia Liu Ya‐bin Xue Dr. Xiao‐jing Wang Dr. Ying‐juan Hao Dr. Jun Zhao Rui‐hong Liu Prof. Dishun Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(28):10149-10159
Heterojunctions of g‐C3N4/Al2O3 (g‐C3N4=graphitic carbon nitride) are constructed by an in situ one‐pot hydrothermal route based on the development of photoactive γ‐Al2O3 semiconductor with a mesoporous structure and a high surface area (188 m2g?1) acting as electron acceptor. A structure modification function of g‐C3N4 for Al2O3 in the hydrothermal process is found, which can be attributed to the coordination between unoccupied orbitals of the Al ions and lone‐pair electrons of the N atoms. The as‐synthesized heterojunctions exhibit much higher photocatalytic activity than pure g‐C3N4. The hydrogen generation rate and the reaction rate constant for the degradation of methyl orange over 50 % g‐C3N4/Al2O3 under visible‐light irradiation (λ>420 nm) are 2.5 and 7.3 times, respectively, higher than those over pristine g‐C3N4. The enhanced activity of the heterojunctions is attributed to their large specific surface areas, their close contact, and the high interfacial areas between the components as well as their excellent adsorption performance, and efficient charge transfer ability. 相似文献
97.
Lithium‐ion (Li‐ion) cells have gained considerable attention in recent years as a power source for various applications owing to their high voltage, high energy density, low self‐discharge, and excellent cycle life. Polymeric materials play a pivotal role in the processing, performance, and safety of Li‐ion cells. The polymeric materials used in Li‐ion cells include: binder for electrode processing, separator, electrolyte, and electrode active material. Active research is being pursued in all of these areas to improve the energy density, power density, cycle life, and safety of Li‐ion cells. This review article gives an overview of the various polymeric materials used in Li‐ion cells and the recent advances in these materials. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
98.
采用熔融晶化法制备了主晶相为SrF_2的Er~(3+)-Yb~(3+)共掺透明氟氧化物玻璃陶瓷,利用DSC、XRD、SEM、UV-Vis-NIR和荧光光谱对样品的结构、形貌、发光性能进行了测试与表征。研究表明:该体系玻璃最佳热处理温度为620℃,最佳热处理时间为2h,并讨论了Yb~(3+)不同掺杂浓度对Er~(3+)-Yb~(3+)共掺玻璃陶瓷样品上转换发光性能的影响,确定Er~(3+)-Yb~(3+)最佳掺杂浓度比为1∶7,同时观察到了明亮的绿光(522,540 nm)和较弱的红光(656 nm),对Er~(3+)和Yb~(3+)之间的能量传递过程进行了讨论。 相似文献
99.
100.
采用凝胶法分别制备出4.5ZnO-5.5Al2O3-90SiO2(ZAS)以及ZAS[DK]:RE3+ (RE=Eu,Tb,Ce) 透明微晶玻璃。利用X射线衍射仪(XRD)、透射电子显微镜(TEM)和荧光光谱仪(PL)等测试手段,研究了稀土离子掺杂浓度对ZAS微晶玻璃的结构和发光性能的影响。XRD结果表明,ZAS[DK]:RE3+ (RE=Eu,Tb,Ce)微晶玻璃包含ZnAl2O4晶相和SiO2非晶相,ZnAl2O4平均晶粒尺寸约为30 nm,稀土离子的掺杂没有显著改变原来的ZnAl2O4晶体结构。TEM结果表明,900 ℃时ZnAl2O4从ZAS体系中析出。PL光谱显示,Eu3+ 存在 5D0→7F2跃迁,ZAS[DK]:Eu3+在611 nm 处发出强烈的红色光;由于Tb3+ 的5D4→7F5 跃迁,ZAS[DK]:Tb3+在541 nm 处发出明亮的绿色光;ZAS[DK]:Ce3+ 在381 nm处显示了蓝光发射,对应于Ce3+ 的5d→4f 轨道跃迁。ZAS[DK]:RE3+ (RE=Eu, Tb, Ce)的PL发射光谱存在着浓度猝灭现象,Eu3+、Tb3+ 和Ce3+的最佳单掺杂摩尔分数分别为20%、20%和3%。CIE色度图表明,ZAS[DK]: RE3+ (RE=Eu,Tb,Ce)的色坐标分别位于红光、绿光和蓝光区域。实验结果表明,ZAS:RE3+ (RE=Eu,Tb,Ce) 微晶玻璃是一种良好的可用于全色显示的白光LED材料。 相似文献