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991.
SigmaPlot软件在化学实验数据处理中的应用 总被引:1,自引:0,他引:1
SigmaPlot是功能强大的数据分析和科学绘图软件,通过实例,初步介绍了SigmaPlot处理实验数据的方法和结果。结果表明,用SigmaPlot对实验数据作处理,解决了化学实验中数据多、处理麻烦、手工作图误差大等问题,使处理过程简单、快捷,提高了效率和准确性。 相似文献
992.
Chemical reactions and damage are important in the study of constitutive laws for some engineering materials, such as polymers and their composites. In this paper, we have derived a general form of constitutive laws for damaged viscoelastic materials including chemical reactions by the use of irreversible thermodynamics and the Hamilton principle. The experimental results have been obtained for ageing solid propellant materials and compared with the theoretical model. Good agreement is found between the theory and experiments.The project supported by National Natural Science Foundation of China. 相似文献
993.
《Magnetic resonance in chemistry : MRC》2002,40(7):480-482
1H, 13C and 15N NMR chemical shifts of 10 substituted pyrazolo[1,5‐a]pyrimidines were assigned based on DQF 1H, 1H COSY, PFG 1H, 13C HMQC and PFG 1H,X (X = 13C and 15N) HMBC experiments and on literature data. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
994.
995.
J. R. Correia S. Cabral-Fonseca F. A. Branco J. G. Ferreira M. I. Eusébio M. P. Rodrigues 《Mechanics of Composite Materials》2006,42(4):325-338
Results of an experimental research into the physical, chemical, mechanical, and aesthetical changes suffered by pultruded
glass-fiber-reinforced polyester profiles during their testing for accelerated aging under the action of moisture, temperature,
and ultraviolet (UV) radiation are presented. The profiles were submitted to the influence of four different exposure environments:
(i) in an immersion chamber, (ii) in a condensation chamber, (iii) in a QUV accelerated weathering apparatus, and (iv) in
a xenon-arc accelerated weathering apparatus. The results obtained were analyzed regarding the changes in their weight, sorption
ability, tensile and flexural strength characteristics, color, and gloss; the chemical changes were investigated by means
of Fourier-transform infrared spectroscopy. Considerable chromatic changes were observed, especially owing to the UV radiation.
Although some reduction in the mechanical properties was observed, particularly in the immersion and condensation chambers,
the durability tests proved a generally good behavior of this material under the aggressive conditions considered.
Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 4, pp. 463–474, July–August, 2006. 相似文献
996.
We have carried out nonempirical quantum-chemical calculations for five-membered heterocyclic molecules containing O or S
atoms and also P or As atoms in the ring, using RHF/6-31G(d) and MP2/6-31G(d) methods with full optimization of their geometry.
We have studied their electronic and spatial structure and the characteristics of the interaction between atoms in the molecules.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 629–634 April, 2006. 相似文献
997.
P. Indelicato S. Boucard E. Lindroth 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,3(1):29-41
We report on a calculation of K, L and M inner-shell ionization energy in atoms with atomic numbers in the range . Many-body effects are evaluated for all n
=1, 2, and 3 hole states. Those include correlation and effects due to the auto-ionizing nature of the hole states (Auger shift). For
high Z we add recent corrected nuclear polarization, and several second-order vacuum polarization corrections. K and L ionization
energies are compared with experimental X-ray absorption edges measurements. Excellent agreement with rare gazes and metal
vapor measurements is found. We also compare our calculations with X-ray transition energies for all K and L lines that involve
K, L and M holes. Finally we use K X-ray lines to deduce an hydrogenlike 1
s Lamb shift for several heavy elements, with far better accuracy than has been obtained by direct measurements of hydrogenlike
ions.
Received: 25 February 1998 / Accepted: 31 March 1998 相似文献
998.
Sheng Pingxing Hu Zhili 《Annals of Differential Equations》2007,23(3):332-341
In this paper,we discuss the reaction model of tri-molecules and the exi- stence of periodic reaction under certain original density conditions of two ob- jects without diffusion phenomena.We prove that the periodic reaction exhibit some chemical phenomena that violate the second law of thermo-mechanics. Finally,we research similar properties and phenomena concerning Belousov- Zhabotinsky reaction model. 相似文献
999.
Advances in the chemistry of Astragalus triterpenoids based on worldwide literature appearing mainly after 1988 were reviewed. The review was dedicated to the memory of Professor N. K. Abubakirov. 相似文献
1000.
Joseph E. Earley 《Foundations of Chemistry》2004,6(3):137-160
One of the main functions that introductory chemistry courses havefulfilled during the past century has been to provide evidence for the generalvalidity of 'the atomic hypothesis.' A second function has been to demonstratethat an analytical approach has wide applicability in rationalizing many kindsof phenomena. Following R.G. Collingwood, these two functions can be recognizedas related to a philosophical 'cosmology' (worldview, weltanshauung) thatbecame dominant in the late Renaissance. Recent developments in many areasof science, and in chemistry, have emphasized the central importance of understandingsynthetic, developmental, and evolutionary aspects of nature. This paperargues that these scientific developments, and changes in other aspects of culture,amount to a widespread shift to an alternative cosmology, a quite different generalworldview. To the extent that this is the case, introductory chemistry coursesought to be changed in fundamental ways. Rather than having a main focus onanalysis to microscopic components, introductory chemistry instruction shouldemphasize current scientific understanding of the (synthetic) evolutionary originsof the present world. This altered approach would provide good preparation forfuture professional work, while also making better contact with the perceivedconcerns of students. 相似文献