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41.
燃煤烟气中AsSePb的形态分布及SCl元素对其形态分布的影响 《燃料化学学报》2003,48(11):1298-1309
基于化学热力学平衡分析方法,计算分析了燃煤烟气中重金属As、Se、Pb的形态分布规律,研究了S、Cl等元素对As、Se、Pb的形态分布规律的影响。结果表明,氧化性气氛下,As以As2O5、As4O6、AsO等氧化物的形式存在;Se主要以SeO2形式存在;Pb在1000 K以下主要是固态PbSO4,1200 K以上为气态PbO。还原性气氛下,As在较低温度时为固态As2S2,900-1400 K以As2、AsS、AsN气体共存,2000 K以上全部转化为气态AsO。Se在1100 K以下主要以气态H2Se存在,1100 K开始生成SeS和Se2气体,1800 K时主要是气态Se和少量气态SeO;Pb在中低温时主要是PbS,1800 K以上气态Pb为主要存在形态。S在还原性气氛下增大了AsS(g)、PbS(g)、SeS(g)的比例,氧化性气氛下对As、Se、Pb形态分布基本无影响;Cl无论在氧化还是还原气氛下对As、Se影响均较小,但对Pb的形态分布影响较大。 相似文献
42.
Sylvia Pulmannová 《International Journal of Theoretical Physics》2003,42(5):907-919
Tensor products of quantum logics and effect algebras with some known problems are reviewed. It is noticed that although tensor products of effect algebras having at least one state exist, in the category of complex Hilbert space effect algebras similar problems as with tensor products of projection lattices occur. Nevertheless, if one of the two coupled physical systems is classical, tensor product exists and can be considered as a Boolean power. Some applications of tensor products (in the form of Boolean powers) to quantum measurements are reviewed. 相似文献
43.
《Magnetic resonance in chemistry : MRC》2003,41(9):731-734
An NMR study of one new and several known abietane diterpenes isolated from the roots of Aegiphila lhotzkyana is described. In addition to 1D NMR, several 2D shift‐correlated NMR pulse sequences (1H–1H‐COSY, NOESY, HMQC and HMBC) were used to establish all the structures, and unambiguously perform the 1H and 13C chemical shift assignments of the new natural diterpene and three derivatives, the NMR data for which have not been reported previously. Revision of current data assignment for teuvincenone H is also suggested. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
44.
Dinesh Topwal U. Manju Sugata Ray S. Raj D. D. Sarma S. R. Krishnakumar M. Bertolo S. La Rosa G. Cautero 《Journal of Chemical Sciences》2006,118(1):87-92
Disordered Sr2FeMoO6 shows a drastic reduction in saturation magnetization compared to highly ordered samples, moreover magnetization as a function
of the temperature for different disordered samples shows qualitatively different behaviours. We investigate the origin of
such diversity by performing spatially resolved photoemission spectroscopy on various disordered samples. Our results establish
that extensive electronic inhomogeneity, arising most probably from an underlying chemical inhomogeneity in disordered samples, is
responsible for the observed magnetic inhomogeneity. It is further pointed out that these inhomogeneities are connected with
composition fluctuations of the type Sr2Fe1+x
Mo1-x
O6 with Fe-rich (x > 0) and Mo-rich (x < 0) regions.
Dedicated to Prof J Gopalakrishnan on his 62nd birthday. 相似文献
45.
An effect of Berry’s phase on the NQR spectrum of the rotating powder sample is described and applied for the determination of the electric field gradient asymmetry. The proposed method involves the analysis of the frequency singularities in the NQR powder patterns of the rotating samples. The Berry’s phases for the eigenstates, associated with an adiabatically changing quadrupole hamiltonian, are calculated for nuclei with a spin I = 3/2 and I = 1 as a function of the asymmetry parameter. 相似文献
46.
The major achievements of the G. F. Gauze Scientific-Research Institute of New Antibiotics, Russian Academy of Medical Sciences, over the last 50 years are reviewed. The structures of antibiotics and related compounds discovered at the Institute and important for medical practise and/or of theoretical interest as new compounds with high biological activity are described.Dedicated to the memory of Director of the G. F. Gauze Scientific-Research Institute of New Antibiotics, Russian Academy of Medical Sciences, and Corresponding Member of the Russian Academy of Medical Sciences Prof. Yu. V. Dudnik (1938–2003).Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1603–1618, November, 2004. 相似文献
47.
S. Azimpour M. Chaichi M. Toomanian 《Journal of Contemporary Mathematical Analysis (Armenian Academy of Sciences)》2007,42(5):270-277
A 4-dimensional Walker metric on a semi Riemanian manifold M, for the canonical metric with c = 0, have been investigated by M. Chaichi, E. García—Río and Y. Matsushita. The paper generalizes these notions to the case of constant c ≠ 0. Specially the form of defining functions of this metric in locally conformally flat 4-dimensional Walker manifolds is found. 相似文献
48.
D. Sasireka E. Palaniyandi K. Iyakutti 《International journal of quantum chemistry》2004,99(3):142-152
Local lattice relaxation of substitutional donors in silicon investigated using self‐consistent multiple scattering Xα (MSXα) method within the framework of the standard muffin‐tin potential approximation is extended to substitutional donors in germanium and substitutional acceptors in both silicon and germanium. Incorporating the effect of lattice relaxation surrounding the impurity makes the model suitable for both shallow and deep levels. Chemical trends of some aspects of impurity states, such as local lattice relaxation and charge transfer, of the impurities both in silicon and germanium are inferred. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2004 相似文献
49.
设H为复的可分无限维Hilbert空间,称有界线性算子T为强不可约的,如果与T可交换的幂等算子只有0和I.王宗尧、蒋春澜、纪有清等人证明了在任何一个套的套代数中都存在大量的强不可约算子,并且找到了它们的酉轨道闭包.本文考虑有限个套的张量积的代数中强不可约算子的存在性问题。证明了:对复平面上任何一个连通完备集σ、总存在一个对角算子N和它的一个范数可以任意小的紧摄动T=X+K,使得T是一个强不可约算子、T在有限个良序套的张量积的代数中,并且σ(T)=σlre(T)=σ(N)=σlre(N)=σ进一步,文章还对具有单点谱的算子和良序套与正交补为良序套的张量积的代数进行了讨论,得到了一些结果. 相似文献
50.
Gabor Schmera Adi Bulsara David Pierson Frank Moss Enrico Di Cera 《Journal of statistical physics》1993,71(5-6):1179-1190
We consider the class of experiments which can be characterized by a Fokker-PIanck dynamics corresponding to the overdamped motion of a state point in a suitable stochastic potential. We assume that the general form of the potential is known (or can be guessed with reasonable accuracy), but that its parameters are to be determined experimentally by measurements made with a noisy instrument. This possible method for determining the potential parameters, which exploits the system's own internal stochastic motion in order to explore rapidly its available parameter space, is substantially more efficient than traditional methods involving time averages of single point measurements, and yet does not appear to have been previously considered. The method could be important when, for example, the experiment must be completed in a limited time owing either to the expense of the experimental materials or to the temporary stationarity of the preparation, situations which are commonly encountered in experimental biochemistry and biology. 相似文献