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21.
FengSHI HongYangLI XiaoJunPENG RongZHANG XiaoQiangCHEN JiangLiFAN LiChengSUN 《中国化学快报》2004,15(12):1407-1410
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied. 相似文献
22.
Grigor'ev S. A. Kalinnikov A. A. Porembskii V. I. Baranov I. E. Borisova E. V. Fateev V. N. 《Russian Journal of Electrochemistry》2004,40(11):1188-1192
A two-dimensional mathematical model for the transport of reactants in a fuel cell with a solid polymer electrolyte is developed. The model is used for analyzing spatial distributions of the concentration of reactants and current density over the cell. The effect of the catalytic-layer activity, reactant speed, bipolar-plate geometry, thickness and porosity of current collector and/or gas-diffusion sublayer, and the reaction mixture composition on the fuel cell efficiency is estimated theoretically and experimentally. 相似文献
23.
Houman Borouchaki Abdelhakim Cherouat Patrick Laug Khemais Saanouni 《Comptes Rendus Mecanique》2002,330(10):709-716
The analysis of mechanical structures using the Finite Element Method in the framework of large elastoplastic strain, needs frequent remeshing of the deformed domain during computation. Indeed, the remeshing is due to the large geometrical distortion of finite elements and the adaptation to the physical behavior of the solution. This paper gives the necessary steps to remesh a mechanical structure during large elastoplastic deformations with damage. An important part of this process is constituted by geometrical and physical error estimates. The proposed method is integrated in a computational environment using the ABAQUS/Explicit solver and the BL2D-V2 adaptive mesher. To cite this article: H. Borouchaki et al., C. R. Mecanique 330 (2002) 709–716. 相似文献
24.
H.-J. Sue E. I. Garcia-Meitin N. A. Orchard 《Journal of Polymer Science.Polymer Physics》1993,31(5):595-608
The fracture behavior of a core-shell rubber (CSR) modified epoxy is investigated using both fracture mechanics and microscopy tools. The CSR-modified epoxy is found to be toughened via numerous line-array cavitations of the CSR particles, followed by plastic flow of the epoxy matrix. The toughening effect via the above craze-like damage process is found to be as effective as that of the well-known widespread rubber cavitation/matrix shear yielding mechanisms. The conditions for triggering the craze-like damage appear to be both stress state and rubber concentration dependent. The type of rubber tougheners utilized also plays a critical role in triggering this rather unusual craze-like damage in epoxy systems. © 1993 John Wiley & Sons, Inc. 相似文献
25.
W. Hufenbach R. Böhm A. Langkamp L. Kroll T. Ritschel 《Mechanics of Composite Materials》2006,42(2):151-162
The basic damage and failure models of multiaxially reinforced composites with a thermoplastic matrix are presented and verified.
Within the framework of continuum damage mechanics, a phenomenological model is introduced, where the damage is defined as
a change in the elasticity tensor. For damage identification, a specific ultrasonic device was developed. A combination of
an immersion set-up and a contact coupling device formed a system for an efficient determination of stiffness-tensor components
from convenient sets of velocity measurements. Linked to a tensile machine, it allowed us to measure the anisotropic damage
of the new materials group caused by tensile loading.
Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 2, pp. 221–234, March–April, 2006. 相似文献
26.
The kinetics of reactions occurring at the gas-exposed surfaces of charged mixed ionic electronic conductors (MIECs) are examined
from theoretical first principles. Analysis based on the classical electrochemical potential-transition state theory model
reveals that the nature of the reactions is electrochemical in general. However, the influence of the surface potential on
the reaction rate is opposite for adsorption and incorporation reactions. Two-dimensional finite volume models of an MIEC
as working electrode in a half-cell configuration are presented. The results for a simple, two-step reduction process show
that the effect of the surface potential on the rate of reactions is minimal for incorporation-limited reactions but more
influential for adsorption-limited reactions.
An erratum to this article is available at . 相似文献
27.
分析了在“用板式电势差计测量电池的电动势和内阻”实验中 ,由于待测干电池的电动势和内阻在实验过程中均不为恒定值而引起的误差 ,依据电化学理论和电阻构成解释了实验现象 ,并给出了实验改进方案 . 相似文献
28.
29.
30.
Positions and intensities for 453 spectral lines in 12 rovibrational bands of 12C16O2 have been determined between 3700 and 3750 cm−1. At three temperatures (294, 500, and 698 K) eight spectra have been recorded at a pressure around 5 mbar and for an absorption path of about 190 cm−1 using a Bomen DA3 Fourier transform spectrometer (4 × 10−3 cm−1 resolution). Some of the measured positions and intensities can be compared with recent experimental results that validate the experimental set-up and the data analysis procedure. The results are also compared with the values listed in the HITRAN 2000 database. If the agreement is generally good, discrepancies are observed for three hot bands. 相似文献