箬叶水溶性多糖的色谱研究

采用纸色谱和气相色谱法研究了从湖北恩施地区生长的箬竹叶中分离纯化的水溶性多糖的单糖组成。在纸色谱分析中,探讨了四种溶剂系统和三种显色剂体系在单糖定性鉴定中的应用,发现展开剂正丁醇∶吡啶∶水（６∶４∶３）和显色剂苯胺－邻苯二甲酸分离效果最好,并可区分五碳和六碳糖。气相色谱分析采用武汉大学研制的开链冠醚为固定相,结果表明其单糖组成为鼠李糖：１４％,岩藻糖：５３％,甘露糖：１２％,葡萄糖：８％,半乳糖：１３％,与文献报道的日本竹叶多糖极不相同。     

活性炭过滤色谱及其在酪氨酸分离中的应用

The basic principles of activated charcoal filtration chromatography and its use in recovering L-tyrosinefrom L-cystine waste were presented in ths paper.     

The calibration of activated charcoal detectors in a small Rn exposure chamber

Passive methods for radon measurements, especially those based on radon adsorption, require observation of proper calibration methods.

The calibration method for diffusion-barrier charcoal detectors in a small (211 dm³) radon chamber has been proposed. The theoretical dependence of radon concentration vs. time inside the chamber during the exposure of charcoal detectors has been obtained and verified experimentally. For this purpose, the chamber volume as well as diffusion and adsorption parameters of the detector were taken into consideration.

For two types of detectors the conformity of calibration factors obtained in two ways: calculated from theoretical points (550 or 683 Bqm⁻³/cps depending on detector type) and from experimental points (553 or 691 Bqm⁻³/cps), was achieved.

The proposed method makes it possible to calibrate different kinds of radon-adsorbing detectors (not only charcoal canisters) in small chambers without the necessity of using any reference, active device.     

Anaerobic upflow fixed-film bioreactor for biomethanation of salty cheese whey

In order to develop a suitable reactor for the biomethanation of high-strength salty cheese whey, the performance of anaerobic upflow fixed-film reactors packed with different support materials, such as charcoal, gravel, brick pieces, pumicestones, and PVC pieces, has been studied. The charcoal-bedded reactor gave the best performance, with the maximum gas production (3.3 L/L digester/d) and an enriched methane content (69% CH₄). Temperature and hydraulic retention time were optimized, with the ultimate aim of improving biomethanation. Maximum gas production (3.3 L/L digester/d) was achieved at a hydraulic retention time of 2 d at 40°C.     

晶界弛豫研究50年

文章综述了我国科学工作者５０年来关于晶界弛豫研究的早期开拓和近期发展．前者包括扭摆内耗仪的发明、晶界内耗峰的发现和无序原子群晶界模型的提出．后者包括澄清了关于晶界内耗峰来源的争论,揭示了晶界弛豫具有一个临界温度,从而提出了一个适合于各种温度的综合的晶界模型．一个最重要的进展是关于竹节晶界内耗峰的发现与其机理的阐明,从而揭示了晶界附近的位错亚结构能够影响晶界本身的性质和结构．这对于研究多晶金属的力学性质提供了一个广阔的途径．另外,晶界与邻域位错的非线性交互作用的发现,为奠定非线性滞弹性这门新学科提供了实验基础     

竹叶提取物的抗氧化活性研究

一般认为黄酮是竹叶提取物中抗氧化作用的有效成分,黄酮含量越高,抗氧化能力越强[1-3]。本实验对不同溶媒竹叶提取物的抗氧化能力做了比较研究,发现抗氧化作用与黄酮含量并不完全成正比关系;并通过进一步的定性实验,证明黄酮并不是竹叶提取物中的唯一的抗氧化有效成分,还有其它     

紫外光下毛竹的自由基与光电子能谱分析

分析了紫外光照射下毛竹自由基的变化规律和表面化学组成及结构的变化.利用电子自旋共振波谱和X射线光电子能谱技术,分别测量紫外光辐照后毛竹颗粒的自由基波谱和X射线光电子能谱.结果表明:毛竹自由基的光谱分裂因子g=2.003 3,自由基的强度随着辐照时间按Y=1-e-b,Pt规律增加;紫外光照60 min后毛竹表面O/C原子比稍有增加,C-C和C-H含量增加,C-O和C=O含量减少,-O-C=O含量增加为原来的3倍左右,说明毛竹表面生成了一些含氧官能团或碳的氧化态增高.     

Comparative Studies on the Development of a 188W-188Re Generator

A comparative study on the sorption behaviour of tungsten and rhenium between anion exchange resin, charcoal and alumina and aqueous media of HNO₃, HCl and NaCl were carried out. The equilibrium distribution coefficient obtained for the different systems were evaluated and discussed in terms of the separation factor between W and Re. It is found that the systems based on alumina and HCl or NaCl are the most promising systems to be used for development of ¹⁸⁸W-¹⁸⁸Re generator. The capacity of a chromatographic column loaded with alumina for ¹⁸⁸W from 0.01 M HCl, 0.7% NaCl and 1.2% NaCl was found to equals 75.3, 91.0 and 126.0 mg/cm, respectively. A recommended procedure was adopted for ¹⁸⁸W-¹⁸⁸Re generator.

Es wurde eine Vergleichsuntersuchung zum Sorptionsverhalten von W und Re zwischen einem Anionenaustauscherharz einer Aktivkohle und einer Tonerde und den wüβirigen Lösungen von HN0₃, HCl and NaCl ausgeführt. Die Gleichgeiwichlsverteilungskoeffizienten der unterschiedlichen Systeme wurden bestimmt und als Trennfaktoren zwischen W und Re diskutiert. Es wurde gefunden, daβ sich das System Tonerde/HCl oder NaCl sehr als Trennsystem für die Entuwicklung eines ¹⁸⁸W¹⁸⁸Re-Generators eignet. Die Kapazitäten einer mit Tonerde gefüllten Säule für ¹⁸⁸W mit 0.01 M HCl, 0.7% NaCl und 1.2% NaCl betrugen entsprechend 75.3, 90.0 und 126.0 mg/cm. Es wird eine geeignete Trennmethode für einen ¹⁸⁸.¹⁸⁸ Re-Generator empfohlen.     

Effect of Alkali Treatment on Structure and Mechanical Properties of Acrylonitrile–Butadiene–Styrene/Bamboo Fiber Composites

The preparation and properties of wood–plastic composites (WPCs) based on acrylonitrile–butadiene–styrene (ABS) and bamboo fibers (BFs) are described. The BFs were first modified by alkali treatment in order to improve their adhesion to an ABS matrix. The BF modifications were monitored by Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Styrene–maleic anhydride (SMA) copolymer, as a compatibilizer, was added to both the untreated and alkali-treated composites. The changes in the structure and the properties resulting from these treatments were observed by the SEM and mechanical tests. The experimental results indicated that both the alkali treatment of the BF and the inclusion of the SMA copolymer improved the interactions between the BF and ABS matrix, and promoted better mechanical properties of the composites.     

竹炭磺酸催化一锅三组分合成α-氨基膦酸酯

以新鲜竹材为原料,经炭化和磺化制得的竹炭磺酸催化各种芳醛、芳胺和亚膦酸二乙酯一锅三组分合成α-氨基膦酸酯.结果表明:该固体酸具有催化性能好、操作简便、来源广泛和可重复利用等优点.