首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   883篇
  免费   38篇
  国内免费   106篇
化学   674篇
晶体学   3篇
力学   2篇
综合类   27篇
数学   218篇
物理学   103篇
  2023年   5篇
  2022年   5篇
  2021年   16篇
  2020年   11篇
  2019年   9篇
  2018年   10篇
  2017年   16篇
  2016年   18篇
  2015年   16篇
  2014年   25篇
  2013年   58篇
  2012年   44篇
  2011年   33篇
  2010年   40篇
  2009年   39篇
  2008年   35篇
  2007年   47篇
  2006年   41篇
  2005年   51篇
  2004年   61篇
  2003年   39篇
  2002年   42篇
  2001年   26篇
  2000年   36篇
  1999年   25篇
  1998年   25篇
  1997年   23篇
  1996年   20篇
  1995年   11篇
  1994年   14篇
  1993年   14篇
  1992年   22篇
  1991年   17篇
  1990年   6篇
  1989年   7篇
  1988年   6篇
  1987年   9篇
  1986年   13篇
  1985年   9篇
  1984年   7篇
  1983年   3篇
  1982年   10篇
  1981年   10篇
  1980年   11篇
  1979年   4篇
  1978年   7篇
  1977年   5篇
  1976年   17篇
  1973年   4篇
  1972年   2篇
排序方式: 共有1027条查询结果,搜索用时 31 毫秒
81.
In Knowledge Discovery in Databases (KDD)/Data Mining literature, interestingness measures are used to rank rules according to the interest a particular rule is expected to evoke. In this paper, we introduce an aspect of subjective interestingness called item-relatedness. Relatedness is a consequence of relationships that exist between items in a domain. Association rules containing unrelated or weakly related items are interesting since the co-occurrence of such items is unexpected. Item-Relatedness helps in ranking association rules on the basis of one kind of subjective unexpectedness. We identify three types of item-relatedness – captured in the structure of a fuzzy taxonomy (an extension of the classical concept hierarchy tree). An item-relatedness measure for describing relatedness between two items is developed by combining these three types. Efficacy of this measure is illustrated with the help of a sample taxonomy. We discuss three mechanisms for extending this measure from a two-item set to an association rule consisting of a set of more than two items. These mechanisms utilize the relatedness of item-pairs and other aspects of an association rule, namely its structure, distribution of items and item-pairs. We compare our approach with another method from recent literature.  相似文献   
82.
高频地波雷达下的多目标跟踪数据处理   总被引:1,自引:0,他引:1  
根据高频地波雷达监测海上低速移动目标的要求及该类雷达的特点,提出了一种与高频地波雷达目标跟踪相适应的多目标跟踪数据处理方案。在该方案中对BTC(bayes tracking confirm)方法与BTT(bayes tracking termination)方法进行了改进,解决了上述两种方法在高频地波雷达实际应用中存在的问题。提出了贝叶斯准则与次数判定相结合的跟踪起始和终结方法。模拟结果表明,该方案能够稳定、有效地实现高频地波雷达密集回波下的多目标跟踪。  相似文献   
83.
We study (generalized) designs supported by words of given composition. We characterize them in terms of orthogonality relations with Specht modules; we define some zonal functions for the symmetric group and we give a closed formula for them, indexed on ordered pair of semi-standard generalized tableaux: Hahn polynomials are a particular case. We derive an algorithm to test if a set is a design. We use it to search designs in some ternary self-dual codes.  相似文献   
84.
For solutions of the complexes of phthalocyanine (PhC) with magnesium (Mg-PhC) and of tetrachloromethyl-PhC with zinc (Zn-PhCCh) in mixtures of glycerin with dimethyl formamide (DMF) and for Zn-PhCCh in toluene and DMF it has been found that the electron absorption spectra substantially depend on the substance concentration. It is shown that these changes are attributable to the association of the molecules of pigments. The number of molecules in the associates and the equilibrium constants for this association are determined. The formation of the trimers of Mg-PhC in binary solutions and the dimers of Zn-PhCCh in toluene, DNF, and binary solutions has been established. It has been found that on association the Q absorption bands of the pigments shift to shorter wavelengths as compared to the bands of the monomers. For the Mg-PhC trimers, the shift is = 1410 cm–1, while for the Zn-PhCCh dimers it is 990 cm–1 in toluene, 930 cm–1 in DMF, and 925 cm–1 in the mixture of DMF with glycerin. It is concluded that the structure of the trimers and dimers is of the type of a stack in which molecules are arranged in parallel one above the other at a distance of 3.5 to 4.0 Å between the planes of the molecules. In association, the fluorescence intensity of the pigments decreases substantially (the decrease corresponds to the decrease in the concentration of the monomer molecules of phthalocyanines), with the fluorescence spectra remaining unchanged. Consequently, the associates of the pigments do not display pronounced fluorescence.  相似文献   
85.
Let V and W be n-dimensional vector spaces over GF(2). A function Q : V W is called crooked (a notion introduced by Bending and Fon-Der-Flaass) if it satisfies the following three properties:
We show that crooked functions can be used to construct distance regular graphs with parameters of a Kasami distance regular graph, symmetric 5-class association schemes similar to those recently constructed by de Caen and van Dam from Kasami graphs, and uniformly packed codes with the same parameters as the double error-correcting BCH codes and Preparata codes.  相似文献   
86.
A new acid‐labile polymer having acetal moieties in the main chain was synthesized by polycondensation of poly (ethylene glycol) (PEG) and lilial, an aldehyde widely used in fragrance applications. The hydrophobicity of the resulting acetal moiety and the hydrophilicity of the PEG chain allowed the polyacetal to exhibit amphiphilicity. The polyacetal derived from PEG having weight average molecular weight (Mw) of 1000 (PEG1000) was soluble in water and self‐associated to form associates in water. The polyacetals were hydrolyzed in acidic aqueous solutions to release hydrophobic lilial from the systems. The release rate of aldehyde from the polyacetal derived from PEG1000 was higher than that from the polyacetal derived from PEG having Mw of 400 (PEG400). These results supported that the release rate of lilial can be controlled by the chain length of PEG, on which hydrophilicity of polyacetal depends. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011  相似文献   
87.
Abstract

The acrylamide copolymer with acrylamide as its main monomer is a modified polyacrylamide. In addition, the acrylamide copolymer is generally to dissolve or swell in water and can be used as thickener, dispersant, flocculant and so on. Therefore, using Acrylamide AM, 2-acrylamide-2-methyl propanesulfonic acid AMPS, dimethyldodecyl (2-acrylamidoethyl) ammoniumbromide AQ12 and vinyltriethoxysilane VTEO as raw materials so that a series of four-membered acrylamide copolymers are prepared in aqueous solution polymerization. The amphoteric structure in the polymer has a unique anti-polyelectrolyte behavior when it is electrically neutral, which can significantly improve the salt resistance of the aqueous polymer. In addition, the hydrolysis of the vinyltriethoxysilane containing silicon structure by hydrophobic association can improve the temperature resistance of the polymer. The optimal reaction conditions were determined by orthogonal experiment: the reaction temperature was 10?°C; the initiator concentration was 0.05?mol%; the monomer concentration was 25?wt% and the pH was 7. Properties of polymer solution indicated that the series of tetra-copolymer possessed salt-tolerant and heat-resisting performances. As an oil displacing agent, it can significantly improve the efficiency of oil displacement, and particularly highlights the effect of 4-member copolymer as an oil displacing agent.  相似文献   
88.
Chemical shifts (c.s.) of 1H nuclei in methanol are measured for methanol-benzene and methanol-phenanthrene systems. A method to determine the equilibrium constant of the molecular association reaction by NMR spectroscopy data is proposed for systems with low solubility of a compound when the dependence of c.s. on the composition is close to a straight line. The equilibrium constants for the formation of molecular complexes in methanol-benzene and methanol-phenanthrene systems are found.  相似文献   
89.
The physiological functions of the two ions, Ca2+ and H+, in controlling mechanical properties of plant cell wall are reviewed. The interactions of these ions with major cell wall polysaccharides during cell growth and development are described. Experimental results for Ca2+/H+-induced molecular associations of some polysaccharides in solutions are also given. This article aims to bridge the understandings of molecular associations in solutions (in vitro) with those occurring in cell wall matrix of high order structure (in vivo).  相似文献   
90.
Conductance data are reported for NaI, KI, RbI, CsI, NH4I, NaClO4, and KClO4 in propylene carbonate at 25°C in the concentration range 1×10–4 –8.3×10–3M. Analysis of the data with the current conductance theories indicates negligible ion-association, strong cation-solvent and weak anion-solvent interactions.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号