双振动合成仪器的设计

指出了用示波器演示双振动合成的不足，设计了BS—Ⅱ型双频调相信号仪，并给出了应用该仪器获得的部分实验图象。     

Predicting vibration signals of automobile engine using chaos theory

Condition monitoring and life prediction of the vehicle engine is an important and urgent problem during the vehicle development process. The vibration signals that are closely associated with the engine running condition and its development trend are complex and nonlinear. The chaos theory is used to treat the nonlinear dynamical system recently. A novel chaos method in conjunction with SVD (singular value decomposition)denoising skill are used to predict the vibration time series. Two types of time series and their prediction errors are provided to illustrate the practical utility of the method.     

受迫振动演示实验装置

本文叙述用示波器显示来演示受迫振动的实验装置，可直观地向学生展示受迫振动的幅频特性和相频特性。     

Analysis of nonlinear sliding structures by modified stochastic linearization methods

Probabilistic characteristics of a sliding structure is investigated by using new versions of stochastic linearization technique. The structure is composed of base part and upper part, which are connected to each other in a spring-damping system. Coulomb friction between the base structure and earth ground is considered. Two alternative versions of stochastic linearization approach, suggested by X. Zhang and I. Elishakoff, respectively, are applied to such a sliding structure to evaluate its statistical properties. Compared with the results of Monte Carlo simulation, the two new approaches are performing much better than the conventional one in their applications to the sliding structure. Moreover, numerical results indicate that the criterion proposed by Elishakoff turns out to be superior to all other versions in the problem under study. Numerical results also suggest that the entire structure may be replaced by the rigid body in the sliding problem as long as the difference of velocity responses are considered less important than those of displacement responses.     

2E－不饱和酰胺的立体选择合成法

以二（苯腈）－二氯化钯为催化剂，在固液相转移条件下，通过芳卤与Ｎ，Ｎ－二乙基丙烯酰胺发生偶联反应，生成了Ｅ式α，β－不饱和酰胺。碘代芳烃的偶联产率较高，从而建立了简便的２Ｅ－不饱和酰胺立体选择合成法。     

1-烃基-1-硅杂环丁烷的合成及其Si—H键伸缩振动频率与结构关系的研究

硅杂环丁烷在有机硅化学中是一类非常重要的小分子环系化合物。由于硅杂环丁烷和环丁烷的环张力相似,因而显示出较高的反应活性。例如能与某些试剂作用,生成开环产物;在光解或热解条件下,产生具有Si=C结构的高活性中间体,可用以合成多种有机硅化合物。     

吡啶酰胺在Cd(Ⅱ)存在下的醇解反应及结构表征

X-射线晶体结构分析表明,在90℃的水热条件下,N-(8-喹啉基)吡啶-3-酰胺在Cd²⁺的存在下发生醇解。醇解产物为8-氨基喹啉(HL₁)和吡啶-3-羧乙酯(HL₂),它们与Cd(Ⅱ)配位形成四方锥型化合物。该配合物为单斜晶系,空间群P2₁/c,a=18.1089(1)?,b=8.9986(1)?,c=19.3070(2)?,β=113.085(1     

Synthesis and characterization of new thermally stable copoly(ester–amide)s from diester–dicarboxylic acids

Three new aromatic diester–dicarboxylic acids containing furan rings, namely, benzofuro[2,3-b]benzofuran-2,9-dicarboxyl-bis-phenyl ester-4,4^′-dicarboxylic acid, benzofuro[2,3-b]benzofuran-2,9-dicarboxyl-bis-phenyl ester-3,3^′-dicarboxylic acid and benzofuro[2,3-b]benzofuran-2,9-dicarboxyl-bis-naphthyl ester-2,2^′-dicarboxylic acid were synthesized by the reaction of benzofuro[2,3-b]benzofuran-2,9-dicarbonyl chloride with 4-hydroxybenzoic acid, 3-hydroxybenzoic acid and 3-hydroxy-naphthalene-2-carboxylic acid, respectively. Diester–dicarboxylic acids were characterized by FT-IR and NMR spectroscopy and elemental analyses. Then, these monomers were converted to aromatic copoly(ester–amide)s by their reaction with various aromatic diamines via the direct polycondensation. These polymers were characterized by viscosity measurements, solubility tests, FT-IR, Ultraviolet and ¹H-NMR spectroscopy and thermogravimetry. The polymers with inherent viscosities in the range of 0.16–0.37 dl/g in dimethyl sulfoxide at 30 °C were obtained in high yield. Most of them dissolved readily at room temperature in polar solvents. The synthesized copoly(ester–amide)s possessed glass-transition temperatures from 210–255 °C. The copoly(ester–amide)s exhibited excellent thermal stabilities and had 10% weight loss at temperature above 295 °C under nitrogen atmosphere.