Total Synthesis and Biological Evaluation of Heliolactone

Strigolactones are phytohormones, which affect diverse aspects of plant growth and development with potential application in modern agriculture. Recently, heliolactone has been isolated as a non‐canonical type of strigolactone from the root exudates of sunflower, and it could be involved in signaling in the rhizosphere as well as in planta. However, its biological activity is yet to be evaluated, due to its relative chemical instability and its low natural abundance. Herein, we describe the gram‐scale synthesis of heliolactone and its derivatives by using Stille cross‐coupling as the key bond‐forming reaction, and we disclose some of their biological activities (soil stability, binding ability to strigolactone receptor, corn germination, sunflower germination, Orobanche cumana germination and leaf senescence) in comparison with other canonical and non‐canonical strigolactones.     

基于无线数传技术的智能农机载高光谱采集系统的研究

为了解决精确农业中高密度的、全面的农田信息采集、数据无线传输和实时处理分析的需要,文章中所讨论的系统利用计算机技术和无线数传技术对GPS, GIS和RS进行有机集成,一方面系统通过AT89lv52单片机,使差分GPS和高光谱仪有机集成,能为采集到的光谱数据提供高精度的空间位置属性,实现光谱数据采集、定位一体化;另一方面利用nRF905数传模块实现数据采集控制系统与微机的数据信息和控制信息互传;同时利用Visual Basic和Map Objects控件集成GIS,实现了具有空间属性的光谱数据可视化管理和分析处理,实时地显示动点轨迹、各图层对应点属性,计算作物微分光谱和植被指数NDVI等功能,为专家系统和决策支持系统提供充足的信息。     

Risk programming for agricultural resource allocation: A multidimensional risk approach

This paper develops an approach to deal with risk in agricultural decisions. Although the model is in line with the Prospect ranking theory and the Partitioned multiobjective risk method, which recognise the multidimensional character of any risk measure taken in agricultural decisionmaking problems, its behavioural hypothesis and analytical development are totally different. The way in which the approach works is illustrated through a simple but wellknown example in agricultural planning.     

基于GIS和禁忌搜索集成技术的农产品物流配送路径优化

分析农产品物流配送模式,对带时间窗的车辆路径问题进行描述,建立有时限的配送路径优化模型,应用GIS与禁忌搜索算法集成技术求解该模型,开发农产品物流配送路径优化系统,并以晋安区农产品物流配送基础数据为范例,进行系统的初步应用研究.     

Investment and the dynamic cost of income uncertainty: The case of diminishing expectations in agriculture

This paper studies optimal investment and the dynamic cost of income uncertainty, applying a stochastic programming approach. The motivation is given by a case study in Finnish agriculture. The investment decision of a representative farm is modelled as a Markov decision process, extended to account for risk. A numerical framework for studying the dynamic uncertainty cost is presented, modifying the classical expected value of perfect information to a dynamic setting. The uncertainty cost depends on the volatility of income: e.g. with stationary income, the dynamic uncertainty cost corresponds to a dynamic option value of postponing investment. The model can be applied to agricultural policy planning. In the case study, the investment decision is sensitive to risk.     

Design,Synthesis and Biological Evaluation of Simplified Analogues of the Major Corn Strigolactones,Zealactone and Zeapyranolactone

Strigolactones are one of the phytohormones, which have multiple activities on plant growth and development. Since these strigolactone activities are highly associated with crop yield, use of strigolactone could be a promising technology in modern sustainable agriculture. The major strigolactones in corn root exudates have been identified as zealactone 1a/b and zeapyranolactone. We recently disclosed the first total synthesis of zealactone 1a/b together with its biological activity in corn. Herein, we describe the design and synthesis of simplified analogues of both corn-derived strigolactones with their bioavailability in soil and their biological activities. These compounds would be potential leads for the development of synthetic strigolactones for the agronomical use in a more sustainable crop production.     

Ion chromatography for the analysis of glyphosate and its selected metabolites. A review

Among all known compounds with herbicide activity glyphosate, has been the most commercially successful one. Currently, it is under evaluation because of its possible cancerogenic properties. However, the question is—if it is possible to completely withdraw it from use. Before it can happen, it is important to be sure of all its benefits and limitations, and this requires further detailed research. Due to the extent and prevalence of its use, glyphosate ends up in the environment and then in food and our bodies. There are several methods used for their determination. One of them is ion chromatography. Taking into account its advantages and disadvantages, as well as its rapid development, their importance in this field can be expected to increase in the near future. This paper summarizes the literature data from the past 22 years. The applications of ion chromatography in the determination of glyphosate in various types of environmental, food, and other samples are described. Moreover, the methods used so far are compared with the possibilities offered by ion chromatography, which main advantages and benefits are easy availability, low operating costs, green chemistry aspects, and suitable validation parameters.     

Stereoselective Synthesis and Biological Profile of All Stereoisomers of Lactam Analogues of Strigolactones GR24 and GR18

Strigolactones (SLs) are signaling molecules involved in plant development and governing interactions with soil microorganisms in the rhizosphere as well as the germination of parasitic weeds. Developing their use in Crop Protection is a promising approach to a sustainable agriculture by mitigating biotic and abiotic stresses. Recently, a new class of lactam analogues of SL has emerged, namely strigolactams, displaying outstanding potency to induce the germination of parasitic weed O. cumana as well as enhanced chemical and soil stability. Herein, we describe the stereoselective synthesis of GR24 and GR18 lactams harnessing the chemistry of chiral keteniminium (KI) salts, in particular the unprecedented reactivity of chloro-substituted KI, supported by DFT calculations. We disclose subsequently the biological activity on corn of the 32 stereopure strigolactams prepared, highlighting the crucial influence of stereochemistry and lactam substitution, rationalized by docking analyses. Finally, we performed stability studies in soil, which reveal that stereoisomers display very different half-lives, reflecting the significant impact of stereochemistry on degradation kinetics.