Cooperative Quantum Cutting of Nano-Crystalline BaF2：Tb^3＋, Yb^3＋ in Oxyfluoride Glass Ceramics

We report on cooperative quantum cutting in Tb^3＋- Yb^3＋ codoped glass ceramics. Precipitation of BaF2 nanocrystals is confirmed by XRD and HRTEM analysis. Near-infrared emission due to transition of Yb^3＋ ions under 485 nm excitation indicates cooperative energy transfer from Tb^3＋ to Yb^3＋. The quantum efficiency of this process reaches 145%. The realization of quantum cutting in glass ceramics may have promising applications in solar cells.     

Application of Symplectic Algebraic Dynamics Algorithm to Circular Restricted Three-Body Problem

Symplectic algebraic dynamics algorithm （SADA ） for ordinary differential equations is applied to solve numerically the circular restricted three-body problem （CR3BP） in dynamical astronomy for both stable motion and chaotic motion. The result is compared with those of Runge~Kutta algorithm and symplectic algorithm under the fourth order, which shows that SADA has higher accuracy than the others in the long-term cMculations of the CR3BP.     

稀土离子Ce,Tb掺杂硼磷酸锶荧光粉的发光性质

采用高温固相法合成了2SrO·0.25B₂O₃·0.75P₂O₅:RE³⁺(RE=Ce,Tb)荧光粉。研究了其中Ce³⁺,Tb³⁺的光谱性质,Ce³⁺和Tb³⁺共掺杂时的能量传递效率,以及Ce³⁺和Tb³⁺的动力学过程。发现在共掺杂的样品中,Tb³⁺的⁵D₄→⁷F₅绿色发射比Tb³⁺单掺杂样品中的绿色发射有显著的提高。当Tb³⁺的含量从1%增加到8%时,Ce³⁺→Tb³⁺的能量传递效率逐渐增加至70%。通过动力学研究,在Ce³⁺和Tb³⁺共掺杂的样品中,提高Tb³⁺的浓度,Ce³⁺的寿命减小。此外,Ce³⁺离子寿命的倒数与Tb³⁺的浓度之间很好地符合线性函数关系,经过拟合Ce³⁺离子的电子跃迁速率和Ce³⁺→Tb³⁺的能量传递速率分别为5.1×10^-2和1.34ns^-1·mol^-1。Tb³⁺的⁵D₄→⁷F₅跃迁的衰减曲线很好地遵守指数式衰减,并且随着Ce³⁺的掺杂浓度提高,Tb³⁺的⁵D₄→⁷F₅寿命增加。结果表明在共掺杂的2SrO·0.25B₂O₃·0.75P₂O₅材料中存在Ce³⁺到Tb³⁺的有效能量传递,这种材料在541nm处有着较强的绿光发射,所以将在发光以及显示领域有潜在的应用前景。     

端面抽运方形复合YAG温度场及热透镜研究

采用数值方法研究了方形截面复合Nd∶YAG激光晶体棒在端面抽运情况下的温度分布及热透镜效应,得到复合激光晶体内温度场的数值解和径向温度梯度引起的轴向传播光相位延迟分布ΔΦT(r),并与同条件下普通晶体的结果进行了比较.结果表明,吸收系数越大,两种晶体中最高温度相差也越大.采用复合晶体可以大幅度降低激光晶体内的温升,同时减小端面形变造成的透镜效应.复合晶体的ΔΦT(r)与普通晶体相似,且不满足对半径r的二次方关系.在rwp时,ΔΦT(r)相对于参考球面透镜的相位畸变Δφ随r的增大而急剧增大.     

Ce2O3对APP-PER-MA膨胀阻燃体系热解过程的协效作用

采用热重分析和红外光谱技术研究了氧化铈（Ce2O3）对以聚磷酸铵(APP)为酸源、季戊四醇(PER)为炭源、蜜胺（MA）为气源的经典膨胀型阻燃剂（IFR）热分解性能的影响。 结果表明,300~400 ℃时Ce2O3的存在加快了体系的分解和无机酸的生成速度,改变了IFR热解发生的时间,但是并没有从根本上改变热解过程;Ce2O3的添加使IFR阻燃剂第一阶段的热解活化能由65.73 kJ/mol提高至73.47 kJ/mol,第二、三、四阶段的热解活化能分别由167.46、135.13、141.34 kJ/mol降低至85.25、96.08、58.18 kJ/mol,并对IFR分解各阶段残留量有很大影响。     

1.319μm连续固体锁模激光器

报道了１．３１９μｍＮｄ：ＹＡＧ连续锁模激光器的技术研究。激光器的谐振腔为低热敏腔，用声光振幅调制器作为锁模元件，泵浦腔具有较高的泵浦效率和输出稳定性，获得了重复频率１００ＭＨｚ，平均功率～０．５４Ｗ，脉宽＜１７０ｐｓ的光脉冲。     

Yb：YAG晶体中的色心

在用引上法生长的Ｙｂ：ＹＡＧ晶体中，存在一个独特的色心，其吸收带位于３７５ｎｍ的６２５ｎｍ，随着Ｙｂ２Ｏ３掺杂浓度的增加，色心浓度增加，探讨了晶体生长过程中色心形成机理。高强γ射线辐照Ｙｂ：ＹＡＧ晶体，诱导大量色心的形成。晶体中的 对激发态Ｙｂ＾３＋离子的荧光寿命具有流淬火效应，因此，Ｙｂ：ＹＡＧ激光晶体需要经高温退火，消除色心的影响。     

Luminescence and energy transfer of Ce and Tb in Y3Si2O8Cl

The luminescence properties of Ce³⁺ and Tb³⁺ in Y₃Si₂O₈Cl have been investigated. The Ce³⁺ excitation bands in the region from 220 to are attributed to the transitions from 4f level to the crystal-field splitting levels of 5d. The Tb³⁺ excitation bands in the region from 220 to are due to the 4f-5d transitions. The spectral energy distributions of Tb³⁺ emission strongly depend on the Tb³⁺ concentration, the emissions of Tb³⁺ decrease with increasing Tb³⁺ concentration, this phenomenon is due to the cross-relaxation between Tb³⁺ ions. The efficient energy transfer from Ce³⁺ to Tb³⁺ in the Y₃Si₂O₈Cl is observed and discussed.     

Fabrication of submicron gratings in fused silica by F<Subscript>2</Subscript>-laser ablation

Submicron surface-relief gratings were fabricated on fused silica by F₂-laser ablation with nanosecond duration pulses from a high-resolution 157-nm optical processing system. A 157 nm wavelength projection mask was prepared by ArF-laser ablation to form a 20-μm period grating of equal lines and spaces. A 25-fold demagnification of the mask by a Schwarzschild objective generated gratings of an 830-nm period and a 250 nm modulation depth, as characterized by SEM, AFM and HeNe-laser beam diffraction. Received: 24 April 2002 / Accepted: 25 April 2002 / Published online: 4 December 2002 RID="*" ID="*"Corresponding author. Fax: +49-551/503 599, E-mail: jihle@llg.gwdg.de     

中间镜式半导体可饱和吸收镜在Nd∶YVO4激光器中被动调Q特性研究

利用一种新型的中间镜式半导体可饱和吸收镜,成功实现了二极管泵浦Nd∶YVO4激光器调Q运转,获得的最短脉冲宽度为8.3 ns,最大平均输出功率为135 mW,重复频率在400 KHz到2 MHz之间.利用这种吸收体被动调Q得到的重复频率大大高于所知的大多数吸收体所进行的被动调Q的重复频率.