全文获取类型
收费全文 | 1188篇 |
免费 | 75篇 |
国内免费 | 175篇 |
专业分类
化学 | 1219篇 |
晶体学 | 6篇 |
力学 | 43篇 |
综合类 | 16篇 |
数学 | 30篇 |
物理学 | 124篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 9篇 |
2021年 | 22篇 |
2020年 | 50篇 |
2019年 | 43篇 |
2018年 | 31篇 |
2017年 | 53篇 |
2016年 | 54篇 |
2015年 | 28篇 |
2014年 | 50篇 |
2013年 | 115篇 |
2012年 | 45篇 |
2011年 | 47篇 |
2010年 | 33篇 |
2009年 | 59篇 |
2008年 | 54篇 |
2007年 | 75篇 |
2006年 | 67篇 |
2005年 | 54篇 |
2004年 | 59篇 |
2003年 | 63篇 |
2002年 | 49篇 |
2001年 | 44篇 |
2000年 | 55篇 |
1999年 | 47篇 |
1998年 | 39篇 |
1997年 | 42篇 |
1996年 | 32篇 |
1995年 | 25篇 |
1994年 | 19篇 |
1993年 | 20篇 |
1992年 | 12篇 |
1991年 | 11篇 |
1990年 | 7篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 1篇 |
排序方式: 共有1438条查询结果,搜索用时 15 毫秒
121.
利用MG-200型摩擦磨损试验机研究了炭纤维增强环氧树脂复合材料/N80钢的摩擦学性能,考察了介质温度对摩擦学性能的影响;用扫描电子显微镜分析了磨损表面形貌.结果表明:在干摩擦条件下,炭纤维增强环氧树脂复合材料与N80钢对摩时的摩擦系数较低,炭纤维增强环氧树脂复合材料的磨损主要表现为树脂基体脱落碳化和炭纤维的折断剥落,偶件钢环则呈现明显的磨粒磨损特征;在油井产出液润滑下炭纤维增强环氧树脂复合材料的磨损率较低,摩擦系数和磨损率随着润滑介质温度的升高而增大,偶件钢环则呈现明显的磨粒磨损和腐蚀磨损特征. 相似文献
122.
123.
《Macromolecular rapid communications》2017,38(11)
Epoxy polymers (EPs) derived from soybean oil with varied chemical structures are synthesized. These polymers are then cured with anhydrides to yield soybean‐oil‐derived epoxy thermosets. The curing kinetic, thermal, and mechanical properties are well characterized. Due to the high epoxide functionality per epoxy polymer chain, these thermosets exhibit tensile strength over an order of magnitude higher than a control formulation with epoxidized soybean oil. More importantly, thermosetting materials ranging from soft elastomers to tough thermosets can be obtained simply by using different EPs and/or by controlling feed ratios of EPs to anhydrides.
124.
Synergistic effect of functional carbon nanotubes and graphene oxide on the anti‐corrosion performance of epoxy coating 下载免费PDF全文
In this work, we reported the synergistic effect of functional carbon nanotubes (CNTs) and graphene oxide (GO) on the anticorrosion performance of epoxy coating. For this purpose, the GO and CNTs were firstly modified by the 3‐aminophenoxyphthalonitrile to realize the nitrile functionalized graphene oxides (GO‐CN) and carbon nanotubes (CNTs‐CN). As modified GO‐CN and CNTs‐CN were characterized and confirmed by Fourier transform infrared spectroscopy, X‐ray photoelectron spectroscopy, and gravimetric analyzer. It was found that about 19 and 24 wt% of 3‐aminophenoxyphthalonitrile were grafted onto the surface of the GO and CNTs, respectively. The electrochemical impedance spectroscopy results showed that the GO‐CN&CNTs‐CN hybrid materials exhibit a remarkable superiority in enhancing the anticorrosion performance of epoxy coatings. Significant synergistic effect of the lamellar structural GO‐CN and CNTs‐CN on the anticorrosion performance of epoxy composite coatings was designed. Besides, the epoxy coating with 1 wt% of the GO‐CN&CNTs‐CN hybrid exhibited the best anticorrosion performance, in which the impedance showed the largest one (immersion in 3.5 wt% of NaCl solution for 168 hr). Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
125.
126.
127.
Short duration stress pulses are of particular interest in determining the interfacial crack tip instability criteria for
the dynamic fracture behavior of laminated carbon-fiber/epoxy composites. However, the heterogeneous architectures of laminated
composites can alter the characteristics of a stress pulse as it propagates toward a crack tip. This makes it difficult to
use standard dynamic testing techniques for characterizing these materials, since these techniques assume the characteristics
of the stress pulse do not change as a result of propagation and can therefore be unambiguously determined from impact conditions.
This paper presents a novel experimental technique that has been developed for characterizing short duration stress pulse
propagation in laminated composite materials. In this technique, a dynamic moiré interferometer is used to capture fringe
patterns corresponding to displacement fields associated with short duration stress pulses that were generated by impacting
0° and 90°/0°/90° carbon-fiber/epoxy composites with a magnetic flyer plate. Appropriate dynamic testing conditions for capturing
high fidelity fringe patterns were determined using the recently developed dynamic moiré fringe contrast factor. The effects
of the composite architecture on the propagation of short duration stress pulses observed with the dynamic moiré interferometer
were confirmed by transient dynamic finite element analysis. From comparisons of experimental and numerical data, it was determined
that the impact conditions for the magnetic flyer plate and laminated composite will not necessarily be planar, which has
a significant effect on the intensity and duration of the propagating stress pulse. 相似文献
128.
In this study the curing kinetics of epoxy based on the diglycidyl ether of bisphenol A (DGEBA), 4,4′‐diaminodiphenyl sulfone (DDS) as a hardener, and SiO2/TiO2 (70:30) as a nanofiller was investigated by nonisothermal differential scanning calorimetry (DSC). The effects of different weight contents of SiO2/TiO2 nanoparticles were studied using DSC in Dynamic Mode and the best value of the nanofiller was found to be 5 phr (parts per hundred). Dynamic measurements were used to obtain the total heat of reaction of the epoxy system as well as its activation energy (Ea) based on the isoconversional methods of Kissinger and Ozawa. The process revealed a dependence of the activation energy on conversion (α). The morphology of the cured system was investigated by scanning electron microscopy (SEM). It showed a strong cross‐linking between the resin and hardner and a relatively better dispersion of surface modified filler nanoparticles. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
129.
Isothermal differential scanning calorimetry (DSC) was used to study the curing behavior of epoxy prepreg Hexply®1454 system, based on diglycidyl ether of bisphenol A (DEGBA)/dicyandiamid (DICY) reinforced by glass fiber. Cure kinetics of an autocatalytic‐type reaction were analyzed by general form of conversion‐dependent function. The characteristic feature of conversion‐dependent function was determined using a reduced‐plot method where the temperature‐dependent reaction rate constant was analytically separated from the isothermal data. An autocatalytic kinetic model was used; it can predict the overall kinetic behavior in the whole studied cure temperature range (115–130°C). The activation energy and pre‐exponential factor were determined as: E = 94.8 kJ/mol and A = 1.75 × 1010 sec?1 and reaction order as 2.11 (m + n = 0.65 + 1.46 = 2.11). A kinetic model based on these values was developed by which the prediction is in good agreement with experimental values. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
130.
A theoretical analysis of nano-deep corrugated long-period waveguide gratings on a SU-8 polymer-based channel waveguide with NOA61 optical epoxy coated upper- and lower cladding is presented. The transmission spectra of the gratings show strong rejection bands both at visible (at wavelength region of 450?460 nm) and infra-red (at wavelength region of 1530?1540 nm) regions when a grating period of ?68 μm with optimized grating tooth height is considered. Phase-matching graphs are studied to find the relationship between resonance wavelength and grating period. These results show that the grating parameters significantly affect the characteristics of transmission spectra as well as the resonance wavelength of the grating. Long-period waveguide grating-based band pass filter made by use of same polymer materials are also designed and analyzed. These types of waveguide grating-based filters can widely be used for visible and infra-red wavelength sensing applications. 相似文献