Spectral Properties of Thioflavin T and Its Complexes with Amyloid Fibrils

Comparative analysis of the absorption and fluorescence spectra and fluorescence excitation spectra of thioflavin T (ThT) in various solvents and in the composition of amyloid fibrils has shown that ThT, when excited in the region of the long-wavelength absorption band, fluoresces in the spectral region with a maximum at 478–484 nm. The appearance in aqueous and alcohol solutions of a fluorescence band with a maximum near 440 nm has been attributed to the presence in the composition of the ThT preparations of an impurity with an absorption band in the 340–350-nm range. The literature data showing that in glycerol ThT has a wide fluorescence spectrum with two maxima are due to the artifact connected with the use of a high concentration of the dye. It has been suggested that the cause of the low quantum yield of ThT aqueous and alcohol solutions is the breakage of the system of conjugated bonds due to the reorientation of the benzothiozole and benzaminic rings of ThT in the excited state with respect to one another. The main factor determining the high quantum yield of fluorescence of ThT incorporated in fibrils is the steric restriction of the rotation of the rings about one another under these conditions. The suggestions made have been verified by the quantum-chemical calculation of the ThT molecule geometry in the ground and excited states.     

Shadowing with multidimensional time in Banach spaces

We study linear dynamical systems with multidimensional time in Banach spaces. Using Taylor functional calculus we prove that under additional assumptions hyperbolic systems have shadowing property.     

CCD光谱谱线标定方法研究

CCD作为光谱分析和测色仪器的光谱接收器件 ,光谱谱线定位受单色仪狭缝和CCD光敏元尺寸影响。提出采用最小二乘法做曲线拟合和质心法来确定光谱线在CCD上的精确定位 ,使光谱谱线的定位精度得到提高 ,并且不受CCD光敏元尺寸限制。实验结果表明 ,两种方法对光谱线的定位 ,具有重复性高 ,稳定性好等特点。在定位精度上 ,两者具有一致性。     

Instability of Solitary Waves in Nonlinear Composite Media

In this paper,we investigate a class of Hamiltonian systems arising in nonlinear composite media.By detailed analysis and computation we obtain a decaying estimates on the semigroup and prove the orbitalinstability of two families of explicit solitary wave solutions (slow family in anisotropic case and solitary wavesin isotropic case),which theoretically verify the related guess and numerical results.     

Linear Relations, Differential Inclusions, and Degenerate Semigroups

A generalized linear differential equation in a Banach space is studied. The construction of a phase space and solutions with the help of the spectral theory of linear operators, ergodic theorems, and degenerate semigroups of linear operators is carried out.     

波长检测技术在温度测量中的应用

提出一种波长检测技术实现温度测量的方法,利用FBG传感器对温度等物理量实施监测,具有测试精度高,应用场合不受限制等特点,当环境参数发生变化时,光纤光栅的有效折射率和光栅周期会受到影响,将引起光纤光栅峰值波长的偏移,依据反射光谱结构的变化,可知道其温度的变化趋势。实验测试结果表明,在温度变化0.1°,波长变化1pm,温度和波长具有良好的线性关系。     

傅里叶变换红外光谱仪遥测污染云团的吸收光谱算法

遥感傅里叶变换红外光谱技术因其具有对污染源作无干扰监测、多组分的同时连续测定、区域性或大范围地区的测量等优点,因而已广泛的应用于遥感测量技术。利用傅里叶变换红外(FTIR)光谱仪远距离探测目标,根据探测的目标源是否充满光谱仪的视场,建立了三种辐射模型。在所建立模型的基础上,选用了D&P公司生产的便携式Model-101型傅里叶变换红外光谱仪,实时探测目标云团和背景,运用差谱法和发射光谱法对探测结果进行了光谱分析,进而得到了扣除背景影响后的目标云团吸收光谱。给出了相应的仿真实验结果示例。实验结果表明,由差谱法得到的结果准确度较好。     

Ⅰ类超晶格势阱中能级分布及电子跃迁规律研究

在研究大量实验曲线的基础上,指出势阱所有能级均有一定的宽度,电子或空穴在各能级中出现的概率符合正态分布,从理论上分析了I类超晶格和双势垒单势阱的发光光谱与吸收光谱·解释了GaAs/Ga1-xAlxAs多量子阱和超晶格吸收光谱吸收边及量子阱变窄时各吸收峰的“蓝移现象”及GaAs/Ga1-xAlxAs双势垒单量子阱样品的电流—电压特性曲线及电导—电压特性曲线的特征和出现的“负阻效应”·     

Nd∶NaR(WO_4)_2晶体生长(R=Bi,Y)

采用提拉法生长出了掺钕钨酸铋钠[Nd∶NaBi(WO4)2,简称Nd∶NBW]和掺钕钨酸钇钠[Nd∶NaY(WO4)2,简称Nd∶NYW]晶体,并给出了制备无开裂优质Nd∶NBW和Nd∶NYW晶体的最佳生长工艺参数。从XRD分析得到Nd∶NBW和Nd∶NYW晶体的晶胞参数,并分析了晶体的拉曼光谱,认为二者结构基本相同,为四方晶系、白钨矿结构、I41/a空间群。由吸收光谱可以看出,Nd∶NBW在802nm有较强的吸收峰,Nd∶NYW在804nm、752nm、586nm附近有较强、较宽的吸收峰,二者均适合于LD泵浦;计算了晶体中Nd3+的吸收截面积。     

偏硅酸钙中Pr3+的4f5d态的光谱特性及Pr3+→Gd3+的能量传递

合成了高效发射UV光的CaSiO3:Pr^3 新型荧光体，研究了室温下Pr^3 的4f5d态的发射和激发光谱，Pr^3 的4f5d态的最低子能级向4f^2组态的^3H4，^3H6和^1G4能级跃迁产生UV发射，并不伴随有4f-4f能级跃迁的可见光发射。Pr^3 的浓度猝灭是由于辐射和无辐射能量传递造成的，同时，在CaSiO3中，存在Pr^3 →Cd^3 的能量传递，探讨了其能量传递特性。