Preparation and microwave absorption properties of electroless Co-Ni-P coated strontium ferrite powder

A new type of Co-Ni-P coated strontium ferrite nanocomposite was prepared with electroless plating enhanced by ultrasonic wave at room temperature. The plating process was studied carefully. The morphology, crystal structure and microwave absorption properties of the Co-Ni-P coated powder were studied with field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), energy dispersive analysis of X-rays (EDX) and vector network analyzer. The results show that the strontium ferrite powder was successfully coated with Co-Ni-P alloy and possesses excellent microwave absorption properties. The maximum microwave loss of the composite powder reaches −44.12 dB. The bandwidth with the loss above −10 dB exceeds 13.8 GHz.     

Numerical simulations of the mitigation of unconfined explosions using water-mist

Mitigating the effects of explosive blasts has been an important concern for a long time. Water-mist presents an attractive option due to its easy availability, extensive use in the fire suppression area, and non-toxicity. However, its ability to mitigate the effects of blasts is unclear. This research uses multiphase numerical simulations to elucidate some of the issues associated with using water-mist to mitigate explosive blasts in unconfined spaces. Initial multidimensional simulations examine the effect of water-mist on the blast wave generated by a TNT explosive. Results show that the droplets are generally swept outward with the shock wave and in general do not penetrate into the secondary fireball. The water-mist does, however, mitigate the shock-front through vaporization and momentum extraction. Further simulations show that momentum extraction has the dominant role in mitigating the leading shock wave. Parametric studies indicate that droplet size and mass loading play a secondary role to the total amount of water between the observer and the explosive blast. This is a promising result for using water-mist for blast-mitigation, because it suggests that water-mist can be as effective as having a more dense “water wall” surrounding the explosive.     

Microwave-promoted Suzuki-Miyaura coupling reactions in a cycloalkane-based thermomorphic biphasic system

Microwave-promoted Suzuki-Miyaura coupling reaction of aryl halides attached to a cycloalkane-soluble platform was accomplished in a cycloalkane-based thermomorphic biphasic system. Following irradiation and subsequent cooling, the monophasic reaction mixture immediately formed a biphasic solution to allow facile workup and separation of the product.     

有关力学谱和内耗工作的综合与回顾

本文广泛地收集了有关内耗，力学谱，超声衰减方面的专著及会议文集。反映了20世纪在此领域的英文，俄文出版的书籍。也列出了历次国际会议及前苏联，乌克兰，中国的国内会议。文中包括了点缺陷，电，声子，位错，晶界，电畴等诸方面在内的内耗与力学谱工作。     

单谐振腔外部Q值的计算方法

 通过对带有耦合器的单驻波腔进行等效电路分析，推导出可计算带有耦合波导的单谐振腔外部Q值的反射相位法，该方法通过计算不同频率的反射相位来确定谐振频率和外部Q值。详细叙述了在CST Microwave Studio中用谐振模式求解法、直接时域跟踪法和反射相位法进行计算的步骤；用这3种方法分别计算了二次发射微波电子枪的外部Q值并和实验测量结果做了比较。结果显示3种计算方法都有很高的精度,但反射相位法的速度最快，耗时1 071 s。计算发现外部Q值与耦合口长度的4.1次方成反比。     

双面金属包覆介质波导模序数的判别方法

在双面金属包覆介质波导中 ,随着介质层厚度的变化 ,会出现TM0 模与TM1 模的分离和简并两种状态 ,从而影响衰减全反射 (ATR)谱中模序数的确认。通过对金属波导的理论分析和实验研究 ,提出了三种模序数确认方法 :本征角计算法、吸收峰全峰半宽比较法和吸收峰峰间距比较法 ,实现了两种状态下对模序数的准确判断     

用最小电离的质子刻度铅–闪烁光纤夹层电磁量能器

研究利用最小电离的质子和已知能量的电子来刻度铅–闪烁光纤夹层电磁量能器.对最小电离粒子输出响应进行光纤衰减修正后,利用最小电离质子的输出响应对量能器测量单元进行标定,然后对不同入射能量的电子事例进行能量重建,重建能量与入射能量有很好的线性关系.本文还对最小电离的质子与μ子对量能器测量单元的输出响应进行了比较,发现二者在误差范围内是一致的.     

Effect of biotransformation on multispecies plume evolution and natural attenuation

Biological transformation of volatile organic compounds is one of the key factors that influence contaminant-plume evolution and thus natural attenuation. In this study we investigate the effect of biological transformation on the transport of contaminants in the aqueous and gaseous phases. The analysis includes the study of the effect of density-driven advection of contaminants in the gaseous phase on multiphase and multispecies flow, fate and transport modeling in the subsurface. Trichloroethylene (TCE) and its two byproducts, dichloroethylene and vinyl chloride, are analyzed as the target contaminants. Our results indicate that density-driven advection of the gaseous phase, which is initiated by evaporation of TCE as a nonaqueous phase liquid, increases the downward and also the lateral migration of TCE within the unsaturated zone. This process also influences the location of high-concentration zones of the byproducts of TCE in the unsaturated and the saturated zones. Biotransformation of TCE contributes to the reduction of dissolved TCE plume development as expected. The daughter byproducts, which are introduced into the subsurface system, show distinct transport patterns as they are affected by their independent degradation kinetics and density-driven advection. These observations, which are based on our simulation results for biotransformation and transport of TCE and its byproducts, are useful in evaluating the natural attenuation processes, its potential health hazards and also the evaluation of potential plume development at contaminated sites.     

A polymer onium acting as phase-transfer catalyst in halogen-exchange fluorination promoted by microwave

A polymerized quaternary ammonium salt polydiallyldimethylammonium chloride, exhibiting high stability to heat and base, was prepared and applied as phase-transfer catalyst (PTC) in halogen-exchange (Halex) fluorination of chloronitrobenzenes to give excellent yields of corresponding fluoronitrobenzenes. Dimethyl sulfoxide was found to be the best solvent when microwave was applied as heating resource.