非牛顿幂律流体有界双重介质渗流模型实空间解析解与样版曲线

在前人工作的基础上,建立了非牛顿幂律流体有界双重介质试井模型.根据模型的特点,提出了相应的特征值问题,求出了特征值和特征函数.定义了油层压力关于空间变量的正交积分变换.根据特征函数系的完备正交性和矩阵微分方程理论,获得了油层压力分布以及井底压力,压力导数的实空间解析解(无穷级数形式).首次直接根据实空间解析解绘制了样版曲线,并在同一张双对数坐标纸上描出拉普拉斯方法制作的样版曲线,同时给出二者间的误差走势图.通过对比分析发现,随着级数项数的增大,根据解析解制作的样版曲线逐渐逼近拉普拉斯方法制作的样版曲线.新疆油田实例证实了该方法的有效性.研究结果进一步补充,完善了试井分析理论.     

Temperature control of electrohydrodynamic micro heat pipes

Active thermal control was achieved by using an electrohydrodynamically (EHD) assisted micro heat pipe array. A simulation model of temperature control of EHD micro heat pipes was established in a Matlab Sinulink environment. An experimental model was designed and fabricated to verify the model and identify the factors most influential to the thermal control via EHD micro heat pipe array. Good correspondence between simulations and experiments was achieved. Electric field intensity, set-point temperature and the gap between the upper and lower set-point temperatures were shown to have a dramatic influence on the temperature control.     

水杨醛类希夫碱在LB膜上的光谱性能的研究

合成了两种末端碳锭长度不同的水杨醛类希夫碱N-十二烷基（2-羟基-5-硝基苯甲亚胺）和N-十六烷基（2-羟基-5-硝基苯甲亚胺），研究了它们在气-液界面上的成膜性能，并通过紫外、荧光、红外显微镜等光谱手段对它们在LB膜上的性能进行了表征。实验结果表明两种希夫碱分子在LB膜中都形成了J-聚体，末端碳链较长的希夫碱 成膜性能相对较好，并且在膜上也能光致发光，但希夫碱分子的LB膜存在一定的缺陷。     

Behaviors of flow mechanisms and heat transfer of non-Newtonian fluids through a spinneret

This investigation examines non-Newtonian flow mechanisms and heat transfer characteristics for a micro spinneret. The working fluid, Polyethylene terephthalate (PET), is the raw material of micro fiber, and a large-scale experimental test model was designed to visualize the complex viscous flow system in the micro spinneret. To visualize the complex convective flow system, an experimental test model was constructed, using glycerin instead of PET. The related parameters of PET were compared with those of glycerin. The power law correlates the shear strain with PET viscosity at various temperatures. The pressure distribution along the flow direction was measured and the flow pattern was visualized using polyethylene (PE) powder of 20–40 m. Similar configurations were calculated for micro spinneret physical parameters to determine the thermal flow characteristics. The Reynolds number in the test model is not less than 10^–2. In the non-Newtonian PET working fluid of practical micro spinneret, flows with Re = 10⁴ to 10^–2 are in the same low Reynolds number flow regime. Therefore, the working fluid is expected to have the same flow characteristic. A numerical solution covering the range of approximately Re = 10^–4 at PET confirms that the flow characteristics of glycerin are constant for Re = 1.228 × 10^–2. The Peclet number in the test model can be adjusted to a value similar to that in the micro spinneret. The flow visualization was compared with that of the numerical solution, and the friction factor and Nusselt number in the micro spinneret were analyzed. Finally, numerical results and friction factor with various exit angles of micro spinneret in a triangular zone flow system were also summarized.     

On Determining the Percolation Reynolds Number and the Characteristic Linear Dimension for Ideal and Fictitious Porous Media

Various versions of representations of the percolation Reynolds number for porous media with isotropic and anisotropic flow properties are considered. The formulas are derived and the variants are analyzed with reference to model porous media with a periodic microstructure formed by systems of capillaries and packings consisting of spheres of constant diameter (ideal and fictitious porous media, respectively). A generalization of the Kozeny formula is given for determining the capillary diameter in an ideal porous medium equivalent to a fictitious medium with respect to permeability and porosity and it is shown that the capillary diameter is nonuniquely determined. Relations for recalculating values of the Reynolds number determined by means of formulas proposed earlier are given and it is shown that taking the microstructure of porous media into account, as proposed in [1, 2], makes it possible to explain the large scatter of the numerical values of the Reynolds number in processing the experimental data.     

THE RATE-INDEPENDENT CONSTITUTIVE MODELING FOR POROUS AND MULTI-PHASE NANOCRYSTALLINE MATERIAL

To determine the time-independent constitutive modeling for porous and multiphase nanocrystalline materials and understand the effects of grain size and porosity on their mechanical behavior, each phase was treated as a mixture of grain interior and grain boundary, and pores were taken as a single phase, then Budiansky's self-consistent method was used to calculate the Young's modulus of porous, possible multi-phase, nanocrystalline materials, the prediction being in good agreement with the results in the literature. Further, the established method is extended tosimulate the constitutive relations of porous and possible multi-phase nanocrystalline materials with small plastic deformation in conjunction with the secant-moduli approach and iso-strain assumption. Comparisons between the experimental grain size and porosity dependent mechanical data and the corresponding predictions using the established model show that it appears to be capable of describing the time-independent mechanical behaviors for porous and multi-phase nanocrystalline materials in a small plastic strain range. Further discussion on the modification factor, the advantages and limitations of the model developed were present.     

一种岩石损伤本构模型在地下强爆炸中的应用

为了描述地下爆炸波的传播,建立了一种考虑塑性硬化、剪胀和损伤软化效应的岩石本构模型,并应用于地下强爆炸自由场的数值计算,获得的速度和位移波形以及峰值速度衰减曲线等与国外地下试验测量数据和同类计算相比十分接近,从而验证了本构模型的有效性。     

后处理工艺制备多级孔Ti-BEA沸石及其环氧化催化性能

基于脱铝多级孔BEA沸石与二氯二茂钛的固相反应,开展了钛掺杂量可调的多级孔Ti-beta后处理工艺制备研究.对制备的多级孔Ti-beta样品的理化性质进行了表征,包括X射线衍射、氮气吸附脱附测试、扫描电镜、透射电镜、紫外可见吸收光谱和紫外拉曼光谱等.结果表明,多级孔BEA沸石具有较好的化学稳定性,脱铝-钛化的后处理过程未对样品多级孔结构产生明显影响. 以环己烯和十二烯的烯烃环氧化为探针反应表征了合成多级孔Ti-beta与纯相微孔Ti-beta沸石的催化性能.结果表明,在小分子环己烯的环氧化反应中,多级孔Ti-beta沸石的催化活性(转化率59.4%)与微孔Ti-beta相当(转化率57.9%);但是在较大分子十二烯的催化反应中,多级孔结构Ti-beta材料的催化性能(转化率11.1%)明显优于纯相微孔材料(转化率6.8%),且产物中环氧化物选择性更高(分别为60.3%和37.8%).     

The Critical Effect of Niobium Doping on the Formation of Mesostructured TiO2: Single‐Crystalline Ordered Mesoporous Nb‐TiO2 and Plate‐like Nb‐TiO2 with Ordered Mesoscale Dimples

Highly ordered mesoporous niobium‐doped TiO₂ with a single‐crystalline framework was prepared by using silica colloidal crystals with ca. 30 nm in diameter as templates. The preparation of colloidal crystals composed of uniform silica nanoparticles is a key to obtain highly ordered mesoporous Nb‐doped TiO₂. The XPS measurements of Nb‐doped TiO₂ showed the presence of Nb⁵⁺ and correspondingly Ti³⁺. With the increase in the amount of doped Nb, the crystalline phase of the product was converted from rutile into anatase, and the lattice spacings of both rutile and anatase phases increased. Surprisingly, the increase in the amount of Nb led to the formation of plate‐like TiO₂ with dimpled surfaces on one side, which was directly replicated from the surfaces of the colloidal silica crystals.     

Determination of phthalate esters from environmental water samples by micro‐solid‐phase extraction using TiO2 nanotube arrays before high‐performance liquid chromatography

We describe a highly sensitive micro‐solid‐phase extraction method for the pre‐concentration of six phthalate esters utilizing a TiO₂ nanotube array coupled to high‐performance liquid chromatography with a variable‐wavelength ultraviolet visible detector. The selected phthalate esters included dimethyl phthalate, diethyl phthalate, dibutyl phthalate, butyl benzyl phthalate, bis(2‐ethylhexyl)phthalate and dioctyl phthalate. The factors that would affect the enrichment, such as desorption solvent, sample pH, salting‐out effect, extraction time and desorption time, were optimized. Under the optimum conditions, the linear range of the proposed method was 0.3–200 μg/L. The limits of detection were 0.04–0.2 μg/L (S/N = 3). The proposed method was successfully applied to the determination of six phthalate esters in water samples and satisfied spiked recoveries were achieved. These results indicated that the proposed method was appropriate for the determination of trace phthalate esters in environmental water samples.