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81.
高效液相色谱法分离和测定面粉中增白剂过氧化苯甲酰 总被引:22,自引:0,他引:22
提出了用高效液相色谱分离和测定面粉中增白剂过氧化苯甲酰的新方法。用乙醇为熔剂通过超声提取面粉中的过氧化苯甲酰,在氢氧化钾存在下使之转化为苯甲酸,再用HPLC进行测定,具有良好的准确度和再现性。 相似文献
82.
Chao Wang Jing Wang Xiang Xiao Guobin Zhong Shijia Wu Kaiqi Xu Wei Zhao Wei Su Jie Zeng Baojun Wu Weili Zhang Changcheng Wu Zhiqiang Shi 《中国化学快报》2019,30(6):1269-1272
A novel cyclic ammonium salt, N,N-dimethylpyrrolidinium tetrafluoroborate (P11-BF4), was successfully synthesized for the first time. The smallest cyclic structure of P11-BF4 induced high solubility and conductivity in PC, which can easier enter the micropores of activated carbon and occupy more surface area during charge/discharge process. 相似文献
83.
Rivard C. J. Himmel M. E. Vinzant T. B. Adney W. S. Wyman C. E. Grohmann K. 《Applied biochemistry and biotechnology》1989,(1):461-478
Economic evaluations of the capital costs for anaerobic digestion systems for gas production show that the reactor is a significant
cost component. The successful application of high solids digestion of processed MSW (e.g., greater than 10% solids within
the digester) would allow a decrease in reactor volume with maintenance of relatively high gas production rates. However,
high solids slurries do not mix well in conventional stirred tank reactors. A horizontal shaft, hydraulically driven reactor
was designed and fabricated to test the anaerobic digestion of high solids concentrations. Digester performance was evaluated
as a function of experimental parameters such as nutrient requirements, feeding rates, pH control, and agitator design/ rotation
speed; horsepower of mixing was also evaluated for the reactor. Several startup protocols were examined to obtain a biologically
stable anaerobic fermentation at high solids levels. 相似文献
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The solubility of glycine,
-alanine,
-valine,
-leucine, and
-isoleucine in water was measured at 298.15 K and pressures up to 400 MPa. The standard deviation of the logarithm of the solubility is 0.001–0.003, equal to or better than the accuracy of atmospheric pressure measurement in the literature (0.001–0.05). A variety of solubility phenomena were observed. The solubility of glycine decreased with increasing pressure, whereas that of
-alanine increased. The
-valine and
-isoleucine have a solubility maximum at around 100 MPa, and
-leucine seems to exhibit a solid-phase phase transition at around 200 MPa. Pressure coefficient of the solubilities at 0.10 MPa is compared with that thermodynamically estimated in reference to aqueous density measurements of glycine and
-alanine at 298.15 K and 0.10 MPa, supporting a reliability of our high-pressure measurements. 相似文献
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构筑了MgO部分稳定的ZrO2基固体电解质电化学电池测量EAF的实验装置,测定了Sm2CuO4的标准Gibbs生成自由能。结果表明化合物RE2CuO23(RE=La,Nd,Sm,Eu)随着镧系元素离子半径减小,热力学稳定性下降,并用晶体场理论解释了这一规律。 相似文献
90.
Human serum is routinely measured for total calcium content in clinical studies. A definitive high-accuracy and low-uncertainty method is required for reference measurements to underpin medical diagnoses. This study presents a novel octopole collision cell ICP-MS, high-accuracy, methodology and comparison of that technique with double-focusing sector field ICP-MS and an ICP-OES method. Double-matched isotope dilution mass spectrometry (IDMS) was employed for ICP-MS techniques and an exact matching bracketing technique using scandium as an internal standard was used for ICP-OES analysis. Medium resolution mode was utilised for double-focusing sector field ICP-MS analysis to resolve the dominant interferences on the 44Ca/42Ca isotope pair. Hydrogen reaction gas was employed to chemically resolve a number of polyatomic interferences predominantly through charge transfer reactions in the octopole collision cell. Comparison data presented for NIST CRM 909b human serum analysis from all three techniques demonstrates highest accuracy (99.6%) and lowest uncertainty (1.1%) for octopole collision cell ICP-MS. Data from ICP-OES using a non-IDMS technique produces comparably accurate data and low-uncertainties. The much higher total expanded uncertainties for double-focusing sector field ICP-MS compared with octopole collision cell data are explained by lower precision on the measurement of the 44Ca/42Ca isotope ratio. Data for octopole collision cell ICP-MS submitted for an international blind trial comparison (CCQM K-14) demonstrated excellent agreement with the mean of all participants with a low expanded uncertainty. 相似文献