关于曲线积分中值定理“中间点”的一个一般性结果

讨论了第一类曲线积分中值定理“中间点”的渐近性质,得到了更具一般性的新结果.     

Voltammetric determination of mesotrione at hanging mercury drop electrode

A study of the electrochemical reduction of the mesotrione pesticide on a hanging mercury drop electrode (HMDE) was performed as a basis for the development of a sensitive analytical method for natural samples. The electrochemical characteristics of herbicide mesotrione dissolved in a phosphate buffer (pH 7.0) have been determined by means of electrochemical techniques such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV) over a wide range of pH from 2.0 to 10.0. The experimental parameters, such as electrolyte type and its pH, pulse amplitude, and scan rate were optimized. The method was applied to the determination of the pesticide in a spiked soil samples. Using this method, a linear calibration curve for mesotrione was obtained up to the 0.1 μM range in pH 7 phosphate buffer solution with a detection limit (S/N = 3) of 50 nM. The method can be applied successfully to the determination of mesotrione in soils. The text was submitted by the authors in English.     

ARL 9800XP型X射线荧光光谱仪的故障及维修

介绍了一例ARL-9800X射线荧光光谱仪的故障及故障排除的措施。     

Synthesis and optical properties of tetraphenylmethane-based tetrahedral fluorescent compounds and their water-soluble PEG-linked polymers

The synthesis and optical properties of tetrahedral fluorescent compounds comprising of tetraphenylmethane as the core and oligothiophenes as the chromophoric arms, and their water-soluble poly(ethylene glycol)-linked polymers are reported.     

Sterically stabilized emulsion polymerization of styrene: Pseudo‐semicontinuous approach

The sterically stabilized emulsion polymerization of styrene initiated by a water‐soluble initiator at different temperatures has been investigated. The rate of polymerization (R_p) versus conversion curve shows the two non‐stationary‐rate intervals typical for the polymerization proceeding under non‐stationary‐state conditions. The shape of the R_p versus conversion curve results from two opposite effects—the increased number of particles and the decreased monomer concentration at reaction loci as the polymerization advances. At elevated temperatures the monomer emulsion equilibrates to a two‐phase or three‐phase system. The upper phase is transparent (monomer), and the lower one is blue colored, typical for microemulsion. After stirring such a multiphase system and initiation of polymerization, the initial coarse polymer emulsion was formed. The average size of monomer/polymer particles strongly decreased up to about 40% conversion and then leveled off. The initial large particles are assumed to be highly monomer‐swollen particles formed by the heteroagglomeration of unstable polymer particles and monomer droplets. The size of the “highly monomer” swollen particles continuously decreases with conversion, and they merge with the growing particles at about 40–50% conversion. The monomer droplets and/or large highly monomer‐swollen polymer particles also serve as a reservoir of monomer and emulsifier. The continuous release of nonionic (hydrophobic) emulsifier from the monomer phase increases the colloidal stability of primary particles and the number of polymer particles, that is, the particle nucleation is shifted to the higher conversion region. Variations of the square and cube of the mean droplet radius with aging time indicate that neither the coalescence nor the Ostwald ripening is the main driving force for the droplet instability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 804–820, 2003     

Study on a Cross Diffusion Parabolic System

This paper considers a kind of strongly coupled cross diffusion parabolic system,which can be usedas the multi-dimensional Lyumkis energy transport model in semiconductor science.The global existence andlarge time behavior are obtained for smooth solution to the initial boundary value problem.When the initialdata are a small perturbation of an isothermal stationary solution,the smooth solution of the problem under theinsulating boundary condition,converges to that stationary solution exponentially fast as time goes to infinity.     

THE LARGE TIME BEHAVIOR OF SPECTRAL APPROXIMATION FOR A CLASS OF PSEUDOPARABOLIC VISCOUS DIFFUSION EQUATION

The asymptotic behavior of the solutions to a class of pseudoparabolic viscous diffusion equation with periodic initial condition is studied by using the spectral method. The semidiscrete Fourier approximate solution of the problem is constructed and the error estiation between spectral approximate solution and exact solution on large time is also obtained. The existence of the approximate attractor AN and the upper semicontinuity d(AN,A)→0 are proved.     

环丙沙星在胶束体系中的荧光特性研究及应用

研究了环丙沙星在胶束体系中的荧光性质，发现十二烷基硫基酸对环丙沙星有较强的增敏作用。据此建立了胶束增敏荧光光谱法测定痕量环丙沙星的新方法，经样品测定，其线性范围为0．033－0．60μg.mL^-1，检出限为0．033μg.mL^-1，回收率为94．0％－98．1％相对标准偏差为1．5％－2．8％。     

Fluorescence anisotropy of acridinedione dyes in glycerol: Prolate model of ellipsoid

Time-dependent reorientations of resorcinol-based acridinidione (ADR) dyes in glycerol were studied using steady-state and time-resolved fluorescence studies. The difference between fluorescence anisotropy decays recorded at 460 nm when exciting at 250 nm and those obtained when exciting at 394 nm are reported. When exciting at 394 nm, the fluorescence anisotropy decay is bi-exponential, while on exciting at 250 nm a mono-exponential fluorescence anisotropy decay is observed. We interpret this in terms of different directions of the absorption dipole at 394 and 250 nm with the emission dipole respectively, which is experimentally validated and further analysed as a prolate model of ellipsoid.     

丁基罗丹明B-Bi(Ⅲ)-SCN~--PVA-Tween-80体系荧光熄灭法测定痕量铋

本文研究了在PVA和Tween 80存在下,铋离子与硫氰酸钾和丁基罗丹明B形成缔合型三元配合物,使丁基罗丹明B的荧光熄灭,建立了痕量铋的荧光分析新方法。工作曲线线性范围为0～5.0μg/25mL。方法灵敏度高,ε_(588)为3.5×10~5L·mol~(-1)·cm~(-1),操作简便。用于铸铁中痕量铋的测定,结果满意。