全文获取类型
收费全文 | 4056篇 |
免费 | 261篇 |
国内免费 | 325篇 |
专业分类
化学 | 1150篇 |
晶体学 | 37篇 |
力学 | 114篇 |
综合类 | 1篇 |
数学 | 22篇 |
物理学 | 3318篇 |
出版年
2024年 | 3篇 |
2023年 | 23篇 |
2022年 | 44篇 |
2021年 | 48篇 |
2020年 | 40篇 |
2019年 | 67篇 |
2018年 | 50篇 |
2017年 | 115篇 |
2016年 | 138篇 |
2015年 | 99篇 |
2014年 | 188篇 |
2013年 | 197篇 |
2012年 | 124篇 |
2011年 | 343篇 |
2010年 | 229篇 |
2009年 | 339篇 |
2008年 | 287篇 |
2007年 | 392篇 |
2006年 | 325篇 |
2005年 | 207篇 |
2004年 | 205篇 |
2003年 | 150篇 |
2002年 | 130篇 |
2001年 | 136篇 |
2000年 | 109篇 |
1999年 | 74篇 |
1998年 | 98篇 |
1997年 | 65篇 |
1996年 | 49篇 |
1995年 | 63篇 |
1994年 | 56篇 |
1993年 | 41篇 |
1992年 | 41篇 |
1991年 | 40篇 |
1990年 | 24篇 |
1989年 | 19篇 |
1988年 | 23篇 |
1987年 | 17篇 |
1986年 | 8篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1975年 | 4篇 |
1974年 | 2篇 |
1973年 | 9篇 |
1972年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有4642条查询结果,搜索用时 14 毫秒
91.
T. de Beer G. Ph. Hoornweg G. J. Grootendorst N. H. Velthorst C. Gooijer 《Analytica chimica acta》1996,330(2-3):189-197
An explorative study on the compatibility of liquid separation systems, such as (micro) liquid chromatography (LC) and capillary electrophoresis (CE), and forward-scattering degenerate four-wave mixing (F-D4WM) as a detection method is presented. F-D4WM is a laser-based technique showing some analogy with holographic spectroscopy: a signal on a theoretical dark background is observed as a result of light absorption by an analyte. Parameters considered are solvent composition focussing on acetonitrile, methanol and water; mobile phases in LC and CE), detector cell construction, and influences of laser beam powers. A specially designed detector cell has been developed to meet the Brewster condition, both at the air-quartz and the quartz-liquid boundaries. For practical reasons, the tested cell has an optical pathlength of 1 mm; reduction to 100 μm is required to apply the cell in microseparations. The F-D4WM technique has been involved for detection in a conventional-size, reversed-phase LC separation of 1- and 2-aminoanthraquinones. The detection limit obtained (for the 1 mm cell) is 2 × 10−5 absorbance units. The experiments indicate that further reduction of background deserves explicit attention. 相似文献
92.
New developments in inductively coupled plasma mass spectrometry (ICP-MS) and laser desorption-time-of-flight mass spectrometry (LD-TOF-MS) for inorganic analysis are described. These include fundamental studies of the ion extraction, process in ICP-MS, development of a highly efficient nebulizer, isotope tracer studies, measurement of elemental speciation by liquid chromatography with ICP-MS detection and characterization of the structures of solids by ion association. The possibilities of determining inorganic species in solutions by electrospray MS are also described. 相似文献
93.
Both absolute molecular weight and molecular sizes (radius of gyration and hydrodynamic radius) of a vinyl-type polynorbornene eluting from size-exclusion chromatography columns were determined by combined with a static and dynamic laser light scattering detector. The hydrodynamic radius of polymer fraction eluting from size-exclusion chromatography columns was obtained from dynamic laser light scattering measurements at only a single angle of 90° by introducing a correction factor. According to the scaling relationship between molecular sizes and molecular weight and the ratio between radius of gyration and hydrodynamic radius, the vinyl-type polynorbornene took a random coil conformation in 1,2,4-trichlorobenzene at 150 °C. 相似文献
94.
硫与金属元素所形成的二元团簇具有很多重要的特性,已受到人们的普遍重视.用激光-串级飞行时间质谱仪,我们曾研究了硫与过渡金属钽、铁等的二元团簇.最近我们选取主族金属元素铝,研究了铝硫团簇的形成及其光解,实验结果表明,与钽硫或铁硫团簇相比,铝硫团簇无论在其组份构成还是在其光解方面,都表现出鲜明的特有规律性.实验的主要参数如下:溅射用激光为Nd:YAG 二倍频,其输出强度控制在约10~7W·cm~(-2),激光的重复频率10Hz 样品位于激光束的焦点附近,由焦距f=50cm 的透镜调整其聚焦状 相似文献
95.
本文扼要地介绍了固体激光质谱学问世20多年来的发展和现状。其中包括有:固体激光质谱的简介和特色;发展过程中有重要贡献科学工作者的主要成就;它的有关基本理论;从仪器和分析实践两个方面介绍其发展概况。文中还就上述几个方面列出带综论性文献,以便读者作进一步了解。最后作者还展望了今后固体激光质谱学的发展前景。 相似文献
96.
徐灿 《高等学校化学学报》1997,18(6):943-946
利用XeCl准分子激光烧蚀多种硅氧多孔结构材料,在负离子通道测得丰富的「(SiO2)nX」^-负离子团簇,并讨论了多孔网结构和表面活性基团的分布对激光能量的吸收,传输及团簇产生的重要作用。 相似文献
97.
This paper reports the development of a method based on capillary electrophoresis with laser-induced fluorescence detection for the simultaneous determination of thiouracil (TU) and phenylthiouracil (PhTU) with high sensitivity (nanomolar range, i.e., attomoles detected). After derivatization with 5-iodoacetamidofluorescein, the analytes were separated by capillary zone electrophoresis using 20 mM phosphate buffer (pH 10.0) and quantified by fluorescence detection. The linearity range, precision, recovery, and detection limits were determined, and the method was shown to be applicable for the determination of TU and PhTU in spiked feed samples and urine. 相似文献
98.
论述了激光拉曼光谱对高分子结构、结晶形态和表征,反应动力学过程和取向的研究,还介绍了纵向声学模、共振、高温高压、光波导和付里叶拉曼光谱在高分子研究中的最新进展。 相似文献
99.
100.
Tsun-Ren Chen 《Journal of Molecular Structure》2005,737(1):35-41
The absorption and emission properties of benzimidazol-2-yl-quinoline (BIQ) and bis (2-(benzimidazol-2-yl) quinolinato) zinc (ZnBIQ) a new emitter used for organic light emitting device (OLED) were reported. Exciplexes are observed for ZnBIQ with N,N′-bis-(1-naphthyl)-N,N′-diphenyl-1,1′-biphenyl-4,4′-diamine (NPB) system, in both electro- and photoluminescent processes. The identification of exciplex emission in co-evaporated and multi-layer ZnBIQ thin film was reported for the first time. The optical formation of the exciplex involves the excitation of a single molecule, followed by the relaxation of that exciton into a lower energy exciplex state. Both BIQ and ZnBIQ possess very high thermal stabilities and can be purified by subliming under the high vacuum condition. Devices consisting of ZnBIQ as the emitting layer have been fabricated, and the emission spectra of ZnBIQ-base devices gave a voltage-dependent spectrum, with the red emission observed (3-7 V), switching over to strong white emission as the bias was raised. 相似文献