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281.
282.
Ronak Eisavi Somayieh Alifam 《Phosphorus, sulfur, and silicon and the related elements》2018,193(4):211-217
ZnFe2O4 nanoparticles were synthesized and used as recyclable magnetic catalyst in the solvent-free conversion of different epoxides to vicinal hydroxythiocyanates with NH4SCN at room temperature. The reactions were carried out by grinding in a mortar with perfect regioselectivity within short times (2-25 min) and with high to excellent yields (75–95%). The nanocatalyst was separated easily using an external magnet and reused for four consecutive cycles without any noticeable loss of efficiency or magnetic property. 相似文献
283.
Michael Heinz Gregor Weiss Dr. Grigoriy Shizgal Dr. Anastasia Panfilova Prof. Dr. Andreas Gansäuer 《Angewandte Chemie (International ed. in English)》2023,62(38):e202308680
We describe a unique catalytic system with an efficient coupling of Ti- and Cr-catalysis in a reaction network that allows the use of [BH4]− as stoichiometric hydrogen atom and electron donor in catalytic radical chemistry. The key feature is a relay hydrogen atom transfer from [BH4]− to Cr generating the active catalysts under mild conditions. This enables epoxide reductions, regiodivergent epoxide opening and radical cyclizations that are not possible with cooperative catalysis with radicals or by epoxide reductions via Meinwald rearrangement and ensuing carbonyl reduction. No typical SN2-type reactivity of [BH4]− salts is observed. 相似文献
284.
In the presence of a catalytic amount of Bi(OTf)3·4H2O and under microwave irradiation, neat mixtures of epoxides and amines afforded smoothly the corresponding 2-amino alcohols. A wide variety of aliphatic amines were reacted with cycloalkene oxide, styrene oxide, and stilbene oxide. The reaction proceeded rapidly and afforded the 2-amino alcohols in high up to quantitative yields. All products could be obtained without aqueous work-up by simple filtration. 相似文献
285.
Wan Xuan Zhang Kang Ye 《中国化学快报》2008,19(2):146-148
Macroporous resin (D201)-supported quartemary ammonium bisulfate (D201-HSO4) was prepared and effectively used in catalyzing the hydrolysis of epoxides or aziridines under mild and non-metal conditions to give the corresponding 1,2-diols and β-amino alcohols in high yields. The catalyst was facilely prepared and recyclable. 相似文献
286.
287.
Hashem Sharghi Mohammad Ali Nasseri 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):1353-1359
2-Phenyl-2-(2-pyridyl)imidazolidine (PPI) catalysis the addition of thiocyanate ion to epoxides to afford g -hydroxy thiocyanate in high yields, mild conditions, and regioselectivity. Thus, several 2-hydroxyethyl thiocyanates, which are useful intermediates toward biological active molecules, are obtained easily in very good yields. 相似文献
288.
Chun-Xi HuangYong Shi Jing-Rong LinRong-Hua Jin Wei-Sheng Tian 《Tetrahedron letters》2011,52(32):4123-4125
A Grignard reagent induced tandem semipinacol rearrangement/chelation-controlled ketone addition process, which converts 20S-hydroxy-5α-pregnane-16(17)-epoxide into an unusual C20-substituted 17S-pregnane-3S,16R,20S-triol, is described. 相似文献
289.
Carbocyclization has been selectively achieved over epoxide formation from a γ-chloro-δ-hydroxy-ketone in the presence of a lithiumamide or using a different strategy in which the related silyloxyenol ether bearing an iodine atom at gamma-position and a silyloxy group in delta-position is reacted with tetrabutylammonium fluoride. These approaches take advantage of (i) the poor reactivity of the intermediate β-halogeno lithiumalkoxide first formed in the former case and (ii) the poorer ability of the fluoride ion to desilylate a silyl ether over a silylenol ether. 相似文献