D072型树脂脱除过氧化氢中金属阳离子的工艺研究

实验考察D072型阳离子交换树脂在交换柱中脱除过氧化氢中微量金属阳离子的动态行为．通过改变料液流速、高径比、料液中交换离子浓度及料液组成等参数，绘制不同条件下的透过曲线，以此考察D072型树脂对过氧化氢中金属阳离子的动态交换性能，从而确定适宜的工艺条件，为工业化生产提供科学依据．     

Preparation, structure, and dynamics of a nickel π-allyl cyanide complex

The complex (dippe)Ni(η³-allyl)(CN) has been prepared and fully characterized (dippe=bis-(diisopropylphosphino)ethane), including X-ray diffraction studies, as a square pyramidal structure. The complex shows dynamic ¹H-NMR behavior consistent with substantial structural rearrangements upon π to σ allyl interconversion. A comparison is made with (dippe)Ni(η³-allyl)Br, which also displays a square pyramidal structure.     

POPOP诱导环糊精形成纳米管的研究

用紫外吸收光谱、稳态荧光、荧光各向异性和动态光散射等方法研究了2,2′-p-亚苯基-双(5-苯基噁唑) (POPOP)分子与环糊精(CD)的相互作用. 结果表明, POPOP分子在浓度较低时与β-CD形成1:2的包合物, 在浓度较高时可以进一步诱导β-CD形成纳米管结构. 同时发现, POPOP分子也可以诱导γ-CD形成纳米管结构. 对比于β-CD, POPOP分子在γ-CD水溶液中的荧光发射峰, 不仅有明显的红移而且也缺失了精细结构, 呈现较宽的大包峰. 这是由于POPOP分子成对进入γ-CD空腔形成了激基缔合物的缘故. pH和温度效应实验进一步表明, POPOP诱导β-CD形成的纳米管在pH大于12和温度高于331 K的环境下不能稳定存在.     

Thermal behaviour and slow molecular mobility in two isomers of biphenylmethanol

This research was aimed to investigate the role of clay on the combustion and kinetic behavior of crude oils in limestone matrix. For this purpose, simultaneous TG (thermogravimetry) and DTA (differential thermal analysis) experiments were performed at three different heating rates as 10–15 and 20°C min^–1, respectively. A uniform trend of decreasing activation energies was observed with the addition of clay. It was concluded that clays surface area affects the values of Arrhenius constant, while it is the catalytic properties of clay, which lower the activation energies of all the reactions, involved in the combustion process.     

聚丙烯酰胺凝胶结构非均匀性的动态光散射研究

利用动态光散射技术研究了聚丙烯酰胺 (PAAm)凝胶结构的非均匀性 ,分析了PAAm凝胶结构非均匀性的形成原因及凝胶动态光散射的数据处理方法和分析结果的物理意义 .研究结果表明 ,PAAm凝胶中含有动态相关长度 (LC)不同的两相 ,其中 ,LC 为 10～ 2 0nm的区域是聚合物稀疏相 ,LC 为 85nm左右的区域是聚合物密集相 ,两相的不均匀分布形成了PAAm凝胶结构的非均匀性 .分析表明 ,PAAm凝胶存在两相主要是由于单体和交联剂的溶解度存在差异所致 .随交联度增大 ,PAAm凝胶结构的非均匀性显著增强     

Solubilization and applications of single-walled carbon nanotubes into aqueous and organic media by the use of nanometer size-controlled fluoroalkyl end-capped oligomeric aggregates

We have studied on the solubilization of single-walled carbon nanotubes (SW-CNTs) into aqueous and organic media by the use of a variety of nanometer size-controlled fluorinated self-assemblies, which were formed by the aggregations of end-capped fluoroalkyl segments in fluoroalkyl end-capped acrylic acid oligomers [R_F-(ACA)_n-R_F], N,N-dimethylacrylamide oligomers [R_F-(DMAA)_n-R_F], acryloylmorpholine oligomers [R_F-(ACMO)_n-R_F], and N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomers [R_F-(DOBAA)_n-R_F]. Fluorinated self assemblies formed in organic media (colorless solutions) could solubilize SW-CNTs into organic media to afford the transparent pale yellow solutions. The dynamic light scattering measurements showed that the size of fluorinated self-assemblies increased after the solubilization of SW-CNTs into organic media. It was suggested that the solubilization of SW-CNTs into organic media is due to the encapsulation of SW-CNTs into fluorinated assemblies. Fluorinated assemblies were also able to solubilize SW-CNTs into water to give the transparent gray solutions. Among a variety of fluorinated assemblies, fluorinated assemblies formed by R_F-(ACMO)_n-R_F [R_F = CF(CF₃)OC₆F₁₃] oligomer was more effective for the solubilization of SW-CNTs into both aqueous and organic media. Contact angle measurements of dodecane and the fluorescence spectra for poly(methyl methacrylate) cast film modified by fluorinated self-assemblies—SW-CNTs complexes showed that SW-CNTs are dispersed above the PMMA surface.     

Effect of the complex forming ion on the physicochemical characteristics of solvation of tetraphenylporphine complexes

The enthalpies of dissolution, transfer, and axial coordination for the Cd(II), Co(II), Mn(III), Fe(III), and Cr(III) complexes of tetraphenylporphine, H₂(TPP), in nonpolar (C₆H₆, CCl₄) and electron-donating solvents (DMF, DMSO, Py,c-C₅H₁₀NH) have been determined calorimetrically at 298.15 K. On the basis of thermogravimetrical data for the corresponding crystallosolvates the composition, thermal stability, and energy of intermolecular interaction of the metal-porphine complexes with pyridine have been calculated. Complexing in noncoordinating solvents brings about no radical change in the physicochemical characteristics of axial coordination which depend critically on the electron structure of the complex-forming metal.Translated fromfzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 846–850, May, 1993.     

动态力学温度谱分析的新方法及其应用 Ⅳ.从动态力学温度谱求两相聚合物的双活化能和应力松弛

提出用两个热流变简单粘弹体的并联体系作为两相聚合物的粘弹模型,将先前的动态力学温度谱分析方法推广到两相聚合物中去.运用这种新方法从动态力学数据求出了PET/70PHB共聚物的双活化能,其中150℃左右的转变活化能为71.9kcal/mol,70℃左右的转变活化能为117.5koal/mol,这一数值与文献上PET/60PHB这个转变的活化能120kcal/mol相接近.文中还计算了共聚物在不同温度下的10s应力松弛模量,所得结果与实测值相吻合.     

Separation of peptides and proteins by capillary electrophoresis using acidic buffers containing tetraalkylammonium cations and cyclodextrins

A method for improving separations of peptides and other positively charged species in capillary zone electrophoresis with untreated capillaries using acidic buffers containing tetraalkylammonium cations is described. Tetramethylammonium and tetrabutylammonium cations dynamically modify the capillary surface, leading to a reversal in the direction of the electroosmotic flow. As a result, the adsorption of positively charged peptides and proteins is minimized, and resolution and peak capacity are improved as the migration of cationic analytes is counterbalanced by the electroosmotic flow. The combining effect of reversing electroosmotic flow and cyclodextrin inclusion complexation on separations of closely related peptides and a protein mixture, as well as tryptic digest of hemoglobin is demonstrated.     

磁化作用对汽油动态挥发性影响的研究

用热重（TG）分析和自行设计的原位动态挥发实验，研究了在不同条件下汽油的挥发性，结果表明，磁化空气或磁化汽油都可提高汽油的挥发性，而汽油和空气共同磁化，可更大幅度地提高汽油的挥发性。