流动注射-电感耦合等离子体发射光谱法测定天然水中的钙和镁

本文采用流动注射－电感耦合等离子体发现光谱联用技术测定了天然水中的钙、镁元素。考察了试液的雾化和曝光时间及载气压力等因素对分析信号的影响。通过与气动连续进样的对比，测出了钙、镁在流动注射进样下的分散系数。本法在测定钙、镁含量高的水性时，不需对试样进行稀释处理。对五个水样中钙、镁的分析结果与EDTA络合滴定法相吻合。     

Interlaboratory comparisons between results from testing metallurgical products for precious metal content

Problems verifying the accuracy of analyses of non-standardized materials for precious metal (PM) content have arisen at the Norilsky Nickel plant, which is a major producer of nickel, copper, and PMs in Russia. Because of the unavailability of certified reference samples for direct accuracy verification, a program of interlaboratory comparisons (ILC) was developed. This program was based on testing three semi-products of the PM production process for PM content. On program completion, a total of 826 results in 98 runs had been obtained. For each run, the calculated mean value of PM concentration was taken to be the reference value. The results obtained by Norilsky Nickel were in agreement with the reference values within the standard deviations calculated for the values. The quality of results yielded with the ILC program, as assessed via the Z-criterion, is regarded as satisfactory.Presented at the Second International Conference on Metrology – Trends and Applications in Calibration and Testing Laboratories, November 4–6, 2003, Eilat, Israel.     

浅析波谱分析课程教学改革

根据在波谱分析课程教学中遇到的一些实际问题,本文探讨了便于波谱分析课程教学的几种方法,并收到了较好的教学效果.     

数字光处理背投电视色度学特性的研究

以色度学的基本理论为基础,结合数字光处理光学引擎的工作原理,探讨了单片式数字光处理光学引擎的彩色显示原理和色温调节原理.提出了单片式数字光处理光学引擎色度学特性的理论计算公式,并利用该公式对夏新DL52HWT型投影电视光学引擎的显示三原色色度坐标、白场平衡的色度坐标和相关色温以及颜色复现误差等色度学特性进行了计算和分析,并对理论计算公式进行了验证.     

Effective Hamiltonian approach to doubly degenerate electronic states

Effective vibronic Hamiltonian models are built for E ⊗e Jahn-Teller systems and analytical solutions are obtained through Lie algebraic methods. Although approximate, we show that these models allow in particular to recover the possible ground state crossover when quadratic couplings are present. The equivalence of E ⊗e and G' ⊗e vibronic systems in cubic symmetry is precisely established through a particular realization of the electronic operators for an orbital quadruplet. We show how this equivalence is broken by a rovibronic interaction which, for a G' ⊗e system, still gives an exactly solvable model.     

上机房营子遗址出土陶器的XRF分析研究

利用X射线荧光对上机房营子遗址出土陶器残片的成分进行分析,用社会科学用统计软件包(SPSS)对实验数据进行多元统计分析.结果表明,不同文化期的样品基本自成一类.本文还将上机房营子遗址与三座店遗址的出土陶片进行比较分析,发现夏家店下层文化晚期两地可能存在着文化交流.     

Total analysis of surface structure and properties by UHV transfer system

We have developed an ultrahigh-vacuum (UHV) complex sample preparation and analysis system, which realizes a reliable surface science analyzing various characters on an identical surface. The system contains three sample-preparation-and-characterization chambers and five analysis chambers. They are (1) an electronic-properties-characterization chamber, (2) a magnetic-properties-characterization chamber, (3) an organic-molecule chamber, (4) UHV SEM, (5) a high-energy-resolution angle-resolved photoelectron spectrometer, (6) a high-energy-resolution display-type spherical mirror analyzer, (7) a room-temperature (RT) STM, and (8) an optical-properties characterization chamber. A special sample holder is used with six electrodes on it, which enables accurate temperature measurement of a sample by connecting a thermocouple directly to the sample even if it is transferred. Four other electrodes can be used for construction of various circuits including evaporators. Some examples are shown.     

基于人工神经网络的肉类光谱识别

利用自组的光纤探头式光谱仪对载体肉类表面进行光谱测量,采用反向传播人工神经网络(BP-ANN)对肉类可见光谱进行识别,分析了隐层神经元、期望误差、判别输出范围等网络参数的调整对识别功能的影响.基于大量实测数据样本,优化网络结构参数选择,建立了良好的人工神经网络,对肉类光谱识别率达到97.5%.     

基于结构元的复模糊数及其序列极限

复模糊数是模糊复分析中的基本概念,在模糊复分析中,它的运算是基于扩张原理的形式给出的,是对元素遍历某个条件所对应的结果进行运算,这种遍历过程给实际操作带来了很多的不便,因此,在一定程度上也阻碍了模糊复分析理论的应用.对此,本文基于模糊结构元的理论基础,探讨了复模糊数运算的另一种新的途径,这种方法简化了复模糊数的运算,也...     

Study of molecular interactions between lipids and proteins using dynamic surface tension measurements: a review

Molecular interactions between small molecules and proteins, such as binding of lipids to proteins, are of fundamental importance in various biological processes. A recently-developed method based on dynamic surface tension measurement is efficient and versatile in detecting such molecular interactions: Axisymmetric Drop Shape Analysis (ADSA) provides a tool for measuring the surface tension (γ) response to surface area changes. Through the analysis of the γ response pattern, surface competitive adsorption between small organic molecules and protein molecules can be detected. Surface squeeze-out of small molecules by proteins can also be observed. Molecular binding of lipids to proteins manifests itself in a modification of the γ response which is not compatible with a simple superposition of the two individual patterns. The specific binding can be studied in terms of dose effects and specificity.