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31.
32.
Several Pd-catalyzed reactions were explored to further functionalize the bromo-substituted 4-amino-1,2,4,5-tetrahydro-2-benzazepin-3-one scaffold (Aba). We report in this paper suitable reaction conditions for Suzuki, Buchwald-Hartwig, and Heck reactions. The substitution pattern of the starting aminobenzazepinone turned out to be crucial for the success of these transition metal-catalyzed reactions, which often required modifications of standard literature procedures. The Pd-catalyzed methods provide access to novel substitution patterns of the Aba scaffold. 相似文献
33.
K. V. Storozhuk 《Proceedings of the American Mathematical Society》2007,135(6):1861-1863
We give a short proof of a generalization of the Rolewicz theorem based on the uniform boundedness principle.
34.
我们采用半经验的Gupta多体势结合遗传算法,系统地研究了Con(n=3-60)团簇的几何结构特性.我们发现在钴团簇的生长中存在一个类fcc构型与类Ih构型之间的竞争,从n=39开始,钴团簇呈现出明显的Ih生长模式.Con(n=3-60)团簇的幻数为13,19,23,38,55,结合钴团簇的平均最近邻原子间距和平均配位数,分析了钴团簇幻数序列存在的原因.我们发现团簇内部原子具有增强团簇对称性和加强团簇稳定性的显著作用. 相似文献
35.
Myung-Soon Lee 《Applied Surface Science》2006,252(14):5019-5025
We prepared high quality Au(1 1 1) film on Si wafer through the spin coating and thermal decomposition of a gold ink, spin-coated-and-fired (SCAF) Au film. The X-ray measurements, XRD and pole-figure analysis, showed that the SCAF Au film has a (1 1 1) out-of-plane orientation with a random in-plane orientation. In order to confirm the chemical activity of the SCAF Au film, we demonstrate the formation of patterned structures with the film by using soft lithography technique. The chemical activities of this physically stable SCAF Au film to the alkanethiols were at least equivalent those of physically deposited the Au films. The possibility of the mass production of micro patterned structure with the SCAF Au film was also demonstrated over the wide region on Si wafer by the microcontact lithography. These suggest that the Au film will help the easy fabrication of various nanosized devices on Si wafer and other substrates. 相似文献
36.
关于PFI-代数与剩余格 总被引:10,自引:0,他引:10
本文提出了一种强FI代数-PFI代数,并且深入研究了它的性质,借此进一步揭示了FI-代数和剩余格之间更加密切的联系,进而以FI-代数为基本框架建立了R0-代数、正则剩余格等逻辑系统的结构特征(包括对隅结构)及其相互关系.这种以FI-代数为基础来统一处理剩余格和R0-代数的方法,同样适合于格蕴涵代数和MV代数等代数结构,而且从中更能清楚地看出它们之间的密切联系,也将有助于对相应形式逻辑系统与模糊推理的研究. 相似文献
37.
X. Yang 《Applied Surface Science》2006,252(10):3647-3657
The room-temperature adsorption and thermally induced processes of propionic acid and pyruvic acid on Ni(1 0 0) have been investigated by electron energy loss spectroscopy (EELS). Computational vibrational analysis of the optimized bidentate structures for acid-Ni model complexes (involving the organic acid and a Ni atom) has been performed by using the two-layer ONIOM method with the Density Functional Theory and used to interpret the vibrational EELS data. Dehydrogenation of the hydroxyl group is found to result in bonding of the carboxylate group in the propionate and pyruvate adspecies to either a single Ni surface atom in a bidentate configuration or two neighbouring Ni atoms in a bridge configuration. Given the similarities in the total energies and related vibrational frequencies obtained by the calculations in the case of pyruvate adspecies, it is difficult to differentiate the alternate adsorption structure, in which the keto O and hydroxyl O atoms are bonded to a Ni atom in a five-member chelate ring configuration. Furthermore, temperature-dependent EELS studies show that both the propionate and pyruvate adspecies could decompose upon annealing to above 400 K and further dissociate to CO adspecies above 550 K and to C and/or O above 600 K. 相似文献
38.
We study the existence and the continuity properties of the boundary values on the real axis of the resolvent of a self-adjoint operator H in the framework of the conjugate operator method initiated by Mourre. We allow the conjugate operator A to be the generator of a C0-semigroup (finer estimates require A to be maximal symmetric) and we consider situations where the first commutator [H,iA] is not comparable to H. The applications include the spectral theory of zero mass quantum field models. 相似文献
39.
Intermolecular Interactions in 8-Aza-D-Homogonane Crystals and their Manifestation in the IR Spectra
A. A. Akhrem A. A. Govorova O. V. Gulyakevich A. S. Lyakhov A. L. Mikhal'chuk I. V. Skornyakov G. B. Tolstorozhev 《Journal of Applied Spectroscopy》2004,71(2):156-163
Crystalline modifications of 8-aza-D-homogon-1,3,5(10),13-tetraen-12,17a-dione have been investigated by IR spectroscopy and x-ray structural analysis. It is shown that this compound crystallizes from solutions of chloroform with hexane in the form of a solvate comprised of chelate hydrogen bonds between the hydrogen atom of the chloroform molecule and the oxygen atoms of the carbonyl groups of the 8-azasteroid molecule. A relation between the changes in the characteristic absorption bands of the CH2-, C=O-, and I=C groups and the structure of the crystalline modifications has been established. 相似文献
40.
Jin-Mok Hur Chung-Seok Seo Sun-Seok Hong Dae-Seung Kang Seong-Won Park 《Reaction Kinetics and Catalysis Letters》2003,80(2):217-222
The concept of a novel electrochemical reduction process for the treatment of spent nuclear fuels in Li2O-LiCl molten salt was proposed and fresh tests using U3O8 powder were carried out to elucidate the reaction mechanism and verify the feasibility of the process. Electrolysis of Li2O and reduction of U3O8 powder took place simultaneously at the cathode part of the electrolysis cell via a catalytic EC mechanism and the conversion of U3O8 to U metal was more than 99%.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献