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21.
Aldehydes undergo smooth conjugate addition to α,β-unsaturated ketones in the presence of 5-(2-hydroxyethyl)-1,3-thiazolium halides and DBU adsorbed onto the surface of basic alumina under microwave irradiation and solvent-free conditions to afford 1,4-diketones in enhanced yields and reduced reaction times compared to conventional methods. 相似文献
22.
The products from the condensation of acetone-anils ( 1 ) and TCNE reaction were characterized after separation. The main products, tricyanoethylene derivatives ( 7–9 ) were isolated with the malonodinitrile derivatives ( 10–12 ), respectively. The [2+2] cycloaddition product ( 13 ), namely 5-methoxy-3,4-(2′,2′,3′,3′-tetracyanocyclobutano)-l,2-dihydro-2,2,4-trimethylquinoline also has been isolated. The distribution of these three products is substituent dependent. 相似文献
23.
Several Pd-catalyzed reactions were explored to further functionalize the bromo-substituted 4-amino-1,2,4,5-tetrahydro-2-benzazepin-3-one scaffold (Aba). We report in this paper suitable reaction conditions for Suzuki, Buchwald-Hartwig, and Heck reactions. The substitution pattern of the starting aminobenzazepinone turned out to be crucial for the success of these transition metal-catalyzed reactions, which often required modifications of standard literature procedures. The Pd-catalyzed methods provide access to novel substitution patterns of the Aba scaffold. 相似文献
24.
O. N. Lyubenko I. G. Ermolenko L. D. Patsenker Krasovitskii I. N. Tur 《Chemistry of Heterocyclic Compounds》2003,39(4):511-519
The behavior of dimethylamino-substituted 7H-benzo[de]pyrazolo[5,1-a]isoquinoline-7-ones, synthesized for the first time, under conditions of the Vilsmeier-Haack reaction. It has been shown that, on heating with POCl3 and DMF, they are converted by electrophilic substitution at the position ortho to the dimethylamino group, followed by cyclization of the iminium adduct to a quinazolinium salt. When an acetyl group is present, the Arnold reaction, leading to the formation of a chloroaryl, accompanies the heterocyclization. The rates and proportion of the reaction products depend on the position of the dimethyl groups relative to the pyrazole ring. 相似文献
25.
继续作者最近的研究,用所谓的Hankel向量方法建立S[a,b]函数类中带边界插值数据的Nevanlinna-Pick插值问题与[a,b]上的某种带约束条件的Hausdorff矩量问题之间解集之间明确的一一对应关系.通过N[a,b]函数类与S[a,b]函数类之间的联系,从而由BNP(N[a,b])问题的可解性准则和解的参数化描述获得BNP(S[a,b)问题的可解性准则和解的参数化表示. 相似文献
26.
Giorgio AbbiatiAntonio Arcadi Egle BeccalliElisabetta Rossi 《Tetrahedron letters》2003,44(28):5331-5334
Intramolecular cyclization of 2-acyl-1-propargyl-1H-indoles in the presence of ammonia provides an easy entry to pyrazino[1,2-a]indole nucleus. 相似文献
27.
HAOJie LIXing 《声学学报:英文版》2003,22(1):77-85
In a syllable-based speaker-independent Chinese continuous speech recognition system based on classical Hidden Markov Model(HMM),a Bayesian approach of keyword confidence estimation is studied,which utilizes both acoustic layer scores and syllable-based statistical language model(LM) score.The Maximum a posteriori(MAP) confidence measure is proposed,and the forward-backward algorithm calculating the MAP confidence scores is deduced.The performance of the MAP confidence measure is evaluated in keyword spotting application and the experiment results show that the MAP confidence scores provide high discriminability for keyword candidates.Furthermore,the MAP confidence measure can be applied to various speech recognition applications. 相似文献
28.
29.
The reaction of a new fluorinated unsymmetrical allenylazine with dimethyl acetylenedicarboxylate and phenylacetylene affords the combined intra-intermolecular criss-cross cycloaddition products, 2,3-disubstituted-1,10-diazatricyclo[5.2.1.04,10]deca-2,6-diene derivatives. The products contain three fused five-membered rings with two nitrogen atoms within an unsaturated heterocyclic system. The structures were assigned using 2D NMR correlations and in the case of the phenylacetylene adduct by X-ray structure analysis. 相似文献
30.
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. 相似文献