La1-xNdxSrCoO4催化剂的合成及其催化性能

采用聚丙烯胺溶胶-凝胶法制备了类钙钛矿La1-xNDxSrCoO4(x=0.1～0.9)复合氧化物催化剂,考察了其对CO和C3H8的催化氧化活性,并运用XRD、IR和TPR等手段对催化剂进行了表征.结果表明,所制备的样品均具有K2NiF4型结构,适量Nd2O3的加入增加了LaSrCoO4的催化活性,使LaSrCoO4催化剂粒度变小、晶格畸变率变大及与氧的结合能力减弱,从而有利于CO和C3H8氧化活性的提高.     

NO-2-I-体系双波长紫外分光光度法测定痕量亚硝酸根

在稀盐酸介质中,亚硝酸根氧化碘化钾的反应产物I-3在288nm和352nm处有两个强吸收峰.基于此建立了双波长紫外分光光度法测定痕量NO-2的新方法.该法简便、快速、选择性好,线性范围为0-0.4μg/mL,检出限为3.4×10-9g/mL.用于河水、井水、矿泉水中亚硝酸根的测定,结果令人满意.     

Fabrication of patterned gold electrodes with spin-coated-and-fired Au(1 1 1) film by the soft lithography

We prepared high quality Au(1 1 1) film on Si wafer through the spin coating and thermal decomposition of a gold ink, spin-coated-and-fired (SCAF) Au film. The X-ray measurements, XRD and pole-figure analysis, showed that the SCAF Au film has a (1 1 1) out-of-plane orientation with a random in-plane orientation. In order to confirm the chemical activity of the SCAF Au film, we demonstrate the formation of patterned structures with the film by using soft lithography technique. The chemical activities of this physically stable SCAF Au film to the alkanethiols were at least equivalent those of physically deposited the Au films. The possibility of the mass production of micro patterned structure with the SCAF Au film was also demonstrated over the wide region on Si wafer by the microcontact lithography. These suggest that the Au film will help the easy fabrication of various nanosized devices on Si wafer and other substrates.     

关于PFI-代数与剩余格

本文提出了一种强FI代数-PFI代数,并且深入研究了它的性质,借此进一步揭示了FI-代数和剩余格之间更加密切的联系,进而以FI-代数为基本框架建立了R0-代数、正则剩余格等逻辑系统的结构特征(包括对隅结构)及其相互关系．这种以FI-代数为基础来统一处理剩余格和R0-代数的方法,同样适合于格蕴涵代数和MV代数等代数结构,而且从中更能清楚地看出它们之间的密切联系,也将有助于对相应形式逻辑系统与模糊推理的研究．     

基于伪随机排列的密码模型及其在MATLAB中的实现

给出了关于密码编码学的一般数学模型,在此基础上提出了一种新颖的能用于中文文稿加密的实用有效的编码方法:基于伪随机排列的密码模型(PRP算法),并在MATLAB中实现了上述模型.通过唯密文攻击和已知明文攻击的密码分析,得知该算法具有很强的抵抗攻击能力.     

乌骨鸡活性肽对体外非酶糖基化的抑制作用

采用正交实验优化了体外非酶糖基化反应体系,体系中加入不同浓度的乌骨鸡活性肽I、Ⅱ37 ℃孵育,同时以肌肽为阳性对照,观察乌骨鸡活性肽对非酶糖基化反应的影响.通过测定预定时间体外非酶糖基化体系的吸光度和荧光值计算乌骨鸡活性肽对非酶糖基化反应的抑制率和对非酶糖基化终产物生成的抑制率.结果表明乌骨鸡活性肽Ⅱ对体外非酶糖基化反应和非酶糖基化终产物的生成均具有较强的抑制作用.     

一维细胞神经网络的完全稳定性分析

运用Lyapunov函数方法,讨论了一维细胞神经网络模型的完全稳定性问题,给出了四组使模型具有完全稳定的充分条件.     

Synthesis and cyclization of 1-arylalk-1-ene-3,5-diynylamines

An investigation of the reaction of 1-lithio-1,3-diynes, generated in situ, with nitriles has been carried out. In the case of aromatic nitriles 1-arylalk-1-ene-3,5-diynylamines are formed, which undergo dimerization and cyclization on isolation, giving 3-(alka-1,3-diynyl)-4-(alk-2-ynyl)-2,6-diarylpyridines. The effect of the nature of the substituent in the benzonitrile molecule on the selectivity of the reaction and the yield of the products has been determined. A scheme is proposed for the conversions and the structures of the intermediates have been established. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 701–710, May, 2006.     

Correlations of Active Galactic Nuclei with Microquasars

Correlations of active galactic nuclei (AGNs) with microquasars are discussed based on the coexistence of the Blandford-Znajek (BZ) and magnetic coupling (MC) processes (CEBZMC) in black hole (BH) accretion disk.The proportions of several quantities of BH systems for both AGNs and microquasars are derived by combining the observational data with CEBZMC. It is shown that the square of the magnetic field at the BH horizon is inversely proportional to the BH mass, while the accretion rate of the disk is proportional to the BH mass. In addition, the very steep emissivity indexes from the recent XMM-Newton observations of the nearby bright Seyfert 1 galaxy MCG-6-30-15 and the microquasars XTE J1650-500 are well fitted by considering the MC effects on the disk radiation. These results suggest strongly the correlations of A GNs with microquasars.     

Magnetic behavior of the bond random mixed compound FE(BR x I1−x )2(x = 0.9) with Mössbauer spectroscopy

The bond random mixed compound Fe(Br_0.9I_0.1)₂ has been studied by magnetization and Mössbauer measurements. Although the zero-field cooled and field-cooled magnetization variations are not like a typical spin glass one, the Mössbauer spectrum below Néel temperature shows a hyperfine field distribution. It implies that the 10% FeI₂ mixed in FeBr₂ can be induced by the bond random effect which causes the sample to exhibit a spin glass-like behavior.