磁流变智能液场致微结构变化的Monte Carlo模拟

从磁流变液中存在的各种相互作用势出发，对Ｎ＝１００个球形羰基铁颗粒均匀分布于一正方形二维体系之中的物理模型，利用ＭｏｎｔｅＣａｒｌｏ方法和Ｍｅｔｒｏｐｌｉｓ算法着重计算了磁流变智能液的场致微结构变化。计算结果表明，磁流变液（ＭＲＦ）的流变效应在外磁场中的变化是由于其ＭＲＦ中磁性颗粒的成链团簇有序化所致。这与磁流变液在外磁场中熵的下降和对ＭＲＦ的光学显微镜观察结果是一致的。     

基于存货质押融资的联盟式银行职能外包最优决策研究

本文将外包思想引入存货质押融资业务中,从供应链的角度分析银行、物流企业和中小企业之间的关系。文中提出了三种外包模式,着重分析了单阶段情况下链状联盟模式的最优化问题,并证明了其解的存在性。最后比较了直接信息和非直接信息情况下银行和物流企业联盟单位产品收益的大小。     

(C_2H_(10)N_2)[H_3As_3O_(10)]的水热合成与晶体结构

采用中温水热方法合成了新化合物(C2H10N2)[H3As3O10].利用X射线粉末衍射仪、红外光谱仪、热重分析仪及X射线单晶衍射仪表征了产物的结构.结果表明:该化合物属于单斜晶系,P2(1)/n空间群;晶胞参数为a=0.808 3(6)nm,b=1.446 9(9)nm,c=0.892 0(8)nm,β=98.16°,V=1.032 7(14)nm3,Z=4,F(000)=864,R1=0.025 3,wR2=0.093 4.其化学式为C2H13As3N2O10,分子量Mr=449.90.该化合物是由有机胺阳离子支撑的第一个具有一维链状结构的砷酸盐化合物,相邻的砷酸盐链通过AAAA堆积方式形成三维拓扑扩展结构.     

链状Eu(BO_2)_3的合成与发光性能研究

采用固相反应合成出链状结构的稀土硼酸盐Eu(BO2)3发光材料。分别利用XRD、TEM、SAED、EDS和PL等测试技术对产物进行了研究,结果表明:链状结构的Eu(BO2)3属于单斜晶系,空间群为I2/a,直径约10～15nm,长度达几个微米,探讨了链状Eu(BO2)3的生长机理。在395nm紫外光激发下,Eu(BO2)3能发出Eu3+的特征红色荧光,发射主峰位于591nm,归属于5D0→7F1磁偶极跃迁。     

一类链状图的枚举特征——纪念李国平院士吴新谋教授诞辰100周年

在并发程序复杂性度量研究中, 作者曾定义了所谓B图, 用以作为 Ada 并发程序中一种会合关系的模型. 该文研究B 图的一种特殊情况---BB图, 一类链状图.n节点 BB 图是在n个节点、高为n-1的有向树上再添加若干条边,其约束条件是: 每个节点的入度不大于二, 每个节点的出度也不大于二. 该文给出BB 图图的若干若干枚举特征,并指出这些特征同第二类Stirling数的密切关系.     

链状正则图的平均距离

本文构造了一类链状正则图G_k∶δ,求出了它们的平均距离D(G_k.δ),并得到关系式上式等号成立当且仅当δ=4f且k=0.这个估计式指出了施容华猜想[1]D(G)≤n/(δ 1)不成立. 文中进一步证明了这一类链状正则图有最大的直径,所以可以作出猜想: 若G是n阶连通图,则D(G)<(n 1)/(δ 1),其中δ是图G的最小度。     

六氢吡啶团簇的研究

The 6H-pyridine clusters have been studied by the TOF mass spectrometry, the VUV from synchrotron radiation and the molecular beam technique. Three-type clusters are observed in the VUV photoionization mass spectroscopy: Pn+(n=2-5,P stands for 6H-pyridine molecule), PnH+ (n=2-4) and Pn (H2O)m+(n=4,5, m=1;n=6, m=1,2). The PnH+ clusters may have the chain structures, the Pn+ and Pn(H2O)m+ clusters may have the cyclic structures, all of these are formed by the hydrogen-bond.     

L-丙氨酸桥联配位聚合物[Cu2(L-ala)2(phen)2]n· 2nClO4·2nH2O的合成及其结构

The complex, [Cu2(L-ala)2(phen)2]n·2nClO4.2nH2O (L-ala=L-alaninate, phen=1,10-phenanthroline) has been synthesized and investigated by elemental analysis, IR spectroscopy, and X-ray diffraction methods.The complex crystallizes in the monoclinic space group P21 with a=1.1611(4) nm, b=0.717 2(2) nm, c=2.0741(7)nm, β=101.028 (6)°,V = 1.695 4(9) nm3, Dc= 1.760 g. Cm-3, Z=4,μ= 1.493 mm-1, F(000) =916, R =0.052 2, wR =0.1279for 7 131 unique reflections. The cations of [Cu2(L-ala)2(phen)2]n2n+ have an one-dimensional polymeric structure,due to the bridging of two Cu(phen)2+ units by a carboxylate group of L-alaninate, and each Cu(Ⅱ) ion is in a slightly distorted square-pyramidal coordination geometry, with the phen (N,N') and the L-ala (N,O) acting as bidentate ligands in the equatorial plane and another carboxylate oxygen atom from a symmetry-related neighboring Lalaninate ion in the apical position.     

L-丙氨酸桥联配位聚合物[Cu2(L-ala)2(phen)2]n·2nClO4·2nH2O的合成及其结构

The complex, [Cu₂(L-ala)₂(phen)₂]_n·2nClO₄·2nH₂O(L-ala=L-alaninate, phen=1,10-phenanthroline) has been synthesized and investigated by elemental analysis, IR spectroscopy, and X-ray diffraction methods. The complex crystallizes in the monoclinic space group P2₁ with a=1.161 1(4) nm, b=0.717 2(2) nm, c=2.074 1(7) nm, β=101.028(6)°, V=1.695 4(9) nm³, D_c=1.760 g·cm^-3, Z=4, μ=1.493 mm^-1, F(000)=916, R=0.052 2, wR=0.127 9 for 7 131 unique reflections. The cations of [Cu₂(L-ala)₂(phen)₂]_n²ⁿ⁺ have an one-dimensional polymeric structure, due to the bridging of two Cu(phen)²⁺ units by a carboxylate group of L-alaninate, and each Cu(Ⅱ) ion is in a slightly distorted square-pyramidal coordination geometry, with the phen (N,N′) and the L-ala(N,O) acting as bidentate ligands in the equatorial plane and another carboxylate oxygen atom from a symmetry-related neighboring L-alaninate ion in the apical position. CCDC: 277541.