Investigation of Hydrolysis in Poly（ethylene terephthalate） by FTIR-ATR

The hydrothermal aging of poly(ethylene terephthalate)(PET) was investigated at 70 95 °C. A new method to investigate the hydrolysis degree of PET by Fourier transform infrared spectroscopy(FTIR) was proposed. The spectra during the hydrothermal aging were measured using attenuated total reflection accessory(ATR). Peak resolving of carbonyl regions was performed, and the ratio of two groups of bands representing carboxylic acids and esters respectively were calculated to show the hydrolysis degree of ester groups in PET. The acid/ester ratio shows exactly the same trend as the average chain scission number per unit mass at various temperatures and thus can be used as a parameter to characterize the hydrolysis and random chain scission of PET. This method related to the hydrolysis mechanism directly, is simple, fast and convenient compared to the traditional methods such as viscometry, end-group titration and size exclusion chromatography(SEC). It may also be useful in hydrolysis characterization of other polyesters.     

初应力下压电半导体板中SH波的传播特性

针对无限大n-型压电半导体板,论文理论研究了其在初应力作用下水平剪切波的传播特性。基于压电半导体三维宏观理论和边界条件得到色散关系,结合数值算例,系统分析了边界条件、初始载流子浓度、板的厚度和初应力大小对SH波传播特性的影响。此外,讨论了初应力下两种不同材料中的SH波传播。研究显示：较小的初应力对相速度影响很小可忽略,当初应力达到一定值时波速急剧下降;类似地,初应力足够大时衰减才会逐渐加强。计算结果对压电半导体器件设计具有一定的理论指导意义。     

The effect of configuration complex on dielectronic recombination process in highly ionized plasmas

This paper analyses the effect of configuration complex on dielectronic recombination （DR） process in highly ionized plasmas （Xe^26＋, Dy^38＋, W^46＋） by using the multiconfiguration relativistic Hartree-Fock method. Resonant and nonresonant radiative stabilizing transitions and decays to autoionizing levels followed by radiative cascades are included. Collisional transitions following electron capture are neglected. The remarkable difference between the isoelectronic trend of the rate coefficients for DR through 3d^94l4l′ and through 3d^94l5l′ is emphasized. The trend of DR through 3d^94l4l′ shows irregularities at relatively low temperature due to the progressive closing of DR channels as atomic number Z increases.     

On the differentiability of depth distribution function of deposited energy, momentum and ion range

Based on the translational invariance of a medium,a new theorem has been proposed and proved rigorously:the depth distributions of the deposited energy,momentum and ion range must be infinitely differentiable functions in amorphous or polycrystalline infinite targets by ion bombardment,if these functions exist.The origin of the “discontinuity”,derived by Dr Glazov in 1995 in J.Phys.:Condens.Matter 7 6365,has been analysed in detail.For the power cross section,neglecting electronic stopping,the linear transport equations determining the depth distribution functions of the deposited energy and monentum (by taking the threshold enerkgy into account )have been solved asymptotically.An important formula derived by Dr Glazov has been confirmed and generalized.The results agree with the new theorem.     

墙体对微波脉冲的衰减特性

 研究墙体对微波脉冲的衰减特性，测量了微波脉冲垂直入射墙体后的脉冲信号，经过计算得到普通砖混墙、普通钢筋混凝土墙、钢筋网混凝土墙对窄带微波和超宽带微波的衰减值；分析了微波脉冲穿越不同墙体的频谱变化。研究结果表明，普通钢筋混凝土墙和普通砖混墙对窄带微波脉冲的衰减为0.342～0.699 dB/cm，对超宽带信号的衰减为0.134～0.183 dB/cm。钢筋网混凝土墙（厚65 cm）对超宽带信号的衰减较大（29.07～45.79 dB），同时使穿透墙体的超宽带信号频率分布向高频位移。     

浑水的声衰减

黄河水含有大量悬浮细粉沙,它是一种泥沙混合物的悬浮液,声波在其中传播时有严重的衰减.无论是从声波在浑水介质中传播的物理研究,还是从黄河治理所用的水声设备角度来说。研究并实际测量黄河浑水介质的声衰减都是一项有意义的工作.若在黄河现场进行较全面的声波衰减的测量,是有很大的困难性和局限性的,这就有必要在实验室内人为的制造“黄河浑水”.为此,我们从八二年的下半年开始筹备。经过半年多的努力,从制造浑水到实际测量,现已告一段落.     

有限温度下二维Heisenberg铁磁系统的声子衰减

在二维正方Heisenberg铁磁系统的基础上建立了磁振子-声子相互作用模型. 利用松原格林函数理论研究了系统的声子衰减，计算了布里渊区的主要对称点线上的声子衰减曲线. 发现在第一布里渊区，在Δ线上，横向声频支声子无衰减，在Z线上，纵向声频支声子无衰减；横向声频支声子衰减比纵向声频支声子衰减至少大一个数量级，并讨论了各项参数的变化对横向声频支声子衰减与纵向声频支声子衰减的影响. 根据声子衰减与声子寿命的关系，声子衰减与声子态密度的关系，可以讨论横向声频支声子与纵向声频支声子的寿命与态密度. 关键词： 磁振子-声子相互作用 横向声频支声子衰减 纵向声频支声子衰减 声子寿命     

高能COIL偏振态的实验研究

 通过两块楔镜补充衰减和中性衰减片相结合的能量衰减方法，测得了功率密度为20 W/mm² COIL的偏振态。采用角反射器作为稳定腔折返装置，提高了激光能量分布的均匀性。激光光束分别以45°的入射角入射到两块楔镜上，被楔镜反射后，垂直通过中性衰减片，最后进入偏振态测试仪。实验结果表明：在腔内没有任何偏振选择器件和不加外部电磁场的情况下，采用折叠式稳定腔的横流双模块氧碘化学激光光束呈现部分偏振性质，而且在出光过程中偏振度逐渐降低。     

基于声光效应的光束偏转控制理论研究

基于参量互作用观点及声光互作用原理,构建了入射光为高斯光并且存在声波吸收情况下的声光偏转器模型.基于此模型研究了超声波频率、声波功率和光束入射角对衍射光的影响.对比了有声波吸收和无声波吸收两种情况下上述三个参量对衍射光产生的不同影响.计算结果表明,同无声光吸收时相比,当存在声波吸收时,偏转器的衍射效率将减小,导致衍射波形畸变,光强峰值位置发生偏移.     

Energy decay for the elastic wave equation with a local time-dependent nonlinear damping

In this paper, we shall investigate the decay property of the solutions to the initial-boundary value problem for the elastic wave equation with a local time-dependent nonlinear damping. We give some decay rate of the energy when the damping term is effective only in a neighborhood of a suitable subset of the boundary. The results obtained in this paper extend, in particular, the known results for the scalar wave equation.