毛细管固定过氧化物酶流动注射化学发光法测定过氧化氢的研究

利用固定有辣根过氧化物酶的毛细管柱作为反应器与流通池,建立了一种简单、快速检测过氧化氢的流动注射化学发光分析新方法.当鲁米诺和过氧化氢的混合溶液流经反应器时,辣根过氧化物酶催化过氧化氢氧化鲁米诺产生化学发光.在选定的实验条件下,化学发光信号与过氧化氢的浓度在3.0×10-8～1.0×10-4mol/L范围内分段呈线性关系,检出限为1×10-8mol/L(S/N=3),相对标准偏差1.4%(1.0 μmol/L,n=9).该方法用于雨水中过氧化氢的测定,结果满意.     

痕量镉的水溶性碳纳米管增敏方波溶出伏安法测定

研究了以羧基化的水溶性碳纳米管(CNT)作为增敏剂,经吸附富集,用方波溶出伏安法测定痕量镉.讨论了吸附溶出的机理,对富集时间、富集电位、镉浓度、HCI加入量的影响及部分离子干扰等进行实验,并对含镉水样进行测定.实验结果发现:Cd2 在-0.65 V左右出现灵敏的溶出峰,峰电流在Cd2 浓度为2.0～10 nmol/L时呈现良好的线性关系,检出限为0.1 nmol/L,回收率为94%～103%.     

BPA在Na-MMT-CMC/GCE修饰电极上的电化学行为与检测

用循环伏安法和方波溶出伏安法研究了双酚A(BPA)在Na-MMT-CMC/GCE修饰电极上的电化学行为,并建立了一种检测BPA的电化学方法.实验表明:在pH 11.27的B-R缓冲溶液中,在0.42 V处出现一灵敏度高、峰形好的氧化峰.在优选的实验条件下,BPA浓度在6.0 ～80 μmol/L范围内与峰电流呈良好的线性关系,方法检出限为0.24 μmol/L,运用该法用于BPA回收率的测定取得令人满意的结果.     

人血清中半胱氨酸测定用自组装电化学传感器的研制

将四羧基钌(Ⅱ)酞菁(RuPc)共价键合到自组装在Au电极表面的巯基丁二胺单分子层上,获得了自组装修饰电极(RuPc-CME).研究了它的电化学性质,并采用扫描电子显微镜(SEM)、傅立叶变换红外光谱(FT-IR)、X射线光电子能仪(XPS)以及循环伏安法(CV)对该电极表面进行了表征.在pH 5.5时,循环伏安图显示RuPc修饰层存在一对氧化还原峰,其峰电位分别为V1pa=1.12 V,V1pc=1.09 V(vs. SCE).它的表面电子的电荷转移系数α为0.52,速率常数Ks=1.43 s-1,表面覆盖度Γ=7.82×10-10mol/cm2,属于单分子层吸附.在pH 3.0～5.5的PBS底液中,该电极对L-半胱氨酸(Hcy)的氧化有催化作用,采用计时安培电流法(CA)测定催化电流与Hcy的浓度在5.0×10-7～5.4×10-5mol/L范围内呈良好的线性关系,检出限为1.8×10-7 mol/L.用于检测人血清样品中的Hcy,结果满意.     

Non-Markovian decoherent quantum walks

Quantum walks act in obviously different ways from their classical counterparts, but decoherence will lessen and close this gap between them. To understand this process, it is necessary to investigate the evolution of quantum walks under different decoherence situations. In this article, we study a non-Markovian decoherent quantum walk on a line. In a short time regime, the behavior of the walk deviates from both ideal quantum walks and classical random walks. The position variance as a measure of the quantum walk collapses and revives for a short time, and tends to have a linear relation with time. That is, the walker's behavior shows a diffusive spread over a long time limit, which is caused by non-Markovian dephasing affecting the quantum correlations between the quantum walker and his coin. We also study both quantum discord and measurement-induced disturbance as measures of the quantum correlations, and observe both collapse and revival in the short time regime, and the tendency to be zero in the long time limit. Therefore, quantum walks with non-Markovian decoherence tend to have diffusive spreading behavior over long time limits, while in the short time regime they oscillate between ballistic and diffusive spreading behavior, and the quantum correlation collapses and revives due to the memory effect.     

磁场对铁质类金属热导率影响的初步分析

通过使用TC-3型固体热导率测定仪测量外加磁场的铁质类金属圆柱的热导率,并采用控制变量法,从而探究磁场对固体热导率的关系,发现外加磁场与铁质类的金属热导率变化存在线性关系。     

从多种角度看线性相关系数

1引言 在科学研究中,我们不但要了解一个变量的变化情况,更要进一步了解一个变量与另一个变量之间的关系．变量之间的常见关系有两种：一是确定性函数关系,变量之间的关系可以用函数表示;二是非确定性相关关系,变量之间有一定的关系,但不能完全用函数表达,变量间只存在统计规律．相关和回归是研究变量间线性关系的重要方法．但两者研究的角度不同．回归是研究变量间的因果关系的,力图把非确定性相关关系化归为确定的函数关系,达到通过自变量的已知值来预测因变量的未知值的目的．     

2009传感器非线性实验考题赏析

<正>传感器是将不便于测量的非电学量转化为易于测量、传输、处理的电学量的器件,其工作过程是通过对某一物理量敏感的元件将感受到的信号按一定规律转化为便于利用的信号。敏感元件大多由半     

Formability and Thermal Stability of Ce62Al15Fe8Co15 Bulk Metallic Glass

The formability and thermal stability of Ce62Al15Fe8Co15 bulk metallic glass （BMG） are studied by x-ray diffraction （XRD） and differential scanning calorimetry. The critical diameter of Ce62Al15Fe8Co15 BMG predicted by the parameter γ is about 3.1 mm, which is roughly in agreement with the XRD results. Stability of the BMG is investigated by means of continuous crystallization diagrams obtained from the extension of the Kissinger and Vogel-Fulcher-Tammann （VFT） equations comparatively. It is found that the dependence of crystallization temperature of the BMG on heating rates follows a nonlinear relationship rather than Kissinger and Lasoka＇s linear fittings. The thermal stability of the BMG is investigated by the VFT equation.     

Study of Fusion Dynamics Using Skyrme Energy Density Formalism with Different Surface Corrections

Within the framework of Skyrme energy density formalism, we investigate the role of surface corrections on the fusion of colliding nuclei. The coefficient of surface correction is varied between 1/36 and 4/36, and its impact is studied on about 180 reactions. The detailed investigations indicate a linear relationship between the fusion barrier heights and strength of the surface corrections. Our analysis of the fusion barriers advocate the strength of surface correction of 1/36.