电感耦合等离子体原子发射光谱(ICP-AES)法测定蒙药巴特日中17种元素的含量

建立了快速、准确同时测定蒙药巴特日中多种元素含量的方法。采用电感耦合等离子体原子发射光谱(ICP-AES)法同时测定了蒙药巴特中17种常量、微量及重金属元素的含量,进行了加标回收实验,结果表明,巴特日中Ca、P、K的含量较高,富含Fe和Mg等营养元素,Pb、Cd等重金属元素均低于国家标准。相对标准偏差(RSD)在0.36%~0.86%,加标回收率为95.8%~103%。测定的实验数据准确,可靠,可用于蒙药巴特日中多种元素的同时测定。     

A Nanosheet-Assembled SnO2-Integrated Anode

There is an ever-increasing trend toward bendable and high-energy-density electrochemical storage devices with high strength to fulfil the rapid development of flexible electronics, but they remain a great challenge to be realised by the traditional slurry-casting fabrication processes. To overcome these issues, herein, a facile strategy was proposed to design integrating an electrode with flexible, high capacity, and high tensile strength nanosheets with interconnected copper micro-fibre as a collector, loaded with a novel hierarchical SnO₂ nanoarchitecture, which were assembled into core–shell architecture, with a 1D micro-fibre core and 2D nanosheets shell. When applied as anode materials for LIBs, the resultant novel electrode delivers a large reversible specific capacity of 637.2 mAh g⁻¹ at a high rate of 1C. Such superior capacity may benefit from rational design based on structural engineering to boost synergistic effects of the integrated electrode. The outer shell with the ultrathin 2D nanoarchitecture blocks can provide favourable Li⁺ lateral intercalation lengths and more beneficial transport routes for electrolyte ions, with sufficient void space among the nanosheets to buffer the volume expansion. Furthermore, the interconnected 1D micro-fibre core with outstanding metallic conductivity can offer an efficient electron transport pathway along axial orientation to shorten electron transport. More importantly, the metal’s remarkable flexibility and high tensile strength provide the hybrid integrated electrode with strong bending and stretchability relative to sintered carbon or graphene hosts. The presented strategy demonstrates that this rational nanoarchitecture design based on integrated engineering is an effective route to maintain the structural stability of electrodes in flexible LIBs.     

基于荧光多光谱融合的水质化学需氧量的检测

为了对水中的有机污染物进行绿色、快速、准确的检测,提出了一种基于荧光多光谱融合的水质化学需氧量(Chemical Oxygen Demand, COD)的检测方法。实验样本为包含近岸海水和地表水在内的实际水样53份,采用标准化学方法获取样本的化学需氧量的理化值,利用荧光分光光度计采集样本的三维荧光光谱并对光谱数据进行处理和建模。在200～300 nm(间隔5 nm)的激发波长范围内将三维光谱展开成二维的发射光谱(发射波长范围250～500 nm,间隔2 nm)。采用ACO-iPLS(蚁群-区间偏最小二乘)算法提取发射光谱特征,PSO-LSSVM(粒子群优化的最小二乘支持向量机)算法建立预测模型,分别建立了单激发波长下的荧光发射光谱数据预测模型、多激发波长下发射光谱的数据级融合(LLDF)预测模型以及多激发波长下发射光谱的特征级融合(MLDF)预测模型,通过对预测效果的对比,得出结论。实验结果表明,对于不同激发波长下荧光发射光谱数据而言,265 nm激发光作用下的发射谱数据的预测模型最优,其检验集决定系数R2_P和外部检验均方根误差RMSEP分别为0.990 1和1.198 6 mg·L-1;对于荧光多光谱数据级融合模型(简写为：LLDF-PSO-LSSVM)而言,在235,265和290 nm激发光作用下的发射光谱的LLDF模型效果最优,其检验集的R2_ｐ和RMSEP分别为0.992 2和1.055 1 mg·L-1;对于荧光多光谱特征级融合模型(MLDF-PSO-LSSVM)而言,在265,290和305 nm激发光作用下的荧光发射光谱的MLDF模型效果最优,其R2_p=0.998 2,RMSEP=0.534 2 mg·L-1。综合比较各类建模结果可知,MLDF-PSO-LSSVM的模型效果最优,说明基于荧光发射光谱数据,采用多光谱特征级融合模型检测水质COD时,检测的精度更高,预测效果更好。     

电阻率与强度性能的关联及铜合金性能分区

铜合金以低电阻率为特征,由于电阻率与强度存在着共同的微观结构机理,两者往往协同变化,而导致难以对合金进行性能的全面评估和选材.本文以Cu-Ni-Mo合金作为研究对象,以团簇结构[Mo_1-Ni_(12)]构建固溶体的近程序结构模型,解析了电阻率和强度依赖于成分的定量变化规律,并定义了拉伸强度/电阻率的值为代表合金本质特性的"强阻比",得到了完全固溶态Cu-Ni-Mo合金的强阻比为7×10~8MPa/?·m,完全析出态的强阻比为(310—490)×10~8MPa/?·m.进而应用强阻比对常用铜合金进行了性能分区,给出铜合金材料选材的依据,得出了基于Cu-(Cr, Zr, Mg, Ag, Cd)等二元基础体系的铜合金适用于高强高导应用,而基于Cu-(Be, Ni, Sn, Fe, Zn, Ti, Al)等为基础二元体系的铜合金不能实现高强高导.该强阻比为310的特征性能分界线的发现为合金性能的全面评估提供了量化依据,可指导高强高导铜合金的选材和研发.     

Four Coordination Polymers Assembled with a New Biscarboxyl-functionalized Schiff Base Ligand

Based on a new biscarboxyl-functionalized Schiff base ligand 1,2-cyclohexanediamino-N,N'-bis[3-methoxyl-5-(p-carboxyl-phenylazo)] salicylidene(H₄L), four polymers,[(CH₃)₂NH₂]₂·[Mn₃(L)₂(H₂O)₄]·2DMF(CP1),[Fe₂(L)(H₂O)(DMF)](CP2),[(CH₃)₂NH₂]·[Cu(HL)]·H₂O(CP3) and[Ni₂(L)(teta)]·2DMF·H₂O(CP4), have been synthesized(teta=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane). In CP1, both of the internal[N₂O₂] pocket and the external carboxylate groups of L^4- anion are ligated by Mn²⁺ ions, and the structure displays a layer. In CP2, the Fe²⁺ cations are linked by L^4- anions to form a binuclear double chain. CP3 displays a[Cu₂(HL)₂] dimer. In CP4, the Ni²⁺ ions are connected by L^4- anions to form a chain. The structures are further linked by hydrogen bonds to form 2D or 3D supramolecular architectures, respectively. CP1 exhibits adsorption ability to three organic dyes.     

Temperature effect on qubit in RbCl quantum rod

We change the ellipsoidal boundary in a quantum rod (QR) into a spherical one by a coordinate transformation, and then study the influences of the ellipsoid aspect ratio and polaron radius on the probability density (PD) and oscillation period (OP) of an electron with the variational method of Pekar type (VMPT). By employing the quantum statistics theory (QST), we investigate the temperature effects on the PD and the OP. Numerical results denote that the electron probability density and the oscillation period increase (decay) with raising temperature in lower (higher) temperature regime. The electron probability density increases (decreases) with increasing ellipsoid aspect ratio when the temperature is in lower (higher) regime. The electron probability density decays (enhances) with increasing polaron radius when the temperature is in lower (higher) temperature regime. The oscillation period is an increasing function of the ellipsoid aspect ratio, whereas it is a decreasing one of the polaron radius.     

The effects of magnetic field and hydrogen-like impurity on RbCl quantum pseudodot qubit

By using a variational method of Pekar type, we investigate the effects of the hydrogen-like impurity and magnetic field on the electron’s probability density (PD) and oscillating frequency (OF) of a RbCl quantum pseudodot qubit. Numerical results indicate that (1) the PD oscillates periodically; (2) the crest of the PD will decrease with increasing the cyclotron frequencies and the Coulombic impurity potential strength; (3) as the cyclotron frequency of the magnetic field and the strength of the Coulombic impurity potential increases, PD’s peaks will occur more frequently; (4) besides, Figs. 1b and 2b clearly show that in a single period the PD will decrease with increasing the cyclotron frequency and the Coulombic impurity potential strength when \( t > 1.8\;\text{fs} \); whereas the changing law is just the opposite when \( t < 1.8\;\text{fs} \); (5) the OF is an aggrandizing function of the strength of the Coulombic impurity potential, whereas it is a decaying one of the cyclotron frequencies of the magnetic field. The coherence of qubit is crucial to the investigations of quantum information and quantum computation, where the electron’s PD, the OF and the coherence time are the physical quantities representing the properties of coherence. Our research results fine that by changing the cyclotron frequency of the magnetic field and the strength of the Coulombic impurity potential one can adjust the electron’s PD and the OF.

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Fig. 1 The PD \( \text{Q}\left( {r,t} \right) \) versus the time \( t \) and the cyclotron frequency of the magnetic field \( \omega_{c} \) with \( \text{V}_{0} = 10.0\,\text{meV, r}_{0} = 1.0\,\text{nm, }\beta \text{ = 1.0}\,\text{meV} \cdot \text{nm} \) and \( x = y = z = 1.0\,\text{nm} \)

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Fig. 2 The PD \( \text{Q}\left( {r,t} \right) \) versus the time \( t \) and strength of the Coulombic impurity potential \( \beta \) with \( \text{V}_{0} = 10.0\,\text{meV, r}_{0} = 1.0\,\text{nm,} \, \omega_{c} \text{ = 2.0}\, \times \text{10}^{13}\,\text{Hz} \) and \( x = y = z = 1.0\,\text{nm} \)

     

一维正方准晶中半无限裂纹问题的解析解

运用广义复变函数方法,通过构造适当的广义保角映射,研究了含有沿准周期方向穿透的半无限裂纹的一维正方准晶的反平面弹性问题,给出了在部分裂纹面上受均匀面外剪切时应力场和裂纹尖端应力强度因子的解析解.将此方法进一步推广到半无限裂纹垂直于一维正方准晶的准周期方向穿透的情形中,得到了相应的平面弹性问题的解析解.当准晶体的对称性增加时,还可以得出一维四方准晶相应问题的解析解.     

The temperature effect of the triangular bound potential quantum dot qubit

We study the eigenenergies and eigenfunctions of the ground and the first-excited states of an electron, which is strongly coupled to LO-phonon in a quantum dot with triangular bound potential by using the Pekar variational method. This system may be used as a two-level qubit. Numerical calculations are performed on the electron probability density varying with respect to the time, the temperature, the electron–LO-phonon coupling strength, the confinement length of the quantum dot and the polar angle. The relationship between the oscillating period and the polar angle is derived.     

一种新型四硫富瓦烯衍生物的合成与表征

以二硫化碳和金属钠为基础物质合成了四硫富瓦烯（TTF）锌的配合物（TTF）Zn（NBu4）2。利用该化合物与苯甲酰氯反应得到的稳定化合物C17H10O2S5在甲醇钠溶液中与2,3-二溴丙醇反应成功合成出目标化合物（一种新配体）,其化学组成为C6H6OS5。利用IR谱、^1HNMR谱及元素分析对此化合物进行了表征。