| 一种新型四硫富瓦烯衍生物的合成与表征 |
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| 引用本文： | 达胡白乙拉.一种新型四硫富瓦烯衍生物的合成与表征[J].光谱实验室,2009,26(5):1303-1305. |
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| 作者姓名： | 达胡白乙拉 |
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| 作者单位： | 内蒙古民族大学化学化工学院内蒙古通辽市霍林河大街22号,028043 |
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| 摘 要： | 以二硫化碳和金属钠为基础物质合成了四硫富瓦烯（TTF）锌的配合物（TTF）Zn（NBu4）2。利用该化合物与苯甲酰氯反应得到的稳定化合物C17H10O2S5在甲醇钠溶液中与2,3-二溴丙醇反应成功合成出目标化合物（一种新配体）,其化学组成为C6H6OS5。利用IR谱、^1HNMR谱及元素分析对此化合物进行了表征。
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| 关 键 词： | 新型四硫富瓦烯衍生物 合成 表征 |
Synthesis and Characterization of a New Tetrethiafulvalence Derivatives |
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| DA Hu-Baiyila.Synthesis and Characterization of a New Tetrethiafulvalence Derivatives[J].Chinese Journal of Spectroscopy Laboratory,2009,26(5):1303-1305. |
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| Authors: | DA Hu-Baiyila |
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| Institution: | Collage of Chemistry;Innermmongolia University for Nationalities;Tongliao;Innermongolia 028043;P.R.China |
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| Abstract: | A new tetrathiafulvalence derivatives En(NBu_4)_2 was synthesized with carbon disulfide and sodium.This compound was reacted with 2,3-dibrimide-1-butyl-propyl-alcobol,and a new coordination complex C_(17)H_(10)O_2S_5 was synthesized and the complex was characterized by IR, ~1HNMR and element analysis. |
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| Keywords: | New Tetrathiafulvalence Derivatives Synthesis Characterization |
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