首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1801篇
  免费   449篇
  国内免费   367篇
化学   1041篇
晶体学   14篇
力学   26篇
综合类   1篇
数学   493篇
物理学   1042篇
  2024年   2篇
  2023年   35篇
  2022年   86篇
  2021年   106篇
  2020年   101篇
  2019年   81篇
  2018年   64篇
  2017年   62篇
  2016年   84篇
  2015年   74篇
  2014年   95篇
  2013年   127篇
  2012年   196篇
  2011年   203篇
  2010年   135篇
  2009年   139篇
  2008年   117篇
  2007年   153篇
  2006年   141篇
  2005年   96篇
  2004年   70篇
  2003年   64篇
  2002年   60篇
  2001年   65篇
  2000年   34篇
  1999年   62篇
  1998年   29篇
  1997年   22篇
  1996年   22篇
  1995年   14篇
  1994年   8篇
  1993年   17篇
  1992年   8篇
  1991年   8篇
  1990年   1篇
  1989年   3篇
  1988年   26篇
  1987年   3篇
  1986年   1篇
  1985年   1篇
  1982年   1篇
  1936年   1篇
排序方式: 共有2617条查询结果,搜索用时 93 毫秒
51.
We investigate wave mixing effects in a phononic crystal that couples the wave dynamics of two channels – primary and control ones – via a variable stiffness mechanism. We demonstrate analytically and numerically that the wave transmission in the primary channel can be manipulated by the control channel's signal. We show that the application of control waves allows the selection of a specific mode through the primary channel. We also demonstrate that the mixing of two wave modes is possible whereby a modulation effect is observed. A detailed study of the design parameters is also carried out to optimize the switching capabilities of the proposed system. Finally, we verify that the system can fulfill both switching and amplification functionalities, potentially enabling the realization of an acoustic transistor.  相似文献   
52.
《数学季刊》2016,(2):178-188
Statistical inference is developed for the analysis of generalized type-II hybrid censoring data under exponential competing risks model. In order to solve the problem that approximate methods make unsatisfactory performances in the case of small sample size, we establish the exact conditional distributions of estimators for parameters by conditional moment generating function(CMGF). Furthermore, confidence intervals(CIs) are constructed by exact distributions, approximate distributions as well as bootstrap method respectively, and their performances are evaluated by Monte Carlo simulations. And finally, a real data set is analyzed to illustrate all the methods developed here.  相似文献   
53.
Research on Chemical Intermediates - Using diaryliodonium salts as the arylating reagent and copper as a catalyst, a series of triarylsulfonium salts bearing benzoyl or benzoheterocyclic moieties...  相似文献   
54.
A miniature mid-infrared (mid-IR) methane (CH4) sensor system was developed by employing a wide-band wire-source and a semi-ellipsoid multi-pass gas cell. A dual-step differential method instead of the traditional one-step differential method was adopted by this sensor to tune measuring range/zero point and to suppress the additive/multiplicative noise. This method included a first subtraction operation between the two output signals (including a detection signal and a reference signal) from the dual-channel detector and a second subtraction operation on the amplitudes of the first-subtraction signal and the reference signal, followed by a ratio operation between the amplitude of the second-subtraction signal and the reference signal. Detailed experiments were performed to assess the performance of the sensor system. The detection range is 0–50 k ppm, and as the concentration gets larger than 12 k ppm, the relative detection error falls into the range of −3% to +3%. The Allan deviation is about 4.65 ppm with an averaging time of 1 s, and such value can be further improved to 0.45 ppm with an averaging time of 124 s. Due to the cost-effective incandescence wire-source, the small-size ellipsoid multi-pass gas cell and the miniature structure of the sensor, the developed standalone device shows potential applications of CH4 detection under coal-mine environment.  相似文献   
55.
International Journal of Theoretical Physics - The mutual derivation between arbitrary distribution forms of momenta and momentum components of particles produced in an isotropic emission source...  相似文献   
56.
57.
As one of the biological endogenous pigments, biliverdin (BV) and its dimethyl ester (BVE) have extremely weak fluorescence in solution with quantum yield less than 0.01%. However, the situation reverses with the addition of zinc ions. The strength for fluorescence of BVE-Zn\begin{document}$ ^{2+} $\end{document} complex is greatly enhanced and fluorescence quantum yield can increase to \begin{document}$ \sim $\end{document}5%. Herein, we studied ultrafast excited state dynamics of BVE-Zn\begin{document}$ ^{2+} $\end{document} complex in ethanol, \begin{document}$ n $\end{document}-propanol, and DMSO solutions in order to reveal the mechanism of fluorescence quantum yield enhancement. The results show that BVE can form a stable coordination complex with zinc with 1:1 stoichiometry in solution. BVE is structurally and energetically more stable in the complex. Using picosecond time-resolve fluorescence and femtosecond transient absorption spectroscopy, we show that smaller non-radiative rate constant of BVE-Zn\begin{document}$ ^{2+} $\end{document} complex in DMSO is the key to increasing its fluorescence quantum yield and the excited state decay mechanism is also revealed. These results provide valuable information about the fluorescence property change after BVE binding to metal ions and may provide a guidance for the study of phytochromes or other fluorescence proteins in which BV/BVE acts as chromophores.  相似文献   
58.
This paper focuses on the stability of a hydropower station. First, we established a novel nonlinear mathematical model of a Francis hydro-turbine governing system considering both fractional-order derivative and time delay. The fractional-order α, which is introduced into the penstock system, in the range from 0.82 to 1.00 is on the left side of the model in a incommensurate manner in increment of 0.03 to provide an adjustable degree of system memory. The time delay τ, which exists between the signal and response in the hydraulic servo system, in the range from 0 s to 0.26 s is inserted on the right side of the model in increment of 0.04 s. Utilizing the principle of statistical physics, we respectively explored the effects of the fractional-order α and the time delay τ on the stable region of the system. Furthermore, we exhaustively investigated the nonlinear dynamic behaviors of the system with different governor parameters by using bifurcation diagrams, time waveforms and power spectrums, finding that only under the condition of reasonable collocation of governor parameters the system can maintain stable operation. Finally, all of the above numerical experiments supply new methods for studying the stability of a hydropower station.  相似文献   
59.
电离能是原子和分子的重要的特性参数,在光物理和光化学过程中起着重要作用,精确电离能对相关研究具有重要意义.电离能是调试零动能光谱信号的重要参考数据,在判断异构物数量和分子构型方面也起着关键作用.1,3-二乙氧基苯是一种重要的苯的衍生物,实验证实在超声分子束中包含两种旋转异构物Ⅰ(downup)和Ⅲ(down-down).它们的精确电离能还未见文献报道.本文采用直线式飞行时间质谱仪测量了静电场中1,3-二乙氧基苯光电离效率曲线,通过不同电场强度下测量的电离能(Stark效应)对场强的平方根线性拟合给出了两种异构物Ⅰ和Ⅲ精确的电离能分别为(62419±2)cm–1和(63378±2)cm–1.相对于通常的脉冲电场加速机制和零动能光谱测量的电离能,精确度大约分别由(±10)cm–1和(±5)cm–1提高到(±2)cm–1.分析和讨论了不同方法测量的物理机制和优缺点.  相似文献   
60.
In a recent paper, we theoretically investigated the density of states of the composite channel–contact system in the Coulomb and Kondo regimes using the self-consistent field approximation. There are the main experimental observations of vibration features in the Coulomb blockade [H. Park et al., Nature (London) 407, 57 (2000)] and Kondo [L. H. Yu et al., Phys. Rev. Lett. 93, 266802 (2004)] regimes. In the Kondo regime, our results show that one peak at E=μ can be observed in the density of states at low temperatures (0.0026 eV ≤ kBT ≤ 0.0000026 eV). Also, the real part of ∑3 has one minimum peak at E=μ and the real par of ∑2 has one maximum peak at E=μ for 0.01 ≤ μ ≤ 0.07 in the Kondo regime at low temperatures.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号