Some Two-Point Resistances of the Sierpinski Gasket Network

In this paper, we use the principle of substitution to replace sub-gaskets of the Sierpinski gasket network by an equivalent Y-network which enables the use of only the Delta–Wye transformation and the series and parallel principles to derive some two-point resistances of the Sierpinski gasket network with dimension two.     

一种难溶多金属氧酸盐配位聚合物的重构与表征

利用电沉积法将不溶于常规无机和有机溶剂的多金属氧酸盐基的配位聚合物1, [{La(H₂O)₅·(dipic)}{La(H₂O)(dipic)}]₂{Mo₈O₂₆}·10H₂O溶解于离子液体[RMIM][HT]或[RMIM][HP]中, 在恒电位下电解, 得到多金属氧酸盐基的配位聚合物膜. 应用红外光谱、X射线光电子能谱和XRD粉末衍射等方法研究多金属氧酸盐基配位聚合物膜的结构, 发现其与多金属氧酸盐基配位聚合物有相同的结构. 实现了多金属氧酸盐基配位聚合物在电极上的重构设计以及多金属氧酸盐基的配位聚合物的二次加工成型.     

Local electric field and configuration of CO molecules adsorbed on a nanostructured surface with nanocones

Based on the nanostructured surface model that the (platinum, Pt) nanocones grow out symmetrically from a plane substrate, the local electric field near the conical nanoparticle surface is computed and discussed. On the basis of these results, the adsorbed CO molecules are modelled as dipoles, and three kinds of interactions, i.e. interactions between dipoles and local electric field, between dipoles and dipoles, as well as between dipoles and nanostructured substrate, are taken into account. The spatial configuration of CO molecules adsorbed on the nanocone surface is then given by Monte-Carlo simulation. Our results show that the CO molecules adsorbed on the nanocone surface cause local agglomeration under the action of an external electric field, and this agglomeration becomes more compact with decreasing conical angle, which results in a stronger interaction among molecules. These results serve as a basis for explaining abnormal phenomena such as the abnormal infrared effect (AIRE), which was found when CO molecules were adsorbed on the nanostructured transition-metal surface.     

Measurement of the solubility of water in 2,2-dichloro-1,1,1-trifluoroethane (HCFC 123)

A metal ebulliometer has been used to measure the solubility of water in 2,2-dichloro-1,1,1-trifluoroethane (HCFC 123) over the temperature range 297–354 K. Solubilities varied from 9.5×10⁻³ to 3.75×10⁻² (mole fraction). Activity coefficients (γ^∞) and distribution coefficients (K^∞) were estimated. The results were used to resolve a discrepancy found in the literature concerning the vapor pressure of HCFC 123.     

THE VOLUME AND TOPOLOGY OF A COMPLETE REIMANNIAN MANIFOLD

51. IntroductionAn importallt problem in memannian geometry is whether the manifold is of finite topological type. By it we mean that there is a compact domain fi C M such that M C fi ishomeomorphic to off x [0, co). If the manifold has nonnegative Ricci curvature, some important results have been obtained by mathematicans (see [1,3,4,5,6, etc.]). It is well knownthat if Ric(M)20, one has Gromvo-Bishop volume comparison theorem and for any givenPPM, r > 0,c(n)vol[B(P, 1)]rsvol[B(p, r)]sw…     

灌喂氯化汞大鼠组织中汞结合金属硫蛋白的色谱/质谱联用表征研究

通过测定大鼠脏器组织中汞的总量、金属硫蛋白(MTs)含量及利用尺寸排阻色谱(SEC)与电感耦合等离子体质谱(ICP-MS)联用技术,分析了灌喂HgCl2大鼠脏器组织中汞与MTs的积累量及金属与MTs的结合形态。结果表明,灌喂HgCl2大鼠各脏器中汞的积累量显著高于其相应的对照组,特别是在肾、肝和睾丸中汞的含量较高,表明此3个脏器受汞的危害最大。MTs的含量水平说明当大鼠脏器受汞污染时,肌体中的MTs将被大量诱导产生以对重金属进行解毒。通过SEC-ICP-MS联用技术获得了组织中的金属与MTs的结合形态,其     

铝基复合材料超精密加工中的刀-屑摩擦磨损性能及模型研究

通过金刚石PCD刀具对非连续SiC增强铝基复合材料的超精密车削加工试验,考察了刀具第二切削变形区(刀具前刀面-切屑间)的摩擦磨损性能,并提出了相应的模型;采用爆炸式快速落刀装置制备出切屑根并分析了积屑瘤的影响因素;采用原子力显微镜对PCD刀具的刃口磨损形貌进行观察,并分析其磨损机理.结果表明:在超精密切削加工非连续增强铝基复合材料的过程中,前刀面仍然有极小的楔型积屑瘤产生;铝基复合材料的摩擦磨损性能明显优于铝合金,且当SiC增强相达到最佳体积分数(20%～25%)时,其摩擦磨损性能最佳;从刀具的耐磨性角度考虑,在超精密加工非连续增强铝基复合材料时适宜采用金刚石刀具.     

Geographical networks: geographical effects on network properties

Complex networks describe a wide range of systems in nature and society. Since most real systems exist in certain physical space and the distance between the nodes has influence on the connections, it is helpful to study geographical complex networks and to investigate how the geographical constrains on the connections affect the network properties. In this paper, we briefly review our recent progress on geographical complex networks with respect of statistics, modelling, robustness, and synchronizability. It has been shown that the geographical constrains tend to make the network less robust and less synchronizable. Synchronization on random networks and clustered networks is also studied.     

Effect of electric field on the electronic spectrum and the persistent current of a quantum ring with two electrons

The effect of an electric field E on a narrow quantum ring that contains two electrons and is threaded by a magnetic flux B has been investigated. Localization of the electronic distribution and suppression of the Aharonov--Bohm oscillation (ABO) are found in the two-electron ring, which are similar to those found in a one-electron ring. However, the period of ABO in a two-electron ring is reduced by half compared with that in a one-electron ring. Furthermore, during the variation of B, the persistent current of the ground state may undergo a sudden change in sign. This change is associated with a singlet--triplet transition and has no counterpart in one-electron rings. For a given E, there exists a threshold of energy. When the energy of the excited state exceeds the threshold, the localization would disappear and the ABO would recover. The value of the threshold is proportional to the magnitude of E. Once the threshold is exceeded, the persistent current is much stronger than the current of the ground state at E=0.     

分子发光法研究空间位阻效应对包络物形成的影响

利用分子发光法研究了正丁醇(n-butanol,n-Bu)和苯酚(phenol,ph)存在下空间位阻效应对β-环糊精(Cyclodextrin,β-CD)和溴代萘(Bromonaphthalene,BrN)包络物形成的影响。在各自最佳实验条件下,2-BrN/β-CD/n-Bu/ph体系的室温磷光(RTP)强度不及1-BrN/β-CD/n-Bu/ph体系的三分之一;而其荧光发射光谱较1-BrN/β-CD/n-Bu/ph发射光谱红移5～10 nm,表明BrN中溴的空间位置对包络物的形成有显著的影响。两四元体系包络常数(K_f)的测定结果也进一步说明这一点。据此,讨论了上述包络物的形成机理。